Self‐Assembled Porphyrazine Nucleosides on DNA Templates: Highly Fluorescent Chromophore Arrays and Sizing Forensic Tandem Repeat Sequences

• Published in: European journal of organic chemistry Vol. 2018; no. 36; pp. 5054 - 5059
• Main Authors: Ishutkina, Mariia V., Berry, Alice R., Hussain, Rohanah, Khelevina, Olga G., Siligardi, Giuliano, Stulz, Eugen
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 30.09.2018; Wiley Subscription Services, Inc; John Wiley and Sons Inc
• Subjects: Adenosine; Arrays; Assembly; Chemistry; Chemistry, Organic; Chromophores; Communication; Communications; Deoxyribonucleic acid; DNA; Fluorescence; Forensic engineering; Functional organic materials; Gene sequencing; Nucleosides; Optical properties; Organic chemistry; Physical Sciences; Porphyrinoids; Science & Technology; Sizing; Supramolecular chemistry; NONCOVALENT; PORPHYRINS; OLIGONUCLEOTIDE; Fluorescence; HYBRIDIZATION; NILE RED; Supramolecular chemistry; Porphyrinoids; DYE; CONSTRUCTION; ENERGY-TRANSFER; SUPRAMOLECULAR SCAFFOLD; BINDING; Functional organic materials

The formation of chromophore arrays using a DNA templating approach leads to the creation of supramolecular assemblies, where the optical properties of the overall system can be fine‐tuned to a large extent. In particular, porphyrin derivatives have been shown to be versatile building blocks; mostly...