Patterned crystal growth and heat wave generation in hydrogels
The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast...
Saved in:
| Published in | Nature communications Vol. 13; no. 1; p. 259 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
England
Nature Publishing Group
11.01.2022
Nature Publishing Group UK Nature Portfolio |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas. |
|---|---|
| AbstractList | The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas.The crystallization of metastable liquid phase change materials releases stored energy upon nucleation. Here, the authors demonstrate area-selective activation of thermoresponsive processes by exothermic crystallization of sodium acetate into trihydrate crystals within a patterned polyacrylamide hydrogel. The crystallization of metastable liquid phase change materials releases stored energy upon nucleation. Here, the authors demonstrate area-selective activation of thermoresponsive processes by exothermic crystallization of sodium acetate into trihydrate crystals within a patterned polyacrylamide hydrogel. Abstract The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas. The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas. The crystallization of metastable liquid phase change materials releases stored energy upon nucleation. Here, the authors demonstrate area-selective activation of thermoresponsive processes by exothermic crystallization of sodium acetate into trihydrate crystals within a patterned polyacrylamide hydrogel. The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas. |
| ArticleNumber | 259 |
| Author | Schroeder, Thomas B H Aizenberg, Joanna |
| Author_xml | – sequence: 1 givenname: Thomas B H orcidid: 0000-0003-2795-1730 surname: Schroeder fullname: Schroeder, Thomas B H email: tschroeder@g.harvard.edu organization: John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA. tschroeder@g.harvard.edu – sequence: 2 givenname: Joanna orcidid: 0000-0002-2343-8705 surname: Aizenberg fullname: Aizenberg, Joanna email: jaiz@seas.harvard.edu, jaiz@seas.harvard.edu organization: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA. jaiz@seas.harvard.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35017471$$D View this record in MEDLINE/PubMed https://www.osti.gov/biblio/1839330$$D View this record in Osti.gov |
| BookMark | eNpdksluFDEURS0UREKTH2CBSrBhU-B52ESKIoZIkWABa8vtejW0qu1guxN1vh53KkQJ3nh49x1fW_c1OgoxAEJvCf5EMNOfMydcqhZT0lIlsGjvXqATijlpiaLs6Mn6GJ3mvMF1MEM056_QMROYKK7ICTr76UqBFKBrfNrn4uZmSPG2jI0LXTOCK82tu4FmgADJlSmGZgrNuO9SHGDOb9DL3s0ZTh_mFfr99cuvi-_t1Y9vlxfnV60XlJVWe8eklkYpJ0FArwjgupNYOOa1FD1I5SVm0IEWsmem-uPC9Mb5db-uhRW6XLhddBt7naatS3sb3WTvD2IarEtl8jNYLDF0nfKdd44TpyrF95h52mMOohpZobOFdb1bb6HzEEpy8zPo80qYRjvEG6uVoFLyCni_AGIuk81-KuBHH0MAXyzRzDB2cPzx4ZYU_-wgF7udsod5dgHiLlsqiaHYGK6r9MN_0k3cpVD_86DSihtCWVXRReVTzDlB_-iYYHuIhF0iYWsk7H0k7F1tevf0rY8t_wLA_gKebLMj |
| CitedBy_id | crossref_primary_10_1016_j_est_2023_106726 crossref_primary_10_1002_adfm_202400203 crossref_primary_10_1021_acsami_4c01914 crossref_primary_10_1039_D2SC02317B crossref_primary_10_1021_jacs_4c04346 crossref_primary_10_1002_adtp_202300035 crossref_primary_10_1039_D4MH00331D crossref_primary_10_1007_s40820_022_00931_4 crossref_primary_10_1080_19475411_2022_2116737 crossref_primary_10_3390_molecules28155931 crossref_primary_10_1021_jacs_2c13264 crossref_primary_10_1002_ange_202320095 crossref_primary_10_1002_anie_202320095 crossref_primary_10_1002_adfm_202301505 crossref_primary_10_1002_adfm_202314353 |
