The rose petal effect and the modes of superhydrophobicity

The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize the hydrophobicity/philicity of a solid surface. However, it was found recently that high CAs can coexist with strong adhesion between water a...

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Published inPhilosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences Vol. 368; no. 1929; pp. 4713 - 4728
Main Authors Bhushan, Bharat, Nosonovsky, Michael
Format Journal Article
LanguageEnglish
Published England The Royal Society 28.10.2010
The Royal Society Publishing
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Abstract The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize the hydrophobicity/philicity of a solid surface. However, it was found recently that high CAs can coexist with strong adhesion between water and a solid surface in the case of the so-called 'rose petal effect'. Several additional parameters have been proposed to characterize the interaction of water with a rough solid surface, including the CA hysteresis, the ability of water droplets to bounce off a solid surface, the tilt angle needed to initiate the flow of a droplet, and the normal and shear adhesion. It is clear now that wetting is not characterized by a single parameter, since several modes or regimes of wetting of a rough surface can exist, including the Wenzel, Cassie, lotus and petal. Understanding the wetting of rough surfaces is important in order to design non-adhesive surfaces for various applications.
AbstractList The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize the hydrophobicity/philicity of a solid surface. However, it was found recently that high CAs can coexist with strong adhesion between water and a solid surface in the case of the so-called 'rose petal effect'. Several additional parameters have been proposed to characterize the interaction of water with a rough solid surface, including the CA hysteresis, the ability of water droplets to bounce off a solid surface, the tilt angle needed to initiate the flow of a droplet, and the normal and shear adhesion. It is clear now that wetting is not characterized by a single parameter, since several modes or regimes of wetting of a rough surface can exist, including the Wenzel, Cassie, lotus and petal. Understanding the wetting of rough surfaces is important in order to design non-adhesive surfaces for various applications.
The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize the hydrophobicity/philicity of a solid surface. However, it was found recently that high CAs can coexist with strong adhesion between water and a solid surface in the case of the so-called 'rose petal effect'. Several additional parameters have been proposed to characterize the interaction of water with a rough solid surface, including the CA hysteresis, the ability of water droplets to bounce off a solid surface, the tilt angle needed to initiate the flow of a droplet, and the normal and shear adhesion. It is clear now that wetting is not characterized by a single parameter, since several modes or regimes of wetting of a rough surface can exist, including the Wenzel, Cassie, lotus and petal. Understanding the wetting of rough surfaces is important in order to design non-adhesive surfaces for various applications.The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize the hydrophobicity/philicity of a solid surface. However, it was found recently that high CAs can coexist with strong adhesion between water and a solid surface in the case of the so-called 'rose petal effect'. Several additional parameters have been proposed to characterize the interaction of water with a rough solid surface, including the CA hysteresis, the ability of water droplets to bounce off a solid surface, the tilt angle needed to initiate the flow of a droplet, and the normal and shear adhesion. It is clear now that wetting is not characterized by a single parameter, since several modes or regimes of wetting of a rough surface can exist, including the Wenzel, Cassie, lotus and petal. Understanding the wetting of rough surfaces is important in order to design non-adhesive surfaces for various applications.
Author Nosonovsky, Michael
Bhushan, Bharat
Author_xml – sequence: 1
  givenname: Bharat
  surname: Bhushan
  fullname: Bhushan, Bharat
– sequence: 2
  givenname: Michael
  surname: Nosonovsky
  fullname: Nosonovsky, Michael
BackLink https://www.ncbi.nlm.nih.gov/pubmed/20855317$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1002/adma.200401726
10.1088/0953-8984/20/39/395005
10.1103/PhysRevLett.99.176102
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Snippet The wetting of rough surfaces remains a subject of active investigation by scientists. The contact angle (CA) is a traditional parameter used to characterize...
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SubjectTerms Adhesion
Hysteresis
Liquids
Nanostructures
Petals
Rose Petal
Self-Cleaning
Solid surfaces
Superhydrophobicity
Surface areas
Surface microstructures
Surface roughness
Wetting
Wetting Regimes
Title The rose petal effect and the modes of superhydrophobicity
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https://royalsocietypublishing.org/doi/full/10.1098/rsta.2010.0203
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