Synthesis and molecular structure of perhalogenated rhenium-oxo corroles

• Published in: Scientific reports Vol. 10; no. 1; p. 19727
• Main Authors: Alemayehu, Abraham B., Einrem, Rune F., McCormick-McPherson, Laura J., Settineri, Nicholas S., Ghosh, Abhik
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 12.11.2020; Nature Publishing Group; Springer
• Subjects: 639/638; 639/638/263; 639/638/403; 639/638/440; 639/638/549; 639/638/911; Bromine; chemical synthesis; Chemistry; Chemistry: 440; Chlorine; coordination chemistry; Halogens; Humanities and Social Sciences; inorganic chemistry; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Kjemi: 440; Laboratories; Ligands; Matematikk og Naturvitenskap: 400; Mathematics and natural science: 400; Molecular structure; multidisciplinary; organic chemistry; Photodynamic therapy; physical chemistry; Rhenium; Science; Science (multidisciplinary); VDP

As part of our efforts to develop rhenium-oxo corroles as photosensitizers for oxygen sensing and photodynamic therapy, we investigated the potential β -perhalogenation of five ReO meso -tris( para -X-phenyl)corroles, Re[T p XPC](O) (X = CF 3 , H, F, CH 3 , and OCH 3 ), with elemental chlorine and b...