Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells

Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light‐to‐chemical energetic transduction. This field of research, called “artificial photosynthesis,” is currently the subject of intense interest, driven by the...

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Published in	Photochemistry and photobiology Vol. 87; no. 5; pp. 946 - 964
Main Authors	Andreiadis, Eugen S., Chavarot-Kerlidou, Murielle, Fontecave, Marc, Artero, Vincent
Format	Journal Article
Language	English
Published	Oxford, UK Blackwell Publishing Ltd 01.09.2011 Wiley
Subjects	Catalysts Cells Chemical Sciences Coordination chemistry Hydrogen production Photochemistry Photosynthesis Signal transduction Solar energy Water
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Abstract	Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light‐to‐chemical energetic transduction. This field of research, called “artificial photosynthesis,” is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon‐free fuel hydrogen through the light‐driven water splitting. In this review, we highlight the recent achievements on light‐driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices. This review surveys the recent achievements in the field of artificial photosynthesis and light‐driven water splitting. Homogeneous photocatalytic H2‐ and O2‐evolving systems (bioconstructs as well as synthetic molecules) are presented, with a specific focus on those containing noble‐metal‐free catalytic centres. Openings regarding the development of a fully molecular‐based technological device for water splitting are discussed.
AbstractList	Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light-to-chemical energetic transduction. This field of research, called "artificial photosynthesis," is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon-free fuel hydrogen through the light-driven water splitting. In this review, we highlight the recent achievements on light-driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices.Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light-to-chemical energetic transduction. This field of research, called "artificial photosynthesis," is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon-free fuel hydrogen through the light-driven water splitting. In this review, we highlight the recent achievements on light-driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices. Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light‐to‐chemical energetic transduction. This field of research, called “artificial photosynthesis,” is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon‐free fuel hydrogen through the light‐driven water splitting. In this review, we highlight the recent achievements on light‐driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices. Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light-to-chemical energetic transduction. This field of research, called "artificial photosynthesis," is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon-free fuel hydrogen through the light-driven water splitting. In this review, we highlight the recent achievements on light-driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices. [PUBLICATION ABSTRACT] Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light‐to‐chemical energetic transduction. This field of research, called “artificial photosynthesis,” is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon‐free fuel hydrogen through the light‐driven water splitting. In this review, we highlight the recent achievements on light‐driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices. This review surveys the recent achievements in the field of artificial photosynthesis and light‐driven water splitting. Homogeneous photocatalytic H2‐ and O2‐evolving systems (bioconstructs as well as synthetic molecules) are presented, with a specific focus on those containing noble‐metal‐free catalytic centres. Openings regarding the development of a fully molecular‐based technological device for water splitting are discussed.
Author	Artero, Vincent Andreiadis, Eugen S. Fontecave, Marc Chavarot-Kerlidou, Murielle
Author_xml	– sequence: 1 givenname: Eugen S. surname: Andreiadis fullname: Andreiadis, Eugen S. organization: Laboratoire de Chimie et Biologie des Métaux, UMR 5249, Université Grenoble 1 - CNRS - CEA, DSV/iRTSV K', Grenoble, France – sequence: 2 givenname: Murielle surname: Chavarot-Kerlidou fullname: Chavarot-Kerlidou, Murielle email: murielle.chavarot-kerlidou@cea.fr organization: Laboratoire de Chimie et Biologie des Métaux, UMR 5249, Université Grenoble 1 - CNRS - CEA, DSV/iRTSV K', Grenoble, France – sequence: 3 givenname: Marc surname: Fontecave fullname: Fontecave, Marc email: murielle.chavarot-kerlidou@cea.fr organization: Laboratoire de Chimie et Biologie des Métaux, UMR 5249, Université Grenoble 1 - CNRS - CEA, DSV/iRTSV K', Grenoble, France – sequence: 4 givenname: Vincent surname: Artero fullname: Artero, Vincent organization: Laboratoire de Chimie et Biologie des Métaux, UMR 5249, Université Grenoble 1 - CNRS - CEA, DSV/iRTSV K', Grenoble, France
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/21740444$$D View this record in MEDLINE/PubMed https://hal.science/hal-01063100$$DView record in HAL
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Copyright	2011 The Authors. Photochemistry and Photobiology © 2011 The American Society of Photobiology 2011 The Authors. Photochemistry and Photobiology © 2011 The American Society of Photobiology. Copyright Blackwell Publishing Ltd. Sep/Oct 2011 Distributed under a Creative Commons Attribution 4.0 International License
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Snippet	Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light‐to‐chemical... Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light-to-chemical...
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SubjectTerms	Catalysts Cells Chemical Sciences Coordination chemistry Hydrogen production Photochemistry Photosynthesis Signal transduction Solar energy Water
Title	Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells
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