| Cites_doi | 10.1038/ncomms14700 10.1021/acsaem.9b02249 10.1039/D0MH02069A 10.1016/0022-3093(93)90467-C 10.1038/s41563-019-0434-0 10.1016/j.rser.2013.12.017 10.1126/scirobotics.aax7044 10.1016/0022-0248(95)00128-X 10.1016/j.sna.2006.07.017 10.1016/S1359-4311(99)00061-7 10.1007/978-3-642-81835-6 10.1038/s41467-020-15415-5 10.1016/0022-0248(73)90107-3 10.1016/B978-075064833-2/50009-7 10.1021/ma50007a007 10.1038/s41467-019-14114-0 10.1016/j.ijheatmasstransfer.2012.09.014 10.1039/c2sm26064f 10.1002/adfm.201200300 10.1016/j.tca.2012.04.013 10.1246/bcsj.70.1289 10.1126/science.1178583 10.1039/D1TA02791C 10.1039/C5CE00389J 10.1016/j.actbio.2012.09.028 10.1016/j.solener.2004.11.014 10.1021/acs.chemrev.7b00285 10.1016/j.enbuild.2018.09.035 10.1016/j.rser.2010.11.018 10.1002/adma.201900248 10.1002/9780470517833 10.1016/j.ab.2014.12.023 10.1002/adma.202001068 10.1002/adma.202008119 10.1089/soro.2016.0008 10.1021/cg050288+ 10.1016/j.tca.2018.10.009 10.1039/C5SM02553B 10.1039/C9SM02221J 10.1038/35081034 10.1039/C4LC00568F 10.1039/C8BM01664J 10.1016/S0008-8846(99)00002-2 10.1126/science.290.5494.1134 10.1016/j.snb.2010.06.017 10.1002/anie.201412160 10.1038/s41586-018-0250-8 10.1016/j.matt.2019.10.019 10.1038/nature11223 10.1002/admt.202000286 10.1119/1.2830533 |
| ContentType | Journal Article |
| Copyright | 2022. The Author(s). The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. The Author(s) 2022 |
| Copyright_xml | – notice: 2022. The Author(s). – notice: The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: The Author(s) 2022 |
| DBID | NPM AAYXX CITATION 3V. 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7X7 7XB 88E 8AO 8FD 8FE 8FG 8FH 8FI 8FJ 8FK ABUWG AFKRA ARAPS AZQEC BBNVY BENPR BGLVJ BHPHI C1K CCPQU DWQXO FR3 FYUFA GHDGH GNUQQ H94 HCIFZ K9. LK8 M0S M1P M7P P5Z P62 P64 PIMPY PQEST PQQKQ PQUKI PRINS RC3 SOI 7X8 OTOTI 5PM DOA |
| DOI | 10.1038/s41467-021-27505-z |
| DatabaseName | PubMed CrossRef ProQuest Central (Corporate) Bacteriology Abstracts (Microbiology B) Calcium & Calcified Tissue Abstracts Chemoreception Abstracts Ecology Abstracts Entomology Abstracts (Full archive) Environment Abstracts Immunology Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) Nucleic Acids Abstracts Oncogenes and Growth Factors Abstracts ProQuest Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) ProQuest Pharma Collection Technology Research Database ProQuest SciTech Collection ProQuest Technology Collection ProQuest Natural Science Collection Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) ProQuest Central UK/Ireland Advanced Technologies & Aerospace Database (1962 - current) ProQuest Central Essentials Biological Science Collection ProQuest Central Technology Collection ProQuest Natural Science Collection Environmental Sciences and Pollution Management ProQuest One Community College ProQuest Central Engineering Research Database Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Central Student AIDS and