Green Synthesized Ag Nanoparticles for Bio-Sensing and Photocatalytic Applications
In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the reduction of silver nitrate (AgNO ) using different leaf extracts. An optimum surface plasmon resonance (SPR) behavior is obtained for neem lea...
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Published in | ACS omega Vol. 5; no. 22; pp. 13123 - 13129 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
09.06.2020
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Abstract | In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the reduction of silver nitrate (AgNO
) using different leaf extracts. An optimum surface plasmon resonance (SPR) behavior is obtained for neem leaf extracts because of the presence of a high concentration of diterpenoids, as evidenced from gas chromatography mass spectroscopy results. The underlying mechanism for the formation of Ag NPs is highlighted. The Ag NPs are in spherical shape and exhibit the hexagonal crystal phase and also show a good stability. The biosensing property of the Ag NPs is evaluated using mancozeb (MCZ) agro-fungicide, and the SPR peak position exhibited a linear response with MCZ concentration. The sensitivity is found to be 39.1 nm/mM. Further, the photocatalytic activity of Ag NPs is tested using 0.5 mM MCZ solution as a model under UV-visible illumination. It is observed that photocatalytic activity is caused by the formation of reactive oxygen species. Therefore, the green synthesized Ag NPs are potential candidates for biosensing and photocatalytic applications. |
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AbstractList | In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the reduction of silver nitrate (AgNO3) using different leaf extracts. An optimum surface plasmon resonance (SPR) behavior is obtained for neem leaf extracts because of the presence of a high concentration of diterpenoids, as evidenced from gas chromatography mass spectroscopy results. The underlying mechanism for the formation of Ag NPs is highlighted. The Ag NPs are in spherical shape and exhibit the hexagonal crystal phase and also show a good stability. The biosensing property of the Ag NPs is evaluated using mancozeb (MCZ) agro-fungicide, and the SPR peak position exhibited a linear response with MCZ concentration. The sensitivity is found to be 39.1 nm/mM. Further, the photocatalytic activity of Ag NPs is tested using 0.5 mM MCZ solution as a model under UV-visible illumination. It is observed that photocatalytic activity is caused by the formation of reactive oxygen species. Therefore, the green synthesized Ag NPs are potential candidates for biosensing and photocatalytic applications. In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the reduction of silver nitrate (AgNO 3 ) using different leaf extracts. An optimum surface plasmon resonance (SPR) behavior is obtained for neem leaf extracts because of the presence of a high concentration of diterpenoids, as evidenced from gas chromatography mass spectroscopy results. The underlying mechanism for the formation of Ag NPs is highlighted. The Ag NPs are in spherical shape and exhibit the hexagonal crystal phase and also show a good stability. The biosensing property of the Ag NPs is evaluated using mancozeb (MCZ) agro-fungicide, and the SPR peak position exhibited a linear response with MCZ concentration. The sensitivity is found to be 39.1 nm/mM. Further, the photocatalytic activity of Ag NPs is tested using 0.5 mM MCZ solution as a model under UV–visible illumination. It is observed that photocatalytic activity is caused by the formation of reactive oxygen species. Therefore, the green synthesized Ag NPs are potential candidates for biosensing and photocatalytic applications. In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the reduction of silver nitrate (AgNO ) using different leaf extracts. An optimum surface plasmon resonance (SPR) behavior is obtained for neem leaf extracts because of the presence of a high concentration of diterpenoids, as evidenced from gas chromatography mass spectroscopy results. The underlying mechanism for the formation of Ag NPs is highlighted. The Ag NPs are in spherical shape and exhibit the hexagonal crystal phase and also show a good stability. The biosensing property of the Ag NPs is evaluated using mancozeb (MCZ) agro-fungicide, and the SPR peak position exhibited a linear response with MCZ concentration. The sensitivity is found to be 39.1 nm/mM. Further, the photocatalytic activity of Ag NPs is tested using 0.5 mM MCZ solution as a model under UV-visible illumination. It is observed that photocatalytic activity is caused by the formation of reactive oxygen species. Therefore, the green synthesized Ag NPs are potential candidates for biosensing and photocatalytic applications. |
Author | Varghese Alex, Kevin Kamakshi, Koppole Tamil Pavai, Parthiban Sekhar, Koppole Chandra Shiva Prasad, Madavi Rugmini, Radhasaran |
Author_xml | – sequence: 1 givenname: Kevin surname: Varghese Alex fullname: Varghese Alex, Kevin organization: Department of Physics, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, India – sequence: 2 givenname: Parthiban surname: Tamil Pavai fullname: Tamil Pavai, Parthiban organization: Department of Physics, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, India – sequence: 3 givenname: Radhasaran surname: Rugmini fullname: Rugmini, Radhasaran organization: Department of Physics, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, India – sequence: 4 givenname: Madavi surname: Shiva Prasad fullname: Shiva Prasad, Madavi organization: Department of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, India – sequence: 5 givenname: Koppole surname: Kamakshi fullname: Kamakshi, Koppole organization: Department of Science and Humanities, Indian Institute of Information Technology Tiruchirappalli, Tiruchirappalli 620 015, Tamil Nadu, India – sequence: 6 givenname: Koppole Chandra surname: Sekhar fullname: Sekhar, Koppole Chandra organization: Department of Physics, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, India |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32548498$$D View this record in MEDLINE/PubMed |
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Snippet | In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the... In this work, sensing and photocatalytic activities of green synthesized silver nanoparticles (Ag NPs) are investigated. Ag NPs have been synthesized by the... |
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Title | Green Synthesized Ag Nanoparticles for Bio-Sensing and Photocatalytic Applications |
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