Simultaneous Chain-Growth and Step-Growth Polymerization of Methoxystyrenes by Rare-Earth Catalysts

The simultaneous chain‐growth and step‐growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system becaus...

Full description

Saved in:

Bibliographic Details
Published in	Angewandte Chemie International Edition Vol. 55; no. 47; pp. 14812 - 14817
Main Authors	Shi, Xiaochao, Nishiura, Masayoshi, Hou, Zhaomin
Format	Journal Article
Language	English
Published	WEINHEIM Blackwell Publishing Ltd 14.11.2016 Wiley Wiley Subscription Services, Inc
Edition	International ed. in English
Subjects	Addition polymerization Anisole Catalysts Chains (polymeric) Chemistry Chemistry, Multidisciplinary Condensation polymerization C−H activation Earth Ethylene gadolinium Insertion Macromolecules Molecular weight Physical Sciences Polydispersity Polymerization Rare earth elements rare-earth metals Reaction mechanisms Science & Technology Syndiotacticity polymerization COORDINATION POLYMERIZATION ISOPRENE COMPLEXES reaction mechanisms LIVING CATIONIC-POLYMERIZATION rare-earth metals P-METHOXYSTYRENE C-H activation ETHYLENE RADICAL POLYMERIZATION COPOLYMERIZATION INITIATORS gadolinium STYRENE-STYRENE SEQUENCES C−H activation
Online Access	Get full text

Cover

Loading…

Abstract	The simultaneous chain‐growth and step‐growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain‐growth polymerization and step‐growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain‐growth and step‐growth polymerization of para‐ and meta‐methoxystyrenes catalyzed by half‐sandwich rare‐earth alkyl complexes, and the step‐growth polymerization proceeds by the C−H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole‐ethylene sequences. In contrast to para‐ and meta‐methoxystyrenes, ortho‐methoxystyrene exclusively undergo syndiospecific, living chain‐growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho‐methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, Mn up to 280 kg mol−1, Mw/Mn <1.10). Growth spurt: Both continuous C=C bond insertion and C−H addition of anisole units to vinyl groups took place in the polymerization of para‐ and meta‐methoxystyrenes when catalyzed by a half‐sandwich rare‐earth catalyst, thus affording novel macromolecules containing multiple branches of alternating anisole‐ethylene sequences. In contrast, the polymerization of ortho‐methoxystyrene occurred exclusively through continuous C=C insertion without involving C−H activation.
AbstractList	The simultaneous chain‐growth and step‐growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain‐growth polymerization and step‐growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain‐growth and step‐growth polymerization of para‐ and meta‐methoxystyrenes catalyzed by half‐sandwich rare‐earth alkyl complexes, and the step‐growth polymerization proceeds by the C−H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole‐ethylene sequences. In contrast to para‐ and meta‐methoxystyrenes, ortho‐methoxystyrene exclusively undergo syndiospecific, living chain‐growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho‐methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, Mn up to 280 kg mol−1, Mw/Mn <1.10). Growth spurt: Both continuous C=C bond insertion and C−H addition of anisole units to vinyl groups took place in the polymerization of para‐ and meta‐methoxystyrenes when catalyzed by a half‐sandwich rare‐earth catalyst, thus affording novel macromolecules containing multiple branches of alternating anisole‐ethylene sequences. In contrast, the polymerization of ortho‐methoxystyrene occurred exclusively through continuous C=C insertion without involving C−H activation. The simultaneous chain‐growth and step‐growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain‐growth polymerization and step‐growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain‐growth and step‐growth polymerization of para‐ and meta‐methoxystyrenes catalyzed by half‐sandwich rare‐earth alkyl complexes, and the step‐growth polymerization proceeds by the C−H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole‐ethylene sequences. In contrast to para‐ and meta‐methoxystyrenes, ortho‐methoxystyrene exclusively undergo syndiospecific, living chain‐growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho‐methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, M n up to 280 kg mol −1 , M w /M n <1.10). The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain-growth polymerization and step-growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain-growth and step-growth polymerization of para- and meta-methoxystyrenes catalyzed by half-sandwich rare-earth alkyl complexes, and the step-growth polymerization proceeds by the C-H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole-ethylene sequences. In contrast to para- and meta-methoxystyrenes, ortho-methoxystyrene exclusively undergo syndiospecific, living chain-growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho-methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, Mn up to 280 kg mol-1 , Mw /Mn <1.10).The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain-growth polymerization and step-growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain-growth and step-growth polymerization of para- and meta-methoxystyrenes catalyzed by half-sandwich rare-earth alkyl complexes, and the step-growth polymerization proceeds by the C-H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole-ethylene sequences. In contrast to para- and meta-methoxystyrenes, ortho-methoxystyrene exclusively undergo syndiospecific, living chain-growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho-methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, Mn up to 280 kg mol-1 , Mw /Mn <1.10). The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain-growth polymerization and step-growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain-growth and step-growth polymerization of para-and meta-methoxystyrenes catalyzed by half-sandwich rare-earth alkyl complexes, and the step-growth polymerization proceeds by the C-H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole-ethylene sequences. In contrast to para-and meta-methoxystyrenes, ortho-methoxystyrene exclusively undergo syndiospecific, living chain-growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho-methoxystyrene) with high molecular weight and narrow polydispersity (rrrr > 99%, M-n up to 280 kgmol(-1), M-w/M-n < 1.10). The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain-growth polymerization and step-growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain-growth and step-growth polymerization of para- and meta-methoxystyrenes catalyzed by half-sandwich rare-earth alkyl complexes, and the step-growth polymerization proceeds by the C-H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole-ethylene sequences. In contrast to para- and meta-methoxystyrenes, ortho-methoxystyrene exclusively undergo syndiospecific, living chain-growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho-methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99%, Mn up to 280kgmol-1, Mw/Mn <1.10). The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules which are difficult to prepare by other means. However, such a transformation is usually difficult to achieve in one polymerization system because chain-growth polymerization and step-growth polymerization proceed by different reaction mechanisms. Reported here is the simultaneous chain-growth and step-growth polymerization of para- and meta-methoxystyrenes catalyzed by half-sandwich rare-earth alkyl complexes, and the step-growth polymerization proceeds by the C-H polyaddition of anisyl units to vinyl groups. This unprecedented transformation affords a new family of macromolecules containing unique alternating anisole-ethylene sequences. In contrast to para- and meta-methoxystyrenes, ortho-methoxystyrene exclusively undergo syndiospecific, living chain-growth polymerization by continuous C=C bond insertion to give perfect syndiotactic poly(ortho-methoxystyrene) with high molecular weight and narrow polydispersity (rrrr >99 %, M up to 280 kg mol , M /M <1.10).
