Multi-compartmental MOF microreactors derived from Pickering double emulsions for chemo-enzymatic cascade catalysis

• Published in: Nature communications Vol. 14; no. 1; pp. 3226 - 14
• Main Authors: Tian, Danping, Hao, Ruipeng, Zhang, Xiaoming, Shi, Hu, Wang, Yuwei, Liang, Linfeng, Liu, Haichao, Yang, Hengquan
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 03.06.2023; Nature Publishing Group; Nature Portfolio
• Subjects: 639/638/298/921; 639/638/77/603; 639/638/77/887; Cascade chemical reactions; Catalysis; Catalysts; Cellular structure; Contact angle; Controllability; Double emulsions; Efficiency; Emulsions; Engineering; Enzymes; Fabrication; Glucose oxidase; Glucose Oxidase - chemistry; Humanities and Social Sciences; Hydrophobicity; Inactivation; Laboratories; Lipase - metabolism; Metabolic engineering; Metabolism; Metal-organic frameworks; Metathesis; Microreactors; multidisciplinary; Nanoparticles; Oxidation; Oxidation-Reduction; Permeability; Porous materials; Porphyrins; Science; Science (multidisciplinary); Substrates; Synthesis; Transesterification

Bioinspired multi-compartment architectures are desired in synthetic biology and metabolic engineering, as credited by their cell-like structures and intrinsic ability of assembling catalytic species for spatiotemporal control over cascade reactions like in living systems. Herein, we describe a gene...