Facile synthesis of pectin-stabilized magnetic graphene oxide Prussian blue nanocomposites for selective cesium removal from aqueous solution

• Published in: Bioresource technology Vol. 216; pp. 391 - 398
• Main Authors: Kadam, Avinash A., Jang, Jiseon, Lee, Dae Sung
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.09.2016
• Subjects: Adsorption; Aniline Compounds - chemistry; aqueous solutions; cesium; Cesium - isolation & purification; Coloring Agents - chemistry; Ferrocyanides - chemistry; Graphene oxide; Graphite - chemistry; heat production; Hydrogen-Ion Concentration; Magnetic nanoparticles; Microscopy, Electron, Scanning; nanocomposites; Nanocomposites - chemistry; Pectin; pectins; Pectins - chemistry; Photoelectron Spectroscopy; Radioactive cesium; scanning electron microscopy; sorption isotherms; Spectroscopy, Fourier Transform Infrared; Temperature; Thermodynamics; Waste Water - chemistry; wastewater; Water Pollutants, Chemical - isolation & purification; Water Pollutants, Radioactive - isolation & purification; X-Ray Diffraction; Pectin; Graphene oxide; Adsorption; Radioactive cesium; Magnetic nanoparticles
• ISSN: 0960-8524; 1873-2976; 1873-2976
• DOI: 10.1016/j.biortech.2016.05.103

[Display omitted] •PSMGPB nanocomposites were synthesized by low cost facile method for cesium removal.•The PSMGPB nanocomposites were characterized by XPS, XRD, MPMS, TEM, and SEM.•Pectin-stabilized separation of graphene oxide sheets enhanced the cesium adsorption.•Based on nonlinear regression, Langmuir model gave the best fit to experimental data.•Thermodynamic study indicated the spontaneous and exothermic nature of adsorption. This work focused on the development of pectin-stabilized magnetic graphene oxide Prussian blue (PSMGPB) nanocomposites for removal of cesium from wastewater. The PSMGPB nanocomposite showed an improved adsorption capacity of 1.609mmol/g for cesium, compared with magnetic graphene oxide Prussian blue, magnetic pectin Prussian blue, and magnetic Prussian blue nanocomposites, which exhibited adsorption capacities of 1.230, 0.901, and 0.330mmol/g, respectively. Increased adsorption capacity of PSMGPB nanocomposites was attributed to the pectin-stabilized separation of graphene oxide sheets and enhanced distribution of magnetites on the graphene oxide surface. Scanning electron microscopy images showed the effective separation of graphene oxide sheets due to the incorporation of pectin. The optimum temperature and pH for adsorption were 30°C and 7.0, respectively. A thermodynamic study indicated the spontaneous and the exothermic nature of cesium adsorption. Based on non-linear regression, the Langmuir isotherm fitted the experimental data better than the Freundlich and Tempkin models.