An Electrically Conducting Three‐Dimensional Iron–Catecholate Porous Framework

• Published in: Angewandte Chemie International Edition Vol. 60; no. 33; pp. 18065 - 18072
• Main Authors: Mähringer, Andre, Döblinger, Markus, Hennemann, Matthias, Gruber, Christoph, Fehn, Dominik, Scheurle, Patricia I., Hosseini, Pouya, Santourian, Irina, Schirmacher, Alfred, Rotter, Julian M., Wittstock, Gunther, Meyer, Karsten, Clark, Timothy, Bein, Thomas, Medina, Dana D.
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 09.08.2021; John Wiley and Sons Inc
• Edition: International ed. in English
• Subjects: Absorption; Broadband; Conduction; Conductors; Crystallites; Crystals; Current carriers; Diamonds; Electrical conductivity; Electrical resistivity; Iron; iron-catecholate; Metal-organic frameworks; porosity; Porous materials; Quantum mechanics; three-dimensional framework; Topology; Metal-Organic Frameworks; three-dimensional framework; iron-catecholate; electrical conductivity; porosity

We report the synthesis of a unique cubic metal–organic framework (MOF), Fe‐HHTP‐MOF, comprising hexahydroxytriphenylene (HHTP) supertetrahedral units and FeIII ions, arranged in a diamond topology. The MOF is synthesized under solvothermal conditions, yielding a highly crystalline, deep black powde...