Author	Nishiura, Masayoshi Hou, Zhaomin Shi, Xiaochao
Author_xml	– sequence: 1 givenname: Xiaochao surname: Shi fullname: Shi, Xiaochao organization: Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan – sequence: 2 givenname: Masayoshi surname: Nishiura fullname: Nishiura, Masayoshi organization: Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan – sequence: 3 givenname: Zhaomin surname: Hou fullname: Hou, Zhaomin email: houz@riken.jp organization: Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/27774727$$D View this record in MEDLINE/PubMed
BookMark	eNqNkktr3DAQgE1JaR7ttcdi6KVQvJUsyZKPwWy3Iem2dPs4ClkeEaVeayPJJO6vr9LdLCXQBwg0Qt-nGQ1znB0MboAse47RDCNUvlGDhVmJcIVqVLFH2RFmJS4I5-QgxZSQgguGD7PjEK4SLwSqnmSHJeec8pIfZXpl12Mf1QBuDHlzqexQLLy7iZe5Grp8FWFzf_7o-mkN3v5Q0bohdyZ_D_HS3U4hTh4GCHk75Z-Uh2KufOIbFVWfLsPT7LFRfYBnu_0k-_J2_rl5V1x8WJw1pxeFZrRkhTbadIKKSuPOlLomilFEMRdGGF1XuGoZhrqFihCmOlOLru06ojTtuGGgKnKSvdq-u_HueoQQ5doGDX2__Z3EgjCGBKEooS8foFdu9EOqTuLUSCRqXrO_UoJSnlZNE_ViR43tGjq58Xat_CTvm5wAsQVuoHUmaAuDhj2GECJClKzkKapQY-Ov_jZuHGJSX_-_mujZltbeheDB7EmM5N24yLtxkftxSQJ9IOhd-uiV7f-s1buqbA_TP5LI0-XZ_He32Lo2RLjdu8p_lxUnnMlvy4VcnovzRvCvckV-AnTQ4aI
CODEN	ACIEAY
CitedBy_id	crossref_primary_10_1021_acs_inorgchem_4c00723 crossref_primary_10_1021_acs_macromol_8b02135 crossref_primary_10_1021_jacs_0c13166 crossref_primary_10_1002_anie_202502665 crossref_primary_10_1021_jacs_4c17210 crossref_primary_10_1126_sciadv_1701011 crossref_primary_10_1039_D3NJ02625F crossref_primary_10_1002_anie_202422147 crossref_primary_10_1016_j_polymer_2017_09_036 crossref_primary_10_1021_acs_macromol_0c01121 crossref_primary_10_1039_D0NJ03852K crossref_primary_10_1002_chem_201805012 crossref_primary_10_1002_marc_201900061 crossref_primary_10_1039_D3PY00798G crossref_primary_10_1039_C6DT04820J crossref_primary_10_1021_jacs_0c01171 crossref_primary_10_1021_jacs_9b04275 crossref_primary_10_1002_cctc_202201083 crossref_primary_10_1002_anie_202210624 crossref_primary_10_1021_acs_macromol_2c02155 crossref_primary_10_1021_acs_macromol_7b01668 crossref_primary_10_1002_anie_201915760 crossref_primary_10_1021_acs_macromol_9b02274 crossref_primary_10_1038_s41428_022_00660_w crossref_primary_10_1002_ange_202502665 crossref_primary_10_1002_anie_202000060 crossref_primary_10_1021_acs_organomet_8b00397 crossref_primary_10_1039_C9PY01789E crossref_primary_10_1039_D4DT01036A crossref_primary_10_1002_anie_202318203 crossref_primary_10_1021_acscatal_8b00885 crossref_primary_10_1016_j_ccr_2017_02_001 crossref_primary_10_1002_chem_201903910 crossref_primary_10_1021_acs_inorgchem_8b02067 crossref_primary_10_1002_ange_202000060 crossref_primary_10_1021_acs_macromol_9b01299 crossref_primary_10_1002_ange_201915760 crossref_primary_10_1021_acs_organomet_7b00526 crossref_primary_10_1039_D3PY00997A crossref_primary_10_1021_acs_macromol_4c00958 crossref_primary_10_1002_ange_201611066 crossref_primary_10_1021_acs_macromol_9b02602 crossref_primary_10_1016_j_xcrp_2023_101246 crossref_primary_10_1002_cctc_201701090 crossref_primary_10_1039_D3PY00959A crossref_primary_10_1039_D1PY01251G crossref_primary_10_1002_ange_202318203 crossref_primary_10_1021_acscatal_8b01364 crossref_primary_10_5059_yukigoseikyokaishi_78_575 crossref_primary_10_3390_catal12040439 crossref_primary_10_6023_cjoc202308007 crossref_primary_10_1039_C8PY00625C crossref_primary_10_1021_acscatal_2c03681 crossref_primary_10_1002_pola_28617 crossref_primary_10_1039_D2CC02489F crossref_primary_10_1021_jacs_8b13316 crossref_primary_10_1002_ange_201705431 crossref_primary_10_1021_acsengineeringau_4c00015 crossref_primary_10_1021_acs_macromol_2c02337 crossref_primary_10_1002_anie_201708797 crossref_primary_10_1021_jacs_3c06482 crossref_primary_10_1016_j_tet_2023_133323 crossref_primary_10_1039_D1QO01859K crossref_primary_10_1021_acs_inorgchem_3c04428 crossref_primary_10_1007_s11172_024_4271_1 crossref_primary_10_1021_jacs_4c02144 crossref_primary_10_1039_D2PY00290F crossref_primary_10_1021_jacs_0c08362 crossref_primary_10_1021_acscatal_1c05546 crossref_primary_10_1021_acs_inorgchem_4c00097 crossref_primary_10_1002_ange_202422147 crossref_primary_10_1039_C8CS00201K crossref_primary_10_3390_inorganics12060172 crossref_primary_10_1002_marc_202000038 crossref_primary_10_1016_j_ccr_2018_08_017 crossref_primary_10_1002_ange_201708797 crossref_primary_10_1002_anie_201705431 crossref_primary_10_1002_ejic_202200699 crossref_primary_10_1021_jacs_4c15046 crossref_primary_10_1021_acs_organomet_1c00439 crossref_primary_10_1055_a_1945_0777 crossref_primary_10_1039_D4DT00838C crossref_primary_10_1021_acs_macromol_1c01581 crossref_primary_10_1021_acs_macromol_8b01405 crossref_primary_10_1002_ange_202210624 crossref_primary_10_1021_acs_organomet_8b00532
Cites_doi	10.1021/ma062261k 10.1039/c3cc43603a 10.1002/anie.201105636 10.1021/ma00206a008 10.1021/jacs.6b03859 10.1021/bm300254s 10.1021/jacs.5b03733 10.1039/C5CC00470E 10.1021/om1012055 10.1021/ma0490451 10.1021/acs.macromol.6b00083 10.1039/C5PY01879J 10.1002/anie.201206233 10.1002/ange.201412166 10.1021/ma00191a021 10.1021/ma301505j 10.1021/ma2000465 10.1021/ma800810m 10.1002/anie.201104011 10.1016/S0079-6700(00)00007-1 10.1021/ma200441w 10.1002/ange.201206233 10.1002/pol.1969.150070732 10.1002/anie.201412166 10.1021/ja1023892 10.1002/macp.1962.020580115 10.1038/nchem.595 10.1002/pola.26792 10.1002/macp.1982.021830111 10.1021/acs.accounts.5b00219 10.1002/ange.201104011 10.1002/ange.201105636 10.1021/ma101835e 10.1021/ma201271r 10.1021/acs.chemrev.5b00393 10.1021/ja046063p 10.1021/ma7027006 10.1021/acs.macromol.5b02223 10.1039/b708534f 10.1039/c5py01879j 10.1039/c5cc00470e
ContentType	Journal Article
Copyright	2016 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright_xml	– notice: 2016 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. – notice: 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