Cancer Research Abstracts SciTech Premium Collection (Proquest) (PQ_SDU_P3) ProQuest Health & Medical Complete (Alumni) Biological Sciences Health & Medical Collection (Alumni Edition) PML(ProQuest Medical Library) Biological Science Database ProQuest Advanced Technologies & Aerospace Database ProQuest Advanced Technologies & Aerospace Collection Biotechnology and BioEngineering Abstracts Access via ProQuest (Open Access) ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central China Genetics Abstracts Environment Abstracts MEDLINE - Academic OSTI.GOV PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
| DatabaseTitle | PubMed CrossRef Publicly Available Content Database ProQuest Central Student Oncogenes and Growth Factors Abstracts ProQuest Advanced Technologies & Aerospace Collection ProQuest Central Essentials Nucleic Acids Abstracts SciTech Premium Collection ProQuest Central China Environmental Sciences and Pollution Management Health Research Premium Collection Natural Science Collection Biological Science Collection Chemoreception Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) ProQuest Medical Library (Alumni) Advanced Technologies & Aerospace Collection ProQuest Biological Science Collection ProQuest One Academic Eastern Edition ProQuest Hospital Collection ProQuest Technology Collection Health Research Premium Collection (Alumni) Biological Science Database Ecology Abstracts ProQuest Hospital Collection (Alumni) Biotechnology and BioEngineering Abstracts Entomology Abstracts ProQuest Health & Medical Complete ProQuest One Academic UKI Edition Engineering Research Database ProQuest One Academic Calcium & Calcified Tissue Abstracts Technology Collection Technology Research Database ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest Natural Science Collection ProQuest Pharma Collection ProQuest Central Genetics Abstracts Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Bacteriology Abstracts (Microbiology B) AIDS and Cancer Research Abstracts ProQuest SciTech Collection Advanced Technologies & Aerospace Database ProQuest Medical Library Immunology Abstracts Environment Abstracts ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | Publicly Available Content Database CrossRef PubMed |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: 8FG name: ProQuest Technology Collection url: https://search.proquest.com/technologycollection1 sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Biology |
| EISSN | 2041-1723 |
| EndPage | 259 |
| ExternalDocumentID | oai_doaj_org_article_060edd7cdcaa41a79f9cf03c2f04e5ca 1839330 10_1038_s41467_021_27505_z 35017471 |
| Genre | Research Support, U.S. Gov't, Non-P.H.S Research Support, Non-U.S. Gov't Journal Article |
| GrantInformation_xml | – fundername: ; grantid: DE-SC0005247 – fundername: ; grantid: P400P2-180743 – fundername: ; grantid: W911NF-17-1-0351 |
| GroupedDBID | --- 0R~ 39C 3V. 53G 5VS 70F 7X7 88E 8AO 8FE 8FG 8FH 8FI 8FJ AAHBH AAJSJ ABUWG ACGFO ACGFS ACIWK ACMJI ACPRK ACSMW ADBBV ADFRT ADRAZ AENEX AFKRA AFRAH AHMBA AJTQC ALIPV ALMA_UNASSIGNED_HOLDINGS AMTXH AOIJS ARAPS ASPBG AVWKF AZFZN BBNVY BCNDV BENPR BGLVJ BHPHI BPHCQ BVXVI C6C CCPQU DIK EBLON EBS EE. EMOBN F5P FEDTE FYUFA GROUPED_DOAJ HCIFZ HMCUK HVGLF HYE HZ~ KQ8 LK8 M1P M48 M7P M~E NAO NPM O9- OK1 P2P P62 PIMPY PQQKQ PROAC PSQYO RNS RNT RNTTT RPM SNYQT SV3 TSG UKHRP AAYXX CITATION 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7XB 8FD 8FK AZQEC C1K DWQXO FR3 GNUQQ H94 K9. P64 PQEST PQUKI PRINS RC3 SOI 7X8 AFGXO AAPBV AAYJO ADQMX AEDAW OTOTI ZA5 5PM |
