Rearrangements of organic peroxides and related processes

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the...

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Published inBeilstein journal of organic chemistry Vol. 12; no. 1; pp. 1647 - 1748
Main Authors Yaremenko, Ivan A, Vil’, Vera A, Demchuk, Dmitry V, Terent’ev, Alexander O
Format Journal Article
LanguageEnglish
Published Germany Beilstein-Institut zur Föerderung der Chemischen Wissenschaften 03.08.2016
Beilstein-Institut
Subjects
artemisinin
Baeyer−Villiger
Chemistry
Criegee
Hock
peroxide
rearrangement
Review
artemisinin
peroxide
Baeyer−Villiger
Criegee
Hock
rearrangement
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Summary:This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.
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ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.12.162