Green synthesis of TiO2 nanoparticles from Syzygium cumini extract for photo-catalytic removal of lead (Pb) in explosive industrial wastewater
Green synthesis is a simple, non-toxic, economical and eco-friendly approach for the synthesis of nanoparticles. In the present work, nanoparticles of titanium dioxide (TiO NPs) were synthesized using an aqueous solution of leaf extract as a capping agent. These green synthesized TiO NPs were furthe...
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Published in | Green processing and synthesis Vol. 9; no. 1; pp. 171 - 181 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
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De Gruyter
01.01.2020
Walter de Gruyter GmbH |
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Abstract | Green synthesis is a simple, non-toxic, economical and eco-friendly approach for the synthesis of nanoparticles. In the present work, nanoparticles of titanium dioxide (TiO
NPs) were synthesized using an aqueous solution of
leaf extract as a capping agent. These green synthesized TiO
NPs were further evaluated for photo catalytic removal of lead from industrial wastewater. Obtained nanoparticles were characterized using: high-resolution scanning electron microscopy (HRSEM), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and Brunauer-Emmett-Teller (BET). Obtained results revealed that synthesized TiO
NPs possess spherical morphology with anatase phase with a large BET surface area of 105 m
/g. Photo catalytic studies of TiO
NPs for lead removal from explosive wastewater were performed in a self-designed reactor. Inductive coupled plasma spectroscopy (ICP) was used to determine the lead concentration. Obtained results witnessed 75.5% removal in chemical oxygen demand (COD) and 82.53% removal in lead (Pb
). This application of green TiO
NPs is being explored for the first time. |
---|---|
AbstractList | Green synthesis is a simple, non-toxic, economical and eco-friendly approach for the synthesis of nanoparticles. In the present work, nanoparticles of titanium dioxide (TiO
2
NPs) were synthesized using an aqueous solution of
Syzygium cumini
leaf extract as a capping agent. These green synthesized TiO
2
NPs were further evaluated for photo catalytic removal of lead from industrial wastewater. Obtained nanoparticles were characterized using: high-resolution scanning electron microscopy (HRSEM), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and Brunauer-Emmett-Teller (BET). Obtained results revealed that synthesized TiO
2
NPs possess spherical morphology with anatase phase with a large BET surface area of 105 m
2
/g. Photo catalytic studies of TiO
2
NPs for lead removal from explosive wastewater were performed in a self-designed reactor. Inductive coupled plasma spectroscopy (ICP) was used to determine the lead concentration. Obtained results witnessed 75.5% removal in chemical oxygen demand (COD) and 82.53% removal in lead (Pb
2+
). This application of green TiO
2
NPs is being explored for the first time. Green synthesis is a simple, non-toxic, economical and eco-friendly approach for the synthesis of nanoparticles. In the present work, nanoparticles of titanium dioxide (TiO NPs) were synthesized using an aqueous solution of leaf extract as a capping agent. These green synthesized TiO NPs were further evaluated for photo catalytic removal of lead from industrial wastewater. Obtained nanoparticles were characterized using: high-resolution scanning electron microscopy (HRSEM), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and Brunauer-Emmett-Teller (BET). Obtained results revealed that synthesized TiO NPs possess spherical morphology with anatase phase with a large BET surface area of 105 m /g. Photo catalytic studies of TiO NPs for lead removal from explosive wastewater were performed in a self-designed reactor. Inductive coupled plasma spectroscopy (ICP) was used to determine the lead concentration. Obtained results witnessed 75.5% removal in chemical oxygen demand (COD) and 82.53% removal in lead (Pb ). This application of green TiO NPs is being explored for the first time. Green synthesis is a simple, non-toxic, economical and eco-friendly approach for the synthesis of nanoparticles. In the present work, nanoparticles of titanium dioxide (TiO2 NPs) were synthesized using an aqueous solution of Syzygium cumini leaf extract as a capping agent. These green synthesized TiO2 NPs were further evaluated for photo catalytic removal of lead from industrial wastewater. Obtained nanoparticles were characterized using: high-resolution scanning electron microscopy (HRSEM), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and Brunauer-Emmett-Teller (BET). Obtained results revealed that synthesized TiO2 NPs possess spherical morphology with anatase phase with a large BET surface area of 105 m2/g. Photo catalytic studies of TiO2 NPs for lead removal from explosive wastewater were performed in a self-designed reactor. Inductive coupled plasma spectroscopy (ICP) was used to determine the lead concentration. Obtained results witnessed 75.5% removal in chemical oxygen demand (COD) and 82.53% removal in lead (Pb2+). This application of green TiO2 NPs is being explored for the first time. |
Author | Mishra, Pradeep Kumar Arif, Zeenat Kumar, Pradeep Sethy, Naresh Kumar |
Author_xml | – sequence: 1 givenname: Naresh Kumar surname: Sethy fullname: Sethy, Naresh Kumar email: nareshks.rs.che15@itbhu.ac.in organization: Department of Chemical Engineering and Technology, Indian Institute of Technology (BHU), Varanasi-221005, India – sequence: 2 givenname: Zeenat surname: Arif fullname: Arif, Zeenat organization: Department of Chemical Engineering and Technology, Indian Institute of Technology (BHU), Varanasi-221005, India – sequence: 3 givenname: Pradeep Kumar surname: Mishra fullname: Mishra, Pradeep Kumar organization: Department of Chemical Engineering and Technology, Indian Institute of Technology (BHU), Varanasi-221005, India – sequence: 4 givenname: Pradeep surname: Kumar fullname: Kumar, Pradeep organization: Department of Chemical Engineering and Technology, Indian Institute of Technology (BHU), Varanasi-221005, India |
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SubjectTerms | Anatase Aqueous solutions Chemical oxygen demand Electron microscopy Energy dispersive X ray spectroscopy extract Fourier transforms green synthesis High resolution Inductively coupled plasma Industrial wastes Industrial wastewater Infrared spectroscopy Lead Light diffraction Light scattering Microscopy Morphology Nanoparticles Organic chemistry photo-catalytic degradation Photon correlation spectroscopy Plant extracts Plasma spectra Scanning electron microscopy Spectroscopy Spectrum analysis Surgical implants Syzygium cumini syzygium cumini extract TiO tio2 nanoparticles Titanium dioxide Transmission electron microscopy Wastewater Wastewater treatment X-ray diffraction |
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Title | Green synthesis of TiO2 nanoparticles from Syzygium cumini extract for photo-catalytic removal of lead (Pb) in explosive industrial wastewater |
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