Preparation of polypropylene/high‐melt‐strength PP open‐cell foam for oil absorption
Oil spills not only cause significant economic losses; they also harm the environment. In this study, high‐melt‐strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical CO2 at various temperatures and pressures to develop open‐cell...
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| Published in | Polymer engineering and science Vol. 61; no. 4; pp. 1139 - 1149 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken, USA
John Wiley & Sons, Inc
01.04.2021
Society of Plastics Engineers, Inc Blackwell Publishing Ltd |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0032-3888 1548-2634 |
| DOI | 10.1002/pen.25654 |
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| Abstract | Oil spills not only cause significant economic losses; they also harm the environment. In this study, high‐melt‐strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical CO2 at various temperatures and pressures to develop open‐cell foams for oil absorption applications. The experimental results show that adding HMSPP increased the foam expansion ratio and the open‐cell content and that the foam processing window widened with increasing HMSPP content. The oil absorption experiment results show that the amount of oil absorption increased with the foam expansion ratio and that low oil viscosity resulted in high oil absorption. In addition, the amount of oil absorption remained unchanged after 10 cycles of oil absorption experiments. The oil absorption kinetics study shows that the oil absorption process complied with the pseudo‐second‐order law. |
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| AbstractList | Oil spills not only cause significant economic losses; they also harm the environment. In this study, high‐melt‐strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical CO
2
at various temperatures and pressures to develop open‐cell foams for oil absorption applications. The experimental results show that adding HMSPP increased the foam expansion ratio and the open‐cell content and that the foam processing window widened with increasing HMSPP content. The oil absorption experiment results show that the amount of oil absorption increased with the foam expansion ratio and that low oil viscosity resulted in high oil absorption. In addition, the amount of oil absorption remained unchanged after 10 cycles of oil absorption experiments. The oil absorption kinetics study shows that the oil absorption process complied with the pseudo‐second‐order law. Oil spills not only cause significant economic losses; they also harm the environment. In this study, high-melt-strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical C[O.sub.2] at various temperatures and pressures to develop open-cell foams for oil absorption applications. The experimental results show that adding HMSPP increased the foam expansion ratio and the open-cell content and that the foam processing window widened with increasing HMSPP content. The oil absorption experiment results show that the amount of oil absorption increased with the foam expansion ratio and that low oil viscosity resulted in high oil absorption. In addition, the amount of oil absorption remained unchanged after 10 cycles of oil absorption experiments. The oil absorption kinetics study shows that the oil absorption process complied with the pseudosecond-order law. Oil spills not only cause significant economic losses; they also harm the environment. In this study, high-melt-strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical C[O.sub.2] at various temperatures and pressures to develop open-cell foams for oil absorption applications. The experimental results show that adding HMSPP increased the foam expansion ratio and the open-cell content and that the foam processing window widened with increasing HMSPP content. The oil absorption experiment results show that the amount of oil absorption increased with the foam expansion ratio and that low oil viscosity resulted in high oil absorption. In addition, the amount of oil absorption remained unchanged after 10 cycles of oil absorption experiments. The oil absorption kinetics study shows that the oil absorption process complied with the pseudosecond-order law. KEYWORDS blending, foams, polypropylene, rheology Oil spills not only cause significant economic losses; they also harm the environment. In this study, high‐melt‐strength polypropylene (HMSPP) and linear polypropylene (PP) were compounded at different ratios and foamed by supercritical CO2 at various temperatures and pressures to develop open‐cell foams for oil absorption applications. The experimental results show that adding HMSPP increased the foam expansion ratio and the open‐cell content and that the foam processing window widened with increasing HMSPP content. The oil absorption experiment results show that the amount of oil absorption increased with the foam expansion ratio and that low oil viscosity resulted in high oil absorption. In addition, the amount of oil absorption remained unchanged after 10 cycles of oil absorption experiments. The oil absorption kinetics study shows that the oil absorption process complied with the pseudo‐second‐order law. |
| Audience | Academic |
| Author | Gebremedhin, Kiday Fiseha Tsai, Yi‐Bei Chang, Rong‐Yu Chien, Tse‐Yu Yeh, Shu‐Kai Tung, Kuo‐Lun |
| Author_xml | – sequence: 1 givenname: Shu‐Kai orcidid: 0000-0002-9131-5133 surname: Yeh fullname: Yeh, Shu‐Kai email: skyeh@mail.ntust.edu.tw organization: National Taiwan University of Science and Technology, Taiwan, Republic of China – sequence: 2 givenname: Yi‐Bei surname: Tsai fullname: Tsai, Yi‐Bei organization: National Taiwan University of Science and Technology, Taiwan, Republic of China – sequence: 3 givenname: Kiday Fiseha surname: Gebremedhin fullname: Gebremedhin, Kiday Fiseha organization: National Taiwan University of Science and Technology, Taiwan, Republic of China – sequence: 4 givenname: Tse‐Yu surname: Chien fullname: Chien, Tse‐Yu organization: CoreTech System (Moldex3D) Co., Ltd., Taiwan, Republic of China – sequence: 5 givenname: Rong‐Yu surname: Chang fullname: Chang, Rong‐Yu organization: CoreTech System (Moldex3D) Co., Ltd., Taiwan, Republic of China – sequence: 6 givenname: Kuo‐Lun surname: Tung fullname: Tung, Kuo‐Lun organization: National Taiwan University, Taiwan, Republic of China |
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| Snippet | Oil spills not only cause significant economic losses; they also harm the environment. In this study, high‐melt‐strength polypropylene (HMSPP) and linear... Oil spills not only cause significant economic losses; they also harm the environment. In this study, high-melt-strength polypropylene (HMSPP) and linear... |
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| SubjectTerms | Absorption blending Chemical properties Economic impact foams Oil spills Plastic foam Plastic foams Polypropylene Production processes rheology |
| Title | Preparation of polypropylene/high‐melt‐strength PP open‐cell foam for oil absorption |
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