| ID | FETCH-LOGICAL-c523t-8ca3686977a6e5ef71e0697605a3c865fe67c603ede856f39501459f9acbfb603 |
| IEDL.DBID | RPM |
| ISSN | 2041-1723 |
| IngestDate | Thu Sep 05 15:41:47 EDT 2024 Tue Sep 17 21:17:20 EDT 2024 Fri May 19 00:37:20 EDT 2023 Fri Aug 16 01:45:51 EDT 2024 Fri Sep 13 05:27:15 EDT 2024 Fri Aug 23 02:30:20 EDT 2024 Sat Sep 28 08:21:09 EDT 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Language | English |
| License | 2022. The Author(s). Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c523t-8ca3686977a6e5ef71e0697605a3c865fe67c603ede856f39501459f9acbfb603 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 USDOE SC0005247 |
| ORCID | 0000-0003-2795-1730 0000-0002-2343-8705 0000000223438705 0000000327951730 |
| OpenAccessLink | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8752664/ |
| PMID | 35017471 |
| PQID | 2618749123 |
| PQPubID | 546298 |
| PageCount | 1 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_060edd7cdcaa41a79f9cf03c2f04e5ca pubmedcentral_primary_oai_pubmedcentral_nih_gov_8752664 osti_scitechconnect_1839330 proquest_miscellaneous_2619209948 proquest_journals_2618749123 crossref_primary_10_1038_s41467_021_27505_z pubmed_primary_35017471 |
| PublicationCentury | 2000 |
| PublicationDate | 2022-01-11 |
| PublicationDateYYYYMMDD | 2022-01-11 |
| PublicationDate_xml | – month: 01 year: 2022 text: 2022-01-11 day: 11 |
| PublicationDecade | 2020 |
| PublicationPlace | England |
| PublicationPlace_xml | – name: England – name: London – name: United Kingdom |
| PublicationTitle | Nature communications |
| PublicationTitleAlternate | Nat Commun |
| PublicationYear | 2022 |
| Publisher | Nature Publishing Group Nature Publishing Group UK Nature Portfolio |
| Publisher_xml | – name: Nature Publishing Group – name: Nature Publishing Group UK – name: Nature Portfolio |
| References | Z Tai (27505_CR27) 2020; 11 CA Orme (27505_CR40) 2001; 411 A Kotikian (27505_CR6) 2019; 4 PA Korevaar (27505_CR13) 2020; 11 MB Maeß (27505_CR53) 2015; 479 H Rodrigue (27505_CR7) 2017; 4 RW Hopper (27505_CR35) 1973; 19 27505_CR50 LD Zarzar (27505_CR15) 2012; 8 AG Shtukenberg (27505_CR42) 2017; 117 Y-C Lin (27505_CR52) 2013; 9 N Kubota (27505_CR37) 1995; 152 B Sandnes (27505_CR21) 2008; 76 J Liu (27505_CR30) 2020; 5 N Beaupere (27505_CR20) 2018; 670 S Chen (27505_CR28) 2020; 3 CT Zhang (27505_CR3) 2020; 16 W Wang (27505_CR12) 2018; 559 GW Scherer (27505_CR43) 1999; 29 H Li (27505_CR45) 2009; 326 N Sarier (27505_CR18) 2012; 540 J Wei (27505_CR25) 2019; 0 KJ Davis (27505_CR39) 2000; 290 B Sandnes (27505_CR33) 2006; 80 FC Meldrum (27505_CR44) 2020; 32 F Benito-Lopez (27505_CR4) 2014; 14 LL Vasiliev (27505_CR22) 2000; 20 27505_CR47 A Sutton (27505_CR2) 2017; 8 G Englmair (27505_CR24) 2018; 180 H Zeng (27505_CR9) 2020; 2 N Kato (27505_CR51) 1997; 70 E Weber (27505_CR46) 2015; 17 27505_CR31 B Yang (27505_CR5) 2007; 134 27505_CR36 X He (27505_CR8) 2012; 487 27505_CR38 Z Ling (27505_CR16) 2014; 31 S Elhadj (27505_CR41) 2006; 6 V Nistor (27505_CR11) 2016; 12 PG De Gennes (27505_CR34) 1981; 14 Y Murase (27505_CR14) 2010; 149 AW Hauser (27505_CR10) 2015; 54 A Lenert (27505_CR17) 2013; 56 LF Cabeza (27505_CR19) 2011; 15 GW Scherer (27505_CR48) 1993; 155 A Choi (27505_CR1) 2019; 7 X Zhao (27505_CR29) 2021; 8 E Asenath-Smith (27505_CR49) 2012; 22 27505_CR23 S Deng (27505_CR32) 2021; 33 27505_CR26 |
