A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes

• Published in: Angewandte Chemie International Edition Vol. 55; no. 41; pp. 12868 - 12872
• Main Authors: Zhou, Yu-Peng, Raoufmoghaddam, Saeed, Szilvási, Tibor, Driess, Matthias
• Format: Journal Article
• Language: English
• Published: Germany Blackwell Publishing Ltd 04.10.2016; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Amination; Aromatic compounds; Carborane; Catalysis; Chelation; Chemical synthesis; Heavy metals; homogeneous catalysis; ligand design; Ligands; N-heterocyclic silylenes; Nickel; o-carboranes; Phosphines; Stretching; Transition metals; Vibration mode; ligand design; nickel; homogeneous catalysis; N-heterocyclic silylenes; o-carboranes

The synthesis and structure of the first 1,2‐bis(NHSi)‐substituted ortho‐carborane [(LSi:)C]2B10H10 (termed SiCCSi) is reported (NHSi=N‐heterocyclic silylene; L=PhC(NtBu)2). Its suitability to serve as a reliable bis(silylene) chelating ligand for transition metals is demonstrated by the formation o...