DBID	BSCLL AAYXX CITATION 17B 1KN BLEPL DTL EGQ GYFQL NPM 7TM K9. 7X8
DOI	10.1002/anie.201609065
DatabaseName	Istex CrossRef Web of Knowledge Current Chemical Reactions Web of Science Core Collection Science Citation Index Expanded Web of Science Primary (SCIE, SSCI & AHCI) Web of Science - Science Citation Index Expanded - 2016 PubMed Nucleic Acids Abstracts ProQuest Health & Medical Complete (Alumni) MEDLINE - Academic
DatabaseTitle	CrossRef Web of Science PubMed ProQuest Health & Medical Complete (Alumni) Nucleic Acids Abstracts MEDLINE - Academic
DatabaseTitleList	CrossRef MEDLINE - Academic Web of Science ProQuest Health & Medical Complete (Alumni) PubMed ProQuest Health & Medical Complete (Alumni)
Database_xml	– sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: 1KN name: Current Chemical Reactions url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.CCR sourceTypes: Enrichment Source Index Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1521-3773
Edition	International ed. in English
EndPage	14817
ExternalDocumentID	4265679511 27774727 000388252700060 10_1002_anie_201609065 ANIE201609065 ark_67375_WNG_NK8KC87V_S
Genre	shortCommunication Research Support, Non-U.S. Gov't Journal Article
GrantInformation_xml	– fundername: JSPS; Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT); Japan Society for the Promotion of Science grantid: 26220802 – fundername: Grants-in-Aid for Scientific Research; Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT); Japan Society for the Promotion of Science; Grants-in-Aid for Scientific Research (KAKENHI) grantid: 26220802 – fundername: ImPACT Program of Council for Science, Technology and Innovation, the Cabinet Office, Government of Japan
GroupedDBID	--- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 23M 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5RE 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABEML ABIJN ABLJU ABPPZ ABPVW ACAHQ ACCFJ ACCZN ACFBH ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFNX AFFPM AFGKR AFPWT AFRAH AFZJQ AHBTC AHMBA AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB B-7 BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BSCLL BTSUX BY8 CS3 D-E D-F D0L DCZOG DPXWK DR1 DR2 DRFUL DRSTM EBS EJD F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M53 MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RNS ROL RWI RX1 RYL SUPJJ TN5 UB1 UPT V2E VQA W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XSW XV2 YZZ ZZTAW ~IA ~KM ~WT AAHQN AAMNL AAYCA AFWVQ ALVPJ AAYXX ABDBF ABJNI AETEA AEYWJ AGHNM AGYGG CITATION 17B 1KN BLEPL DTL GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED GROUPED_WOS_WEB_OF_SCIENCE NPM YIN 7TM K9. 7X8
ID	FETCH-LOGICAL-c5425-cfcfd8486c1df2c93a5404178f8fc9616b51e9be6335adf98dbdd3ac4d7f5ea63
IEDL.DBID	DR2
ISICitedReferencesCount	85
ISICitedReferencesURI	https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000388252700060
ISSN	1433-7851 1521-3773
IngestDate	Fri Jul 11 00:17:23 EDT 2025 Sun Jul 13 03:23:45 EDT 2025 Sun Jul 13 02:52:36 EDT 2025 Wed Feb 19 02:41:22 EST 2025 Fri Aug 29 15:53:24 EDT 2025 Wed Jul 09 18:19:28 EDT 2025 Thu Apr 24 23:02:03 EDT 2025 Tue Jul 01 03:27:22 EDT 2025 Wed Jan 22 16:39:07 EST 2025 Wed Oct 30 09:57:33 EDT 2024
IsPeerReviewed	true
IsScholarly	true
Issue	47
Keywords	polymerization COORDINATION POLYMERIZATION ISOPRENE COMPLEXES reaction mechanisms LIVING CATIONIC-POLYMERIZATION rare-earth metals P-METHOXYSTYRENE C-H activation ETHYLENE RADICAL POLYMERIZATION COPOLYMERIZATION INITIATORS gadolinium STYRENE-STYRENE SEQUENCES C−H activation
Language	English
License	http://onlinelibrary.wiley.com/termsAndConditions#vor 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
LinkModel	DirectLink
LogoURL	https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg
MergedId	FETCHMERGED-LOGICAL-c5425-cfcfd8486c1df2c93a5404178f8fc9616b51e9be6335adf98dbdd3ac4d7f5ea63
Notes	ark:/67375/WNG-NK8KC87V-S ArticleID:ANIE201609065 istex:DD1A1F0576C1958A7D72CEAAB3E6C9811684DEB0 KAKEN ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ORCID	0000-0003-2841-5120 0000-0001-5178-7972 0000-0003-2748-9814
PMID	27774727
PQID	1844744794
PQPubID	946352
PageCount	6
ParticipantIDs	webofscience_primary_000388252700060CitationCount proquest_miscellaneous_1835508340 pubmed_primary_27774727 proquest_journals_1844744794 wiley_primary_10_1002_anie_201609065_ANIE201609065 crossref_citationtrail_10_1002_anie_201609065 istex_primary_ark_67375_WNG_NK8KC87V_S webofscience_primary_000388252700060 crossref_primary_10_1002_anie_201609065 proquest_journals_1906089795
ProviderPackageCode	CITATION AAYXX
PublicationCentury	2000
PublicationDate	November 14, 2016
PublicationDateYYYYMMDD	2016-11-14
PublicationDate_xml	– month: 11 year: 2016 text: November 14, 2016 day: 14
PublicationDecade	2010
PublicationPlace	WEINHEIM
PublicationPlace_xml	– name: WEINHEIM – name: Germany – name: Weinheim
PublicationTitle	Angewandte Chemie International Edition
PublicationTitleAbbrev	ANGEW CHEM INT EDIT
PublicationTitleAlternate	Angew. Chem. Int. Ed
PublicationYear	2016
Publisher	Blackwell Publishing Ltd Wiley Wiley Subscription Services, Inc
Publisher_xml	– name: Blackwell Publishing Ltd – name: Wiley – name: Wiley Subscription Services, Inc