| References_xml | – volume: 8 year: 2017 ident: 27505_CR2 publication-title: Nat. Commun. doi: 10.1038/ncomms14700 contributor: fullname: A Sutton – volume: 3 start-page: 2526 year: 2020 ident: 27505_CR28 publication-title: ACS Appl. Energy Mater. doi: 10.1021/acsaem.9b02249 contributor: fullname: S Chen – volume: 8 start-page: 1230 year: 2021 ident: 27505_CR29 publication-title: Mater. Horiz. doi: 10.1039/D0MH02069A contributor: fullname: X Zhao – volume: 155 start-page: 1 year: 1993 ident: 27505_CR48 publication-title: J. Non-Cryst. Solids doi: 10.1016/0022-3093(93)90467-C contributor: fullname: GW Scherer – ident: 27505_CR26 doi: 10.1038/s41563-019-0434-0 – volume: 31 start-page: 427 year: 2014 ident: 27505_CR16 publication-title: Renew. Sustain. Energy Rev. doi: 10.1016/j.rser.2013.12.017 contributor: fullname: Z Ling – volume: 4 start-page: eaax7044 year: 2019 ident: 27505_CR6 publication-title: Sci. Robot doi: 10.1126/scirobotics.aax7044 contributor: fullname: A Kotikian – volume: 152 start-page: 203 year: 1995 ident: 27505_CR37 publication-title: J. Cryst. Growth doi: 10.1016/0022-0248(95)00128-X contributor: fullname: N Kubota – volume: 134 start-page: 194 year: 2007 ident: 27505_CR5 publication-title: Sens. Actuators Phys. doi: 10.1016/j.sna.2006.07.017 contributor: fullname: B Yang – volume: 20 start-page: 913 year: 2000 ident: 27505_CR22 publication-title: Appl. Therm. Eng. doi: 10.1016/S1359-4311(99)00061-7 contributor: fullname: LL Vasiliev – ident: 27505_CR36 doi: 10.1007/978-3-642-81835-6 – volume: 11 year: 2020 ident: 27505_CR27 publication-title: Nat. Commun. doi: 10.1038/s41467-020-15415-5 contributor: fullname: Z Tai – volume: 19 start-page: 177 year: 1973 ident: 27505_CR35 publication-title: J. Cryst. Growth doi: 10.1016/0022-0248(73)90107-3 contributor: fullname: RW Hopper – ident: 27505_CR50 doi: 10.1016/B978-075064833-2/50009-7 – volume: 14 start-page: 1637 year: 1981 ident: 27505_CR34 publication-title: Macromolecules doi: 10.1021/ma50007a007 contributor: fullname: PG De Gennes – volume: 11 start-page: 1 year: 2020 ident: 27505_CR13 publication-title: Nat. Commun. doi: 10.1038/s41467-019-14114-0 contributor: fullname: PA Korevaar – volume: 56 start-page: 380 year: 2013 ident: 27505_CR17 publication-title: Int. J. Heat Mass Transf. doi: 10.1016/j.ijheatmasstransfer.2012.09.014 contributor: fullname: A Lenert – ident: 27505_CR23 – volume: 8 start-page: 8289 year: 2012 ident: 27505_CR15 publication-title: Soft Matter doi: 10.1039/c2sm26064f contributor: fullname: LD Zarzar – volume: 22 start-page: 2891 year: 2012 ident: 27505_CR49 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201200300 contributor: fullname: E Asenath-Smith – volume: 540 start-page: 7 year: 2012 ident: 27505_CR18 publication-title: Thermochim. Acta doi: 10.1016/j.tca.2012.04.013 contributor: