Robust links in photoactive covalent organic frameworks enable effective photocatalytic reactions under harsh conditions

• Published in: Nature communications Vol. 15; no. 1; pp. 1267 - 17
• Main Authors: Wang, Jia-Rui, Song, Kepeng, Luan, Tian-Xiang, Cheng, Ke, Wang, Qiurong, Wang, Yue, Yu, William W., Li, Pei-Zhou, Zhao, Yanli
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 10.02.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 140/131; 140/146; 147/135; 147/143; 639/301/299/1013; 639/301/923/3931; 639/638/298/923/1028; Catalysts; Catalytic activity; Covalence; Decarboxylation; Humanities and Social Sciences; Hydrogen peroxide; Linkages; multidisciplinary; Organic acids; Photocatalysis; Photocatalysts; Photosensitivity; Quinoline; Robustness; Science; Science (multidisciplinary)

Developing heterogeneous photocatalysts for the applications in harsh conditions is of high importance but challenging. Herein, by converting the imine linkages into quinoline groups of triphenylamine incorporated covalent organic frameworks (COFs), two photosensitive COFs, namely TFPA-TAPT-COF-Q an...