References	T. Yokozawa, Y. Ohta, Chem. Commun. 2013, 49, 8281 A. Yamamoto, M. Nishiura, J. Oyamada, H. Koshino, Z. Hou, Macromolecules 2016, 49, 2458. K. Nakatani, M. Ouchi, M. Sawamoto, Macromolecules 2008, 41, 4579. X. Shi, M. Nishiura, Z. Hou, J. Am. Chem. Soc. 2016, 138, 6147. E. S. Wilks, Prog. Polym. Sci. 2000, 25, 9 M. Mizutani, E. F. Palermo, L. M. Thoma, K. Satoh, M. Kamigaito, K. Kuroda, Biomacromolecules 2012, 13, 1554 M. Uchiyama, K. Satoh, M. Kamigaito, Polym. Chem. 2016, 7, 1387 J. Oyamada, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 2011, 50, 10720 Angew. Chem. 2015, 127, 5294 M. Nishiura, Z. Hou, Nat. Chem. 2010, 2, 257 T. Shima, M. Nishiura, Z. Hou, Organometallics 2011, 30, 2513 D. Liu, R. Wang, M. Wang, C. Wu, Z. Wang, C. Yao, B. Liu, X. Wan, D. Cui, Chem. Commun. 2015, 51, 4685 S. E. M. Selke, J. D. Culter, R. J. Hernandez, Plastics Packaging: Properties, Processing, Applications, and Regulations, 2nd Ed., Hanser Gardner Pub., 2004. Y. Luo, J. Baldamus, Z. Hou, J. Am. Chem. Soc. 2004, 126, 13910 Angew. Chem. 2012, 124, 13000. K. Kojima, M. Sawamoto, T. Higashimura, Macromolecules 1990, 23, 948 M. Mizutani, K. Satoh, M. Kamigaito, J. Am. Chem. Soc. 2010, 132, 7498 J. Oyamada, Z. Hou, Angew. Chem. Int. Ed. 2012, 51, 12828 F. Guo, M. Nishiura, H. Koshino, Z. Hou, Macromolecules 2011, 44, 2400 H. Yuki, Y. Okamoto, Y. Kuwae, K. Hatada, J. Polym. Sci. Part A-1 1969, 7, 1933. M. Nishiura, F. Guo, Z. Hou, Acc. Chem. Res. 2015, 48, 2209. H. Zhang, Y. Luo, Z. Hou, Macromolecules 2008, 41, 1064 Angew. Chem. 2011, 123, 12218 T. Yokozawa, Y. Ohta, Chem. Rev. 2016, 116, 1950. A. J. Perkowski, W. You, D. A. Nicewicz, J. Am. Chem. Soc. 2015, 137, 7580 A. Grassi, P. Longo, A. Proto, A. Zambelli, Macromolecules 1989, 22, 104. X. Li, M. Nishiura, K. Mori, T. Mashiko, Z. Hou, Chem. Commun. 2007, 4137 X. Zhang, H. Dou, Z. Zhang, W. Zhang, X. Zhu, J. Zhu, J. Polym. Sci. Part A 2013, 51, 3907 L. Pan, K. Zhang, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 2011, 50, 12012 X. Li, Z. Hou, Macromolecules 2010, 43, 8904 T. Yoshizaki, A. Kanazawa, S. Kanaoka, S. Aoshima, Macromolecules 2016, 49, 71. P. De, R. Faust, Macromolecules 2004, 37, 7930 T. Kawamura, T. Uryu, K. Matsuzaki, Makromol. Chem. 1982, 183, 125 S. V. Kostjuk, A. V. Radchenko, F. Ganachaud, Macromolecules 2007, 40, 482 A. Kanazawa, S. Shibutani, N. Yoshinari, T. Konno, S. Kanaoka, S. Aoshima, Macromolecules 2012, 45, 7749 F. Guo, M. Nishiura, H. Koshino, Z. Hou, Macromolecules 2011, 44, 6335 M. Mizuntani, K. Satoh, M. Kamigaito, Macromolecules 2011, 44, 2382 D. Liu, C. Yao, R. Wang, M. Wang, Z. Wang, C. Wu, F. Lin, S. Li, X. Wan, D. Cui, Angew. Chem. Int. Ed. 2015, 54, 5205 G. Natta, G. Dall'Asta, G. Mazzanti, A. Casale, Makromol. Chem. 1962, 58, 217 Angew. Chem. 2011, 123, 10908. 1989; 22 2004; 126 2013; 49 2000; 25 2015; 51 2011; 30 1962; 58 2007 2004 2012; 13 1982; 183 2015; 48 2010; 43 2016; 7 1990; 23 2015; 137 2013; 51 2012 2012; 51 124 2004; 37 1969; 7 2010; 132 2011; 44 2015 2015; 54 127 2016; 116 2011 2011; 50 123 2016; 138 2007; 40 2008; 41 2010; 2 2012; 45 2016; 49 e_1_2_2_4_1 Selke S. E. M. (e_1_2_2_3_2) 2004 e_1_2_2_24_1 e_1_2_2_22_2 e_1_2_2_6_2 e_1_2_2_20_1 e_1_2_2_2_2 e_1_2_2_41_2 e_1_2_2_8_2 e_1_2_2_43_2 e_1_2_2_28_1 e_1_2_2_45_1 e_1_2_2_26_2 e_1_2_2_45_2 e_1_2_2_13_2 e_1_2_2_36_2 e_1_2_2_38_2 e_1_2_2_11_1 e_1_2_2_30_2 e_1_2_2_19_1 e_1_2_2_17_2 e_1_2_2_32_2 e_1_2_2_15_2 e_1_2_2_34_2 e_1_2_2_23_2 e_1_2_2_5_2 e_1_2_2_21_2 e_1_2_2_1_1 e_1_2_2_40_1 e_1_2_2_29_2 e_1_2_2_42_2 e_1_2_2_7_2 e_1_2_2_44_1 e_1_2_2_27_2 e_1_2_2_44_2 e_1_2_2_25_3 e_1_2_2_9_2 e_1_2_2_25_2 e_1_2_2_12_2 e_1_2_2_37_2 e_1_2_2_37_3 e_1_2_2_39_1 e_1_2_2_10_2 e_1_2_2_31_1 e_1_2_2_18_2 e_1_2_2_16_2 e_1_2_2_33_2 e_1_2_2_14_2 e_1_2_2_35_2 Pan, L. (000388252700060.26) 2011; 123 Oyamada, J. (000388252700060.22) 2011; 123 Perkowski, AJ (WOS:000357062000010) 2015; 137 Oyamada, J. (000388252700060.24) 2012; 124 Uchiyama, M (WOS:000369692700004) 2016; 7 Liu, DT (WOS:000354190800042) 2015; 54 YUKI, H (WOS:A1969E134500032) 1969; 7 Shima, T (WOS:000290001900010) 2011; 30 GRASSI, A (WOS:A1989R898500021) 1989; 22 Nakatani, K (WOS:000257366200010) 2008; 41 Nishiura, M (WOS:000359892700006) 2015; 48 Zhang, XM (WOS:000322656500016) 2013; 51 NATTA, G (WOS:A1962WX81200015) 1962; 58 Guo, F (WOS:000294076300014) 2011; 44 Yamamoto, A (WOS:000374195600006) 2016; 49 Selke, S. E. M. (000388252700060.29) 2004 Kanazawa, A (WOS:000309505500010) 2012; 45 Luo, YJ (WOS:000224873600017) 2004; 126 Nishiura, M (WOS:000275928300011) 2010; 2 KAWAMURA, T (WOS:A1982NC54200011) 1982; 183 Guo, F (WOS:000289593200002) 2011; 44 Zhang, H (WOS:000253331200004) 2008; 41 Pan, L (WOS:000298085000030) 2011; 50 Shi, XC (WOS:000376331000015) 2016; 138 Yokozawa, T (WOS:000323519200001) 2013; 49 Mizutani, M (WOS:000303951600037) 2012; 13 Oyamada, J (WOS:000297175600046) 2011; 50 Yokozawa, T (WOS:000371106000006) 2016; 116 Oyamada, J (WOS:000312305400035) 2012; 51 KOJIMA, K (WOS:A1990CP85700008) 1990; 23 Li, XF (WOS:000250085500017) 2007 De, P (WOS:000224472500014) 2004; 37 Kostjuk, SV (WOS:000243839700014) 2007; 40 Liu, DT (WOS:000350486300034) 2015; 51 Mizuntani, M (WOS:000289028500085) 2011; 44 Mizutani, M (WOS:000278190600052) 2010; 132 Wilks, ES (WOS:000087633800003) 2000; 25 Yoshizaki, T (WOS:000368322000009) 2016; 49 Li, XF (WOS:000283693500028) 2010; 43 Liu, D. (000388252700060.13) 2015; 127
References_xml	– reference: T. Shima, M. Nishiura, Z. Hou, Organometallics 2011, 30, 2513; – reference: S. E. M. Selke, J. D. Culter, R. J. Hernandez, Plastics Packaging: Properties, Processing, Applications, and Regulations, 2nd Ed., Hanser Gardner Pub., 2004. – reference: T. Yoshizaki, A. Kanazawa, S. Kanaoka, S. Aoshima, Macromolecules 2016, 49, 71. – reference: F. Guo, M. Nishiura, H. Koshino, Z. Hou, Macromolecules 2011, 44, 2400; – reference: A. Yamamoto, M. Nishiura, J. Oyamada, H. Koshino, Z. Hou, Macromolecules 2016, 49, 2458. – reference: A. Kanazawa, S. Shibutani, N. Yoshinari, T. Konno, S. Kanaoka, S. Aoshima, Macromolecules 2012, 45, 7749; – reference: M. Nishiura, Z. Hou, Nat. Chem. 2010, 2, 257; – reference: S. V. Kostjuk, A. V. Radchenko, F. Ganachaud, Macromolecules 2007, 40, 482; – reference: J. Oyamada, Z. Hou, Angew. Chem. Int. Ed. 2012, 51, 12828; – reference: D. Liu, C. Yao, R. Wang, M. Wang, Z. Wang, C. Wu, F. Lin, S. Li, X. Wan, D. Cui, Angew. Chem. Int. Ed. 2015, 54, 5205; – reference: H. Yuki, Y. Okamoto, Y. Kuwae, K. Hatada, J. Polym. Sci. Part A-1 1969, 7, 1933. – reference: D. Liu, R. Wang, M. Wang, C. Wu, Z. Wang, C. Yao, B. Liu, X. Wan, D. Cui, Chem. Commun. 