fullname: N Sarier – volume: 70 start-page: 1289 year: 1997 ident: 27505_CR51 publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.70.1289 contributor: fullname: N Kato – volume: 326 start-page: 1244 year: 2009 ident: 27505_CR45 publication-title: Science doi: 10.1126/science.1178583 contributor: fullname: H Li – ident: 27505_CR31 doi: 10.1039/D1TA02791C – volume: 17 start-page: 5873 year: 2015 ident: 27505_CR46 publication-title: CrystEngComm doi: 10.1039/C5CE00389J contributor: fullname: E Weber – volume: 9 start-page: 5243 year: 2013 ident: 27505_CR52 publication-title: Acta Biomater. doi: 10.1016/j.actbio.2012.09.028 contributor: fullname: Y-C Lin – volume: 80 start-page: 616 year: 2006 ident: 27505_CR33 publication-title: Sol. Energy doi: 10.1016/j.solener.2004.11.014 contributor: fullname: B Sandnes – volume: 117 start-page: 14042 year: 2017 ident: 27505_CR42 publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.7b00285 contributor: fullname: AG Shtukenberg – volume: 180 start-page: 159 year: 2018 ident: 27505_CR24 publication-title: Energy Build. doi: 10.1016/j.enbuild.2018.09.035 contributor: fullname: G Englmair – volume: 15 start-page: 1675 year: 2011 ident: 27505_CR19 publication-title: Renew. Sustain. Energy Rev. doi: 10.1016/j.rser.2010.11.018 contributor: fullname: LF Cabeza – volume: 0 start-page: 1900248 year: 2019 ident: 27505_CR25 publication-title: Adv. Mater. doi: 10.1002/adma.201900248 contributor: fullname: J Wei – ident: 27505_CR38 doi: 10.1002/9780470517833 – volume: 479 start-page: 40 year: 2015 ident: 27505_CR53 publication-title: Anal. Biochem. doi: 10.1016/j.ab.2014.12.023 contributor: fullname: MB Maeß – volume: 32 start-page: 2001068 year: 2020 ident: 27505_CR44 publication-title: Adv. Mater. doi: 10.1002/adma.202001068 contributor: fullname: FC Meldrum – volume: 33 start-page: 2008119 year: 2021 ident: 27505_CR32 publication-title: Adv. Mater. doi: 10.1002/adma.202008119 contributor: fullname: S Deng – ident: 27505_CR47 – volume: 4 start-page: 3 year: 2017 ident: 27505_CR7 publication-title: Soft Robot. doi: 10.1089/soro.2016.0008 contributor: fullname: H Rodrigue – volume: 6 start-page: 197 year: 2006 ident: 27505_CR41 publication-title: Cryst. Growth Des. doi: 10.1021/cg050288+ contributor: fullname: S Elhadj – volume: 670 start-page: 184 year: 2018 ident: 27505_CR20 publication-title: Thermochim. Acta doi: 10.1016/j.tca.2018.10.009 contributor: fullname: N Beaupere – volume: 12 start-page: 3582 year: 2016 ident: 27505_CR11 publication-title: Soft Matter doi: 10.1039/C5SM02553B contributor: fullname: V Nistor – volume: 16 start-page: 1463 year: 2020 ident: 27505_CR3 publication-title: Soft Matter doi: 10.1039/C9SM02221J contributor: fullname: CT Zhang – volume: 411 start-page: 775 year: 2001 ident: 27505_CR40 publication-title: Nature doi: 10.1038/35081034 contributor: fullname: CA Orme – volume: 14 start-page: 3530 year: 2014 ident: 27505_CR4 publication-title: Lab. Chip doi: 10.1039/C4LC00568F contributor: fullname: F Benito-Lopez – volume: 7 start-page: 2277 year: 2019 ident: 27505_CR1 publication-title: Biomater. Sci. doi: 10.1039/C8BM01664J contributor: fullname: A Choi – volume: 29 start-page: 1347 year: 1999 ident: 27505_CR43 publication-title: