Adsorption behavior and performance of ammonium onto sorghum straw biochar from water
Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource uti...
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Published in | Scientific reports Vol. 12; no. 1; pp. 5358 - 11 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Nature Publishing Group UK
30.03.2022
Nature Publishing Group Nature Portfolio |
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Abstract | Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6–10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling. |
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AbstractList | Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6-10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling. Abstract Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6–10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling. Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6-10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling.Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6-10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling. Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile, the wastewater produced by winemaking is typical organic wastewater with a high ammonium concentration. To solve the problem of resource utilization of SS and remove ammonium from water, SS was used to prepare biochar as an adsorbent for ammonium adsorption. Batch adsorption experiments were carried out to study the influencing factors and adsorption mechanisms of ammonium onto sorghum straw biochar (SSB). The results showed that the adsorption capacity of SSB was much higher than that of SS. The SSB pyrolyzed at 300 °C had the highest adsorption capacity. The favorable pH was 6–10, and the optimal dosage was 2.5 g/L. The adsorption process and behavior conformed to the pseudo-second-order kinetic and Langmuir isotherm adsorption models. The maximum ammonium adsorption capacity of SSB at 45 °C was 7.09 mg/g, which was equivalent to 7.60 times of SS. The ammonium adsorption of SS and SSB was mainly chemical adsorption. The regeneration test indicated that SSB had good regeneration performance after three adsorption-regeneration cycles. This work suggests that SSB could be potentially applied to sewage treatment containing ammonium to achieve the purpose of resource recycling. |
ArticleNumber | 5358 |
Author | Zhao, Ruohan Jiang, Yuting Wang, Bing Zhang, Xueyang Wang, Xiangui Pan, Changbin Ge, Banggui Xu, Huajie |
Author_xml | – sequence: 1 givenname: Huajie surname: Xu fullname: Xu, Huajie organization: Moutai Institute – sequence: 2 givenname: Bing surname: Wang fullname: Wang, Bing email: bwang6@gzu.edu.cn organization: College of Resources and Environment Engineering, Guizhou University, Key Laboratory of Karst Georesources and Environment, Ministry of Education – sequence: 3 givenname: Ruohan surname: Zhao fullname: Zhao, Ruohan organization: College of Resources and Environment Engineering, Guizhou University – sequence: 4 givenname: Xiangui surname: Wang fullname: Wang, Xiangui organization: Moutai Institute – sequence: 5 givenname: Changbin surname: Pan fullname: Pan, Changbin organization: Moutai Institute – sequence: 6 givenname: Yuting surname: Jiang fullname: Jiang, Yuting organization: Moutai Institute – sequence: 7 givenname: Xueyang surname: Zhang fullname: Zhang, Xueyang organization: School of Environmental Engineering, Xuzhou University of Technology – sequence: 8 givenname: Banggui surname: Ge fullname: Ge, Banggui organization: Kweichow Moutai Co., Ltd |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35354834$$D View this record in MEDLINE/PubMed |
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Snippet | Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem. Meanwhile,... Abstract Sorghum has been widely used for liquor production and brewing, but how to make efficiently utilize sorghum straw (SS) has become an urgent problem.... |
SourceID | doaj pubmedcentral proquest pubmed crossref springer |
SourceType | Open Website Open Access Repository Aggregation Database Index Database Enrichment Source Publisher |
StartPage | 5358 |
SubjectTerms | 704/172/169 704/172/4081 Adsorption Ammonium Ammonium Compounds Charcoal Humanities and Social Sciences multidisciplinary Organic wastes Resource utilization Science Science (multidisciplinary) Sewage treatment Sorghum Straw Wastewater Wastewater treatment Water Water Pollutants, Chemical |
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Title | Adsorption behavior and performance of ammonium onto sorghum straw biochar from water |
URI | https://link.springer.com/article/10.1038/s41598-022-08591-5 https://www.ncbi.nlm.nih.gov/pubmed/35354834 https://www.proquest.com/docview/2645337923 https://www.proquest.com/docview/2645856519 https://pubmed.ncbi.nlm.nih.gov/PMC8967861 https://doaj.org/article/a47ed5dbaf8641f895911f89c686a820 |
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