2015, 51, 4685; – reference: A. Grassi, P. Longo, A. Proto, A. Zambelli, Macromolecules 1989, 22, 104. – reference: M. Nishiura, F. Guo, Z. Hou, Acc. Chem. Res. 2015, 48, 2209. – reference: X. Li, M. Nishiura, K. Mori, T. Mashiko, Z. Hou, Chem. Commun. 2007, 4137; – reference: M. Mizutani, E. F. Palermo, L. M. Thoma, K. Satoh, M. Kamigaito, K. Kuroda, Biomacromolecules 2012, 13, 1554; – reference: T. Yokozawa, Y. Ohta, Chem. Commun. 2013, 49, 8281; – reference: M. Mizuntani, K. Satoh, M. Kamigaito, Macromolecules 2011, 44, 2382; – reference: T. Kawamura, T. Uryu, K. Matsuzaki, Makromol. Chem. 1982, 183, 125; – reference: M. Uchiyama, K. Satoh, M. Kamigaito, Polym. Chem. 2016, 7, 1387; – reference: L. Pan, K. Zhang, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 2011, 50, 12012; – reference: H. Zhang, Y. Luo, Z. Hou, Macromolecules 2008, 41, 1064; – reference: J. Oyamada, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 2011, 50, 10720; – reference: G. Natta, G. Dall'Asta, G. Mazzanti, A. Casale, Makromol. Chem. 1962, 58, 217; – reference: X. Zhang, H. Dou, Z. Zhang, W. Zhang, X. Zhu, J. Zhu, J. Polym. Sci. Part A 2013, 51, 3907; – reference: Angew. Chem. 2015, 127, 5294; – reference: F. Guo, M. Nishiura, H. Koshino, Z. Hou, Macromolecules 2011, 44, 6335; – reference: P. De, R. Faust, Macromolecules 2004, 37, 7930; – reference: K. Kojima, M. Sawamoto, T. Higashimura, Macromolecules 1990, 23, 948; – reference: A. J. Perkowski, W. You, D. A. Nicewicz, J. Am. Chem. Soc. 2015, 137, 7580; – reference: E. S. Wilks, Prog. Polym. Sci. 2000, 25, 9; – reference: Angew. Chem. 2011, 123, 12218; – reference: Angew. Chem. 2011, 123, 10908. – reference: X. Li, Z. Hou, Macromolecules 2010, 43, 8904; – reference: K. Nakatani, M. Ouchi, M. Sawamoto, Macromolecules 2008, 41, 4579. – reference: M. Mizutani, K. Satoh, M. Kamigaito, J. Am. Chem. Soc. 2010, 132, 7498; – reference: T. Yokozawa, Y. Ohta, Chem. Rev. 2016, 116, 1950. – reference: Y. Luo, J. Baldamus, Z. Hou, J. Am. Chem. Soc. 2004, 126, 13910; – reference: X. Shi, M. Nishiura, Z. Hou, J. Am. Chem. Soc. 2016, 138, 6147. – reference: Angew. Chem. 2012, 124, 13000. – volume: 51 start-page: 3907 year: 2013 publication-title: J. Polym. Sci. Part A – volume: 13 start-page: 1554 year: 2012 publication-title: Biomacromolecules – volume: 49 start-page: 71 year: 2016 publication-title: Macromolecules – volume: 58 start-page: 217 year: 1962 publication-title: Makromol. Chem. – volume: 50 123 start-page: 10720 10908 year: 2011 2011 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 44 start-page: 6335 year: 2011 publication-title: Macromolecules – volume: 138 start-page: 6147 year: 2016 publication-title: J. Am. Chem. Soc. – volume: 183 start-page: 125 year: 1982 publication-title: Makromol. Chem. – start-page: 4137 year: 2007 publication-title: Chem. Commun. – volume: 41 start-page: 1064 year: 2008 publication-title: Macromolecules – volume: 132 start-page: 7498 year: 2010 publication-title: J. Am. Chem. Soc. – volume: 41 start-page: 4579 year: 2008 publication-title: Macromolecules – volume: 23 start-page: 948 year: 1990 publication-title: Macromolecules – volume: 44 start-page: 2382 year: 2011 publication-title: Macromolecules – volume: 49 start-page: 8281 year: 2013 publication-title: Chem. Commun. – volume: 7 start-page: 1933 year: 1969 publication-title: J. Polym. Sci. Part A-1 – volume: 43 start-page: 8904 year: 2010 publication-title: Macromolecules – volume: 51 124 start-page: 12828 13000 year: 2012 2012 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 37 start-page: 7930 year: 2004 publication-title: Macromolecules – volume: 137 start-page: 7580 year: 2015 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 2209 year: 2015 publication-title: Acc. Chem. Res. – volume: 25 start-page: 9 year: 2000 publication-title: Prog. Polym. Sci. – volume: 116 start-page: 1950 year: 2016 publication-title: Chem. Rev. – volume: 2 start-page: 257 year: 2010 publication-title: Nat. Chem. – volume: 126 start-page: 13910 year: 2004 publication-title: J. Am. Chem. Soc. – volume: 51 start-page: 4685 year: 2015 publication-title: Chem. Commun. – year: 2004 – volume: 22 start-page: 104 year: 1989 publication-title: Macromolecules – volume: 40 start-page: 482 year: 2007 publication-title: Macromolecules – volume: 54 127 start-page: 5205 5294 year: 2015 2015 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 49 start-page: 2458 year: 2016 publication-title: Macromolecules – volume: 45 start-page: 7749 year: 2012 publication-title: Macromolecules – volume: 30 start-page: 2513 year: 2011 publication-title: Organometallics – volume: 44 start-page: 2400 year: 2011 publication-title: Macromolecules – volume: 7 start-page: 1387 year: 2016 publication-title: Polym. Chem. – volume: 50 123 start-page: 12012 12218 year: 2011 2011 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – ident: e_1_2_2_14_2 doi: 10.1021/ma062261k – ident: e_1_2_2_40_1 – ident: e_1_2_2_9_2 doi: 10.1039/c3cc43603a – ident: e_1_2_2_45_1 doi: 10.1002/anie.201105636 – ident: e_1_2_2_12_2 doi: 10.1021/ma00206a008 – ident: e_1_2_2_39_1 doi: 10.1021/jacs.6b03859 – ident: e_1_2_2_7_2 doi: 10.1021/bm300254s – ident: e_1_2_2_31_1 – ident: e_1_2_2_16_2 doi: 10.1021/jacs.5b03733 – ident: e_1_2_2_26_2 doi: 10.1039/C5CC00470E – ident: e_1_2_2_4_1 – ident: e_1_2_2_28_1 – ident: e_1_2_2_42_2 doi: 10.1021/om1012055 – ident: e_1_2_2_13_2 doi: 10.1021/ma0490451 – ident: e_1_2_2_43_2 – ident: e_1_2_2_11_1 – ident: e_1_2_2_38_2 doi: 