Cem. Concr. Res. doi: 10.1016/S0008-8846(99)00002-2 contributor: fullname: GW Scherer – volume: 290 start-page: 1134 year: 2000 ident: 27505_CR39 publication-title: Science doi: 10.1126/science.290.5494.1134 contributor: fullname: KJ Davis – volume: 149 start-page: 272 year: 2010 ident: 27505_CR14 publication-title: Sens. Actuators B Chem. doi: 10.1016/j.snb.2010.06.017 contributor: fullname: Y Murase – volume: 54 start-page: 5434 year: 2015 ident: 27505_CR10 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201412160 contributor: fullname: AW Hauser – volume: 559 start-page: 77 year: 2018 ident: 27505_CR12 publication-title: Nature doi: 10.1038/s41586-018-0250-8 contributor: fullname: W Wang – volume: 2 start-page: 194 year: 2020 ident: 27505_CR9 publication-title: Matter doi: 10.1016/j.matt.2019.10.019 contributor: fullname: H Zeng – volume: 487 start-page: 214 year: 2012 ident: 27505_CR8 publication-title: Nature doi: 10.1038/nature11223 contributor: fullname: X He – volume: 5 start-page: 2000286 year: 2020 ident: 27505_CR30 publication-title: Adv. Mater. Technol. doi: 10.1002/admt.202000286 contributor: fullname: J Liu – volume: 76 start-page: 546 year: 2008 ident: 27505_CR21 publication-title: Am. J. Phys. doi: 10.1119/1.2830533 contributor: fullname: B Sandnes |
| SSID | ssj0000391844 |
| Score | 2.4902596 |
| Snippet | The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable... Abstract The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a... The crystallization of metastable liquid phase change materials releases stored energy upon nucleation. Here, the authors demonstrate area-selective activation... |
| SourceID | doaj pubmedcentral osti proquest crossref pubmed |
| SourceType | Open Website Open Access Repository Aggregation Database Index Database |
| StartPage | 259 |
| SubjectTerms | Acetic acid Aqueous solutions Crystal growth Crystallization Crystals Heat Heat transfer Heat waves Hydrogels Internal energy Latent heat Liquid phases Nucleation Phase change materials Photomasks Polyacrylamide Polymerization Sodium Sodium acetate Temperature gradients Wave generation Wave propagation |
| SummonAdditionalLinks | – databaseName: DOAJ Directory of Open Access Journals dbid: DOA link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1La9wwEBYlEOil9F03aVCht2IiRe9LoA0JodDSQwO5Cb28GyjesHFaNr8-M7Kz7JZCLz0ZW8JYM9boG2bmG0I-yBxdlEa3QSXVyshDa5XCLCvDc8zcJo3FyV-_6fML-eVSXW60-sKcsJEeeBTcIdOs5GxSTiFIHozrXOqYSEcdk0WlERpxteFMVRssHLgucqqSYcIe3shqEzAjASnNVXu3dRJVwn64LGBj_Q1s_pkzuXEInT0lTyb0SD-NX_2MPCr9c7I79pNcvSDH3ytbJlhOmpYrwH0_6Qzc7GFOQ58pml36O_wqdFa5plEl9Kqn81VeLmZwRr4kF2enP07O26lBQpvAfxxam4LQVgOEC7qo0hleGNyBhxJEslp1RZukmSi5WKU74WoQESQYUuwiDLwiO_2iL28ILVmpIKPBN8piknPY1CoqF20AO1Qa8vFBWP565MHwNX4trB9F60G0vorW3zXkM8pzPRM5rOsD0KyfNOv_pdmG7KE2PEAB5LNNmPiTBo-QTgjWkP0HJflp2914cAetkQ5O44a8Xw_DhsEoSOjL4rbOcVgvLG1DXo86XX8nRlnRS2-I2dL21kK2R_qreSXlBr8PsI58-z9WvkceH2GVBeMt5_tkZ1jelneAfYZ4UH_ze_f6AwM priority: 102 providerName: Directory of Open Access Journals – databaseName: ProQuest Health & Medical Collection dbid: 7X7 