Raman spectroscopy — Useful tool for studying the catalysts derived from Mo and V-oxyanion-intercalated layered double hydroxides
Layered double hydroxides with Me-based oxyanions (MeMo, V) in the interlayer gallery were prepared by ion exchange and used as efficient catalysts for the mild oxidation of organic sulfides with H2O2. Raman spectroscopy was used as the main and very efficient technique for the advanced characteriza...
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| Published in | Applied clay science Vol. 104; pp. 205 - 210 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.02.2015
Elsevier |
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| Abstract | Layered double hydroxides with Me-based oxyanions (MeMo, V) in the interlayer gallery were prepared by ion exchange and used as efficient catalysts for the mild oxidation of organic sulfides with H2O2. Raman spectroscopy was used as the main and very efficient technique for the advanced characterization of these materials during their preparation and catalytic use. First, it served for monitoring the progression of the ion exchange during the preparation of the catalysts, and then the Raman spectroscopy provided precise information regarding the type of the oxyanions located in the catalyst structure, before and after the oxidation reaction.
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•Raman spectroscopy was used for characterizing LDH containing Mo- and V-oxyanions•These materials are good catalysts for the mild oxidation of thiophenes with H2O2•Mo-LDH were stables catalysts, while the V-LDH suffered major modifications |
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| AbstractList | Layered double hydroxides with Me-based oxyanions (Medouble bond; length as m-dashMo, V) in the interlayer gallery were prepared by ion exchange and used as efficient catalysts for the mild oxidation of organic sulfides with H sub(2)O sub(2). Raman spectroscopy was used as the main and very efficient technique for the advanced characterization of these materials during their preparation and catalytic use. First, it served for monitoring the progression of the ion exchange during the preparation of the catalysts, and then the Raman spectroscopy provided precise information regarding the type of the oxyanions located in the catalyst structure, before and after the oxidation reaction. Layered double hydroxideswithMe-based oxyanions (Me_Mo, V) in the interlayer gallerywere prepared by ionexchange and used as efficient catalysts for the mild oxidation of organic sulfideswith H2O2. Raman spectroscopywas used as the main and very efficient technique for the advanced characterization of these materials duringtheir preparation and catalytic use. First, it served for monitoring the progression of the ion exchange duringthe preparation of the catalysts, and then the Raman spectroscopy provided precise information regarding thetype of the oxyanions located in the catalyst structure, before and after the oxidation reaction. Layered double hydroxides with Me-based oxyanions (MeMo, V) in the interlayer gallery were prepared by ion exchange and used as efficient catalysts for the mild oxidation of organic sulfides with H2O2. Raman spectroscopy was used as the main and very efficient technique for the advanced characterization of these materials during their preparation and catalytic use. First, it served for monitoring the progression of the ion exchange during the preparation of the catalysts, and then the Raman spectroscopy provided precise information regarding the type of the oxyanions located in the catalyst structure, before and after the oxidation reaction. [Display omitted] •Raman spectroscopy was used for characterizing LDH containing Mo- and V-oxyanions•These materials are good catalysts for the mild oxidation of thiophenes with H2O2•Mo-LDH were stables catalysts, while the V-LDH suffered major modifications |
| Author | Popa, Marcel Ionel Petit, Eddy Ciocan, Cristina Elena Dobrea, Iuliana Daniela Dumitriu, Emil Hulea, Vasile |
| Author_xml | – sequence: 1 givenname: Iuliana Daniela surname: Dobrea fullname: Dobrea, Iuliana Daniela organization: Institut Charles Gerhardt, UMR 5253, CNRS-UM2-ENSCM-UM1, Matériaux Avancés pour la Catalyse et la Santé, 8 rue de l'Ecole Normale, 34 296 Cedex 5, Montpellier, France – sequence: 2 givenname: Cristina Elena surname: Ciocan fullname: Ciocan, Cristina Elena organization: Institut Charles Gerhardt, UMR 5253, CNRS-UM2-ENSCM-UM1, Matériaux Avancés pour la Catalyse et la Santé, 8 rue de l'Ecole Normale, 34 296 Cedex 5, Montpellier, France – sequence: 3 givenname: Emil surname: Dumitriu fullname: Dumitriu, Emil organization: Technical University “Gh. Asachi”, Faculty of Chemical Engineering and Environmental Protection, 70A, Prof. D. Mangeron Bvd, Iasi, Romania – sequence: 4 givenname: Marcel Ionel surname: Popa fullname: Popa, Marcel Ionel organization: Technical University “Gh. Asachi”, Faculty of Chemical Engineering and Environmental Protection, 70A, Prof. D. Mangeron Bvd, Iasi, Romania – sequence: 5 givenname: Eddy surname: Petit fullname: Petit, Eddy organization: Institut Européen des Membranes, UMR 5635, ENSCM-UM2-CNRS, Place Eugène Bataillon, 34 095 Cedex 5, Montpellier, France – sequence: 6 givenname: Vasile surname: Hulea fullname: Hulea, Vasile email: vasile.hulea@enscm.fr organization: Institut Charles Gerhardt, UMR 5253, CNRS-UM2-ENSCM-UM1, Matériaux Avancés pour la Catalyse et la Santé, 8 rue de l'Ecole Normale, 34 296 Cedex 5, Montpellier, France |
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| Keywords | Vanadate Hydrotalcite Raman spectroscopy Molybdate Sulfoxidation |
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| SubjectTerms | Catalysis Catalysts Chemical Sciences Hydrotalcite Hydroxides Ion exchangers Molybdate Monitoring Oxidation Raman spectroscopy Sulfides Sulfoxidation Vanadate |
| Title | Raman spectroscopy — Useful tool for studying the catalysts derived from Mo and V-oxyanion-intercalated layered double hydroxides |
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