10.1021/acs.macromol.6b00083 – ident: e_1_2_2_17_2 doi: 10.1039/C5PY01879J – ident: e_1_2_2_44_1 doi: 10.1002/anie.201206233 – ident: e_1_2_2_25_3 doi: 10.1002/ange.201412166 – ident: e_1_2_2_27_2 doi: 10.1021/ma00191a021 – volume-title: Plastics Packaging: Properties, Processing, Applications, and Regulations, year: 2004 ident: e_1_2_2_3_2 – ident: e_1_2_2_15_2 doi: 10.1021/ma301505j – ident: e_1_2_2_6_2 doi: 10.1021/ma2000465 – ident: e_1_2_2_23_2 doi: 10.1021/ma800810m – ident: e_1_2_2_1_1 – ident: e_1_2_2_37_2 doi: 10.1002/anie.201104011 – ident: e_1_2_2_2_2 doi: 10.1016/S0079-6700(00)00007-1 – ident: e_1_2_2_35_2 doi: 10.1021/ma200441w – ident: e_1_2_2_44_2 doi: 10.1002/ange.201206233 – ident: e_1_2_2_19_1 doi: 10.1002/pol.1969.150070732 – ident: e_1_2_2_25_2 doi: 10.1002/anie.201412166 – ident: e_1_2_2_5_2 doi: 10.1021/ja1023892 – ident: e_1_2_2_21_2 doi: 10.1002/macp.1962.020580115 – ident: e_1_2_2_20_1 – ident: e_1_2_2_29_2 doi: 10.1038/nchem.595 – ident: e_1_2_2_8_2 doi: 10.1002/pola.26792 – ident: e_1_2_2_22_2 doi: 10.1002/macp.1982.021830111 – ident: e_1_2_2_30_2 doi: 10.1021/acs.accounts.5b00219 – ident: e_1_2_2_37_3 doi: 10.1002/ange.201104011 – ident: e_1_2_2_45_2 doi: 10.1002/ange.201105636 – ident: e_1_2_2_34_2 doi: 10.1021/ma101835e – ident: e_1_2_2_36_2 doi: 10.1021/ma201271r – ident: e_1_2_2_10_2 doi: 10.1021/acs.chemrev.5b00393 – ident: e_1_2_2_32_2 doi: 10.1021/ja046063p – ident: e_1_2_2_33_2 doi: 10.1021/ma7027006 – ident: e_1_2_2_18_2 doi: 10.1021/acs.macromol.5b02223 – ident: e_1_2_2_24_1 – ident: e_1_2_2_41_2 doi: 10.1039/b708534f – volume: 132 start-page: 7498 year: 2010 ident: WOS:000278190600052 article-title: Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization: Marriage of Vinyl Polymers and Polyesters publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja1023892 – volume: 40 start-page: 482 year: 2007 ident: WOS:000243839700014 article-title: Controlled/living cationic polymerization of p-methoxystyrene in solution and aqueous dispersion using tris(pentafluorophenyl)borane as a Lewis acid:: Acetonitrile does the job publication-title: MACROMOLECULES doi: 10.1021/ma062261k – volume: 126 start-page: 13910 year: 2004 ident: WOS:000224873600017 article-title: Scandium half-metallocene-catalyzed syndiospecific styrene polymerization and styrene-ethylene copolymerization: Unprecedented incorporation of syndiotactic styrene-styrene sequences in styrene-ethylene copolymers publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja046063p – volume: 54 start-page: 5205 year: 2015 ident: WOS:000354190800042 article-title: Highly Isoselective Coordination Polymerization of ortho-Methoxystyrene with β-Diketiminato Rare-Earth-Metal Precursors publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201412166 – volume: 183 start-page: 125 year: 1982 ident: WOS:A1982NC54200011 article-title: STEREOREGULARITY OF POLYSTYRENE DERIVATIVES .1. POLY(METHYLSTYRENE)S AND POLY(METHOXYSTYRENE)S OBTAINED WITH ZIEGLER CATALYST, CATIONIC CATALYST, OR RADICAL INITIATORS publication-title: MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS – volume: 13 start-page: 1554 year: 2012 ident: WOS:000303951600037 article-title: Design and Synthesis of Self-Degradable Antibacterial Polymers by Simultaneous Chain- and Step-Growth Radical Copolymerization publication-title: BIOMACROMOLECULES doi: 10.1021/bm300254s – start-page: 4137 year: 2007 ident: WOS:000250085500017 article-title: Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/b708534f – volume: 44 start-page: 6335 year: 2011 ident: WOS:000294076300014 article-title: Scandium-Catalyzed Cyclocopolymerization of 1,5-Hexadiene with Styrene and Ethylene: Efficient Synthesis of Cyclopolyolefins Containing Syndiotactic Styrene-Styrene Sequences and Methylene-1,3-cyclopentane Units publication-title: MACROMOLECULES doi: 10.1021/ma201271r – volume: 7 start-page: 1387 year: 2016 ident: WOS:000369692700004 article-title: A phosphonium intermediate for cationic RAFT polymerization publication-title: POLYMER CHEMISTRY doi: 10.1039/c5py01879j – volume: 37 start-page: 7930 year: 2004 ident: WOS:000224472500014 article-title: Living carbocationic polymerization of p-methoxystyrene using p-methoxystyrene hydrochloride/SnBr4 initiating system:: Determination of the absolute rate constant of propagation for ion pairs publication-title: MACROMOLECULES doi: 10.1021/ma0490451 – volume: 50 start-page: 12012 year: 2011 ident: WOS:000298085000030 article-title: Chain-Shuttling Polymerization at Two Different Scandium Sites: Regio- and Stereospecific "One-Pot" Block Copolymerization of Styrene, Isoprene, and Butadiene publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201104011 – volume: 7 start-page: 1933 year: 1969 ident: WOS:A1969E134500032 article-title: STEREOSPECIFIC POLYMERIZATION OF OMICRON-METHOXYSTYRENE BY ANIONIC INITIATORS publication-title: JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY – volume: 58 start-page: 217 year: 1962 ident: WOS:A1962WX81200015 article-title: STEREOSPECIFICITY IN THE CATIONIC CO-ORDINATED POLYMERIZATION OF METHOXYSTYRENES publication-title: MAKROMOLEKULARE CHEMIE – volume: 50 start-page: 10720 year: 2011 ident: WOS:000297175600046 article-title: Scandium-Catalyzed Silylation of Aromatic C-H Bonds publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201105636 – volume: 23 start-page: 948 year: 1990 ident: WOS:A1990CP85700008 article-title: LIVING CATIONIC POLYMERIZATION OF P-METHOXYSTYRENE BY THE HI/ZNI2 AND HI/I2 INITIATING SYSTEMS - EFFECTS OF TETRABUTYLAMMONIUM HALIDES IN A POLAR-SOLVENT publication-title: MACROMOLECULES – volume: 138 start-page: 6147 year: 2016 ident: WOS:000376331000015 article-title: C-H Polyaddition of Dimethoxyarenes to Unconjugated Dienes by Rare Earth Catalysts publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b03859 – volume: 41 start-page: 1064 year: 2008 ident: WOS:000253331200004 article-title: Scandium-catalyzed syndiospecific copolymerization of styrene with isoprene publication-title: MACROMOLECULES doi: 10.1021/ma7027006 – volume: 25 start-page: 9 year: 2000 ident: WOS:000087633800003 article-title: Polymer nomenclature: the controversy between source-based and structure-based representations (a personal perspective) publication-title: PROGRESS IN POLYMER SCIENCE – volume: 45 start-page: 7749 year: 2012 ident: WOS:000309505500010 article-title: Structure Effects of Lewis Acids on the Living Cationic Polymerization of p-Methoxystyrene: Distinct Difference in Polymerization Behavior from Vinyl Ethers publication-title: MACROMOLECULES doi: 10.1021/ma301505j – volume: 49 start-page: 8281 year: 2013 ident: WOS:000323519200001 article-title: Scope of controlled synthesis via chain-growth condensation polymerization: from aromatic polyamides to π-conjugated polymers publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c3cc43603a – volume: 2 start-page: 257 year: 2010 ident: WOS:000275928300011 article-title: Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls publication-title: NATURE CHEMISTRY doi: 10.1038/nchem.595 – volume: 116 start-page: 1950 year: 2016 ident: WOS:000371106000006 article-title: Transformation of Step-Growth Polymerization into Living Chain-Growth Polymerization publication-title: CHEMICAL REVIEWS doi: 10.1021/acs.chemrev.5b00393 – volume: 51 start-page: 3907 year: 2013 ident: WOS:000322656500016 article-title: Fast and effective copper(0)-mediated simultaneous chain- and step-growth radical polymerization at ambient temperature publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.26792 – volume: 123 start-page: 12218 year: 2011 ident: 000388252700060.26 publication-title: Angew. Chem. – volume: 43 start-page: 8904 year: 2010 ident: WOS:000283693500028 article-title: Scandium-Catalyzed Regio- and Stereospecific cis-1,4-Polymerization of 1,3-Cyclohexadiene and Copolymerization with Ethylene publication-title: MACROMOLECULES doi: 10.1021/ma101835e – volume: 44 start-page: 2382 year: 2011 ident: WOS:000289028500085 article-title: Degradable Poly(N-isopropylacrylamide) with Tunable Thermosensitivity by Simultaneous Chain- and Step-Growth Radical Polymerization publication-title: MACROMOLECULES doi: 10.1021/ma2000465 – volume: 51 start-page: 4685 year: 2015 ident: WOS:000350486300034 article-title: Syndioselective coordination polymerization of unmasked polar methoxystyrenes using a pyridenylmethylene fluorenyl yttrium precursor publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c5cc00470e – volume: 41 start-page: 4579 year: 2008 ident: WOS:000257366200010 article-title: Terminal umpolung in metal-catalyzed living radical polymerization: Quantitative end-capping of carbon-halogen bond via a modifier monomer publication-title: MACROMOLECULES doi: 10.1021/ma800810m – volume: 49 start-page: 2458 year: 2016 ident: WOS:000374195600006 article-title: Scandium-Catalyzed Syndiospecific Chain-Transfer Polymerization of Styrene Using Anisoles as a Chain Transfer Agent publication-title: MACROMOLECULES doi: 10.1021/acs.macromol.6b00083 – volume: 49 start-page: 71 year: 2016 ident: WOS:000368322000009 article-title: Quantitative and Ultrafast Synthesis of Well-Defined Star-Shaped Poly(p-methoxystyrene) via One-Pot Living Cationic Polymerization publication-title: MACROMOLECULES doi: 10.1021/acs.macromol.5b02223 – volume: 127 start-page: 5294 year: 2015 ident: 000388252700060.13 publication-title: Angew. Chem. – volume: 137 start-page: 7580 year: 2015 ident: WOS:000357062000010 article-title: Visible Light Photoinitiated Metal-Free Living Cationic Polymerization of 4-Methoxystyrene publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.5b03733 – volume: 30 start-page: 2513 year: 2011 ident: WOS:000290001900010 article-title: Tetra-, Penta-, and Hexanuclear Yttrium Hydride Clusters from Half-Sandwich Bis(anninobenzyl) Complexes Containing Various Cyclopentadienyl Ligands publication-title: ORGANOMETALLICS doi: 10.1021/om1012055 – volume: 124 start-page: 13000 year: 2012 ident: 000388252700060.24 publication-title: Angew. Chem. – year: 2004 ident: 000388252700060.29 publication-title: Plastics Packaging: Properties, Processing, Applications, and Regulations – volume: 51 start-page: 12828 year: 2012 ident: WOS:000312305400035 article-title: Regioselective C?H Alkylation of Anisoles with Olefins Catalyzed by Cationic Half-Sandwich Rare Earth Alkyl Complexes publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201206233 – volume: 48 start-page: 2209 year: 2015 ident: WOS:000359892700006 article-title: Half-Sandwich Rare-Earth-Catalyzed Olefin Polymerization, Carbometalation, and Hydroarylation publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/acs.accounts.5b00219 – volume: 44 start-page: 2400 year: 2011 ident: WOS:000289593200002 article-title: Cycloterpolymerization of 1,6-Heptadiene with Ethylene and Styrene Catalyzed by a THF-Free Half-Sandwich Scandium Complex publication-title: MACROMOLECULES doi: 10.1021/ma200441w – volume: 123 start-page: 10908 year: 2011 ident: 000388252700060.22 publication-title: Angew. Chem. – volume: 22 start-page: 104 year: 1989 ident: WOS:A1989R898500021 article-title: REACTIVITY OF SOME SUBSTITUTED STYRENES IN THE PRESENCE OF A SYNDIOTACTIC SPECIFIC POLYMERIZATION CATALYST publication-title: MACROMOLECULES
SSID	ssj0028806
Score	2.49727
Snippet	The simultaneous chain‐growth and step‐growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules... The simultaneous chain-growth and step-growth polymerization of a monomer is of great interest and importance because it can produce unique macromolecules...
Source	Web of Science
SourceID	proquest pubmed webofscience crossref wiley istex
SourceType	Aggregation Database Index Database Enrichment Source Publisher
StartPage	14812
SubjectTerms	Addition polymerization Anisole Catalysts Chains (polymeric) Chemistry Chemistry, Multidisciplinary Condensation polymerization C−H activation Earth Ethylene gadolinium Insertion Macromolecules Molecular weight Physical Sciences Polydispersity Polymerization Rare earth elements rare-earth metals Reaction mechanisms Science & Technology Syndiotacticity
Title	Simultaneous Chain-Growth and Step-Growth Polymerization of Methoxystyrenes by Rare-Earth Catalysts
URI	https://api.istex.fr/ark:/67375/WNG-NK8KC87V-S/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201609065 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000388252700060 https://www.ncbi.nlm.nih.gov/pubmed/27774727 https://www.proquest.com/docview/1844744794 https://www.proquest.com/docview/1906089795 https://www.proquest.com/docview/1835508340
Volume	55
WOS	000388252700060
WOSCitedRecordID	wos000388252700060
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwELZQOcAFyju0ICNVcEqbOE6cHKto20LVFWop9GY5fmhXrbJok5W6nPgJ_EZ-CTN5tVsVgeC2WdtxPDMef7bnQchWmKC7ZKF84QIFGxTLfMDJzteOa6dBSHhjPH40Tg5O-Yez-OyaF38bH2I4cMOZ0ehrnOCqqHaugoaiBzaaZiVBBssoKGE02EJUdDzEj2IgnK17URT5mIW-j9oYsJ3V5iur0l0k8OVtkPPG6rQKaJsVae8hUf1YWkOU8-1FXWzrbzfCPP7PYNfJgw6u0t1Wvh6RO7Z8TO7lfZa4J2R6MkWbRFXa2aKi-URNy5_ff-zD5r6eUFUaimZkV_98nF0s8Y6odf6kM0ePMIX15bLC03BQu7RY0mM1t9BkBFI9oTmeL0Fx9ZSc7o0-5Qd-l77B1zEwGditnUl5mujQOKazSAE65KFIXep0loRJEYc2K2wSRbEyLktNYUykNDfCxVYl0TOyVs5K-4JQTI0mjHVWCcOVESB4irEi4hpUSmICj_g9-6TuYptjio0L2UZlZhIJKAcCeuTdUP9rG9XjtzXfNtIwVFPzc7SFE7H8Mt6X48P0ME_FZ3nikc1eXGSnBioJ22cuOAbxv70YegjSTGTQzZuhGBiIlzYt4-AVgAgBJ3MY5PNWCodvYQLAOwBQj2xdF8uhvLn3TVmMxgXQk0fCv6mWdwTEoAi1R1gjl38gk9wdvx8NTy__pdEGuY-_0c8z5JtkrZ4v7CsAfHXxupnUvwDtjE87
linkProvider	Wiley-Blackwell
linkToHtml	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwELagPZQLb0qgQJAqOKVNHCdOjlXYdst2I9QHcLMcP7SrVlm0m5W6nPgJ_EZ-CTPJJmWrIhAcE9txPB7bn-2ZbwjZDmJ0lyykx60vYYNiqAc42XrKMmUVKAmrjceHedw_Y-8_R601IfrCNPwQ3YEbjox6vsYBjgfSu1esoeiCjbZZsZ_COnqbrGNYb6TPf3fcMUhRUM_GwSgMPYxD3_I2-nR3tfzKurSOIr68CXReW59WIW29Ju3fI0XbmsYU5XxnXhU76us1osf_au59cneJWN29RsUekFumfEg2sjZQ3CMyPhmjWaIszWQ-c7ORHJc_vn0_gP19NXJlqV20JLt682FyscBrosb_051Yd4hRrC8XMzwQh5nXLRbusZwaKNIDxR65GR4xQfLsMTnb751mfW8ZwcFTEfQz9LiyOmFJrAJtqUpDCQCRBTyxiVVpHMRFFJi0MHEYRlLbNNGF1qFUTHMbGRmHT8haOSnNU-JidDSujTWSayY1B92TlBYhUzCrxNp3iNf2n1BLenOMsnEhGmJmKlCAohOgQ952-b80xB6_zfmmVocum5yeozkcj8Sn_EDkg2SQJfyjOHHIVqsvYjkTzATsoBlnyON_czLU4CcpT6Ga110ydCDe2zQdB58AUAhQmUEjNxs17P6FcsDvgEEdsv2rXnbp9dVvQiO0L4CaHBL8TbZsKUDkRagcQmvF_IOYxF5-2Ouenv1LoVdko386PBJHh_ngObmD79HtM2BbZK2azs0LwH9V8bIe4T8BuDhTVw
linkToPdf	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwELaglYAL70KggJEqOKXNw4mTYxV227I0qloKvVmOH9pVq2y1D6nLiZ_Ab-SXMJNXu1URCG7Z2I7X47H92Z75hpANP0Z3yUK63HoSNigmcAEnW1dZpqwCJWGV8fh-Hu8es48n0ckVL_6aH6I7cMORUc3XOMDPtd26JA1FD2w0zYq9FJbR22SV4RPCosOOQCoA7az9i8LQxTD0LW2jF2wtl19allZRwhc3Yc5ry9Myoq2WpP4DItvG1JYop5vzWbGpvl3jefyf1j4k9xu8SrdrBXtEbpnyMbmbtWHinpDR0QiNEmVpxvMpzYZyVP78_mMHdvezIZWlpmhHdvnmYHy2wEui2vuTji3dxxjWF4spHofDvEuLBT2UEwNFeqDWQ5rhARMkT5-S437vc7brNvEbXBVBL0N_K6sTlsTK1zZQaSgBHjKfJzaxKo39uIh8kxYmDsNIapsmutA6lIppbiMj43CNrJTj0jwnFGOjcW2skVwzqTlongyCImQK5pRYew5x2-4TqiE3xxgbZ6KmZQ4EClB0AnTI-y7_eU3r8duc7ypt6LLJySkaw_FIfM13RD5IBlnCv4gjh6y36iKaeWAqYP_MOEMW_5uToQYvSXkK1bztkqED8dam7jj4BEBCAMoMGvms1sLuvwQc0DsgUIdsXFXLLr26-E2CCK0LoCaH-H-TLWsEiKwIM4cElV7-QUxiO9_rdb9e_EuhN-TOwYe--LSXD16Se_gafT59tk5WZpO5eQXgb1a8rsb3L3xFUgY
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Simultaneous+Chain-Growth+and+Step-Growth+Polymerization+of+Methoxystyrenes+by+Rare-Earth+Catalysts&rft.jtitle=Angewandte+Chemie+International+Edition&rft.au=Shi%2C+Xiaochao&rft.au=Nishiura%2C+Masayoshi&rft.au=Hou%2C+Zhaomin&rft.date=2016-11-14&rft.pub=Wiley+Subscription+Services%2C+Inc&rft.issn=1433-7851&rft.eissn=1521-3773&rft.volume=55&rft.issue=47&rft.spage=14812&rft_id=info:doi/10.1002%2Fanie.201609065&rft.externalDBID=NO_FULL_TEXT
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1433-7851&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1433-7851&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1433-7851&client=summon