link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3daxNBEB9qRfCl-O3ZKiv4Jkfucvt1L5YqliAoPljI27JflxTkrk2vLelf78zeJRoRn0KyR9ib2Z39zc7MbwDe8eBqx5XMrfAi5660uRaCsqxUGVwotZdUnPz1m5yd8S9zMd-D2aYWhtIqNzYxGerQebojnyDS14rXaGgn1tEtgO8nxxeXOfWPojjr2EzjHtwvpwgrcGWrudrethAPuuZ8rJopKj254slGUIYCUZyL_G7nZEoE_vjR4Ub7F_j8O4fyj0Pp9BEcjGiSnQzqfwx7sX0CD4b-kuun8OF7Ys9ES8r8ao048CdboNvdL5ltAyMzzG7tTWSLxD1NKmLnLVuuw6pb4Jn5DM5OP__4NMvHhgm5R3-yz7W3ldQSIZ2VUcRGlbHAb-ix2MprKZoolZdFFUPUQjZVnYKKdVNb7xqHA89hv-3a-BJYDEJY7hT9I4_K1zU1uXKidtqiXYoZvN8Iy1wMvBgmxbMrbQbRGhStSaI1dxl8JHlunyRO6_RDt1qYcYuYQhYxBOWDt5aXVuG8fFNUftoUPApvMzgkbRiEBsRv6ykRyPeGIF5VFRkcbZRkxm14ZX4vmgzebodxA1FUxLaxu07P1FQ_zHUGLwadbudJUVfy2jNQO9reeZHdkfZ8mUi60Q9E7MNf_X9ah_BwSvUURZmX5RHs96vr-BpRTu_epAX8C4GI_FI priority: 102 providerName: ProQuest – databaseName: Scholars Portal Journals: Open Access dbid: M48 link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwEB6VIlAviGcJLchI3FAg2diOfQAEiKpCKuLASr1ZtuPsVqoSSFPa7a9nxklWLNoTpyixEznz_Eb2zAC84pXTjpcytcKLlLvcpkoIOmVV5pWrcuUlJSeffJPHc_71VJzuwNTuaCTgxdbQjvpJzbvzN9e_Vh9Q4d8NKePq7QWP6k6HDahauUhvbsHtGS84SfzJCPejZS40BjR8zJ3Z_uoe3KW9NorVNlxVrOiPlxY1bxsa_fdQ5V9e6ug-3BvhJfs4yMMD2AnNQ7gzNJxcPYL332M5TTStzHcrBIbnbIFxeL9ktqkY2WV2ZX8HtojFqIln7Kxhy1XVtQt0oo9hfvTlx-fjdOygkHoMMPtUeVtIJRHjWRlEqMs8ZHiHIYwtvJKiDrL0MitCFZSQdaHjLqOutfWudjjwBHabtglPgYVKCMtdSV_kofRaU9crJ7RTFg1VSOD1RCzzcyiUYeIGd6HMQGWDVDaRyuYmgU9Ez_VMKnIdH7Tdwow6YzKZhaoqfeWt5bktcV2-zgo_qzMehLcJHBA3DGIFKnjr6WSQ7w1hvqLIEjicmGQmsTIYL6qSa3TXCbxcD6NG0TaJbUJ7GedoSijmKoH9gafrdU6ikUC5we2NH9kcac6WsWo3BoYIhviz_37zAPZmlHuR5WmeH8Ju312G54iIevciivkf2QwJcQ priority: 102 providerName: Scholars Portal |
| Title | Patterned crystal growth and heat wave generation in hydrogels |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/35017471 https://www.proquest.com/docview/2618749123/abstract/ https://search.proquest.com/docview/2619209948 https://www.osti.gov/biblio/1839330 https://pubmed.ncbi.nlm.nih.gov/PMC8752664 https://doaj.org/article/060edd7cdcaa41a79f9cf03c2f04e5ca |
| Volume | 13 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1da9sw8Gg7NvpS9j23XfBgb8ONXX36ZZCWZiWQErYV8iYkWU4CrV1SdyP99TvJTmjGnvYiYUs28t3pPnwfAvhMC5MbKniimWUJNZlOJGM-ykpkhSkyablPTh5f8ctrOpqy6Q6wdS5MCNq3ZnFS3dyeVIt5iK28u7X9dZxYfzI-Rx0b5Qrt78KuIOSJiR7YL8nRaqFdgkxKZP-eBnbggxF8NXOWPO7DC-9Q8wbZljwKZfuxq3F7_Uvl_Dty8okoGr6Eg06HjAftWl_Bjqtew_P2VMnVG_g6CTUzkX_GdrlC7e8mnqGx3cxjXRWxZ77xb_3LxbNQcdojJl5U8XxVLOsZSsq3cD28-Hl-mXTHJCQWrcgmkVYTLjkqcpo75kqRuRSv0E7RxErOSseF5SlxhZOMlyQPrsS8zLU1pcGBd7BX1ZX7ALErGNPUCP9G6oTNc3-0lWG5kRq5kYvgyxpY6q6thqGCF5tI1UJZIZRVgLJ6jODMw3Mz01eyDjfq5Ux1-FQpT11RCFtYrWmmBa7Llimxp2VKHbM6giOPDYUKga9qa334j22UV-wISSM4XiNJdZvvXqFRKAXNUSZH8GkzjNvG-0J05eqHMCf3WcNURvC-xelmnWvSiEBsYXvrQ7ZHkFJDae6OMg__-8kj2D_1CRZplmTZMew1ywf3EdWexvSQ2KcCWzn81oNng8Hoxwj7s4uryfde-JWA7ZjKXtgOfwAKeQho |
| link.rule.ids | 230,315,733,786,790,870,891,2115,12083,12792,21416,24346,27957,27958,31754,31755,33408,33409,33779,33780,43345,43635,43840,53827,53829,74102,74392,74659 |
| linkProvider | National Library of Medicine |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1Lb9QwEB5BEYIL4k1oASNxQ1GT-pkLCBDVAm3FoZX2Zjm2s1sJJWU3BW1_PTNOdmER4hQljiJnxh5_4xl_A_BKhLqqhVa5k17moi5dbqSkLCtdhjqUxis6nHx8oiZn4vNUTscNt-WYVrm2iclQh87THvk-In2jRYWG9u3F95yqRlF0dSyhcR1uCM4FpfTpqd7ssRD7uRFiPCtTcLO_FMkyUF4CEZvL_GprPUq0_XjpcHr9C3L-nTn5x1J0eBfujBiSvRuUfg-uxfY-3ByqSq4ewJuviTMT7SfzixWiv29shs52P2euDYyML_vpfkQ2S4zTpBh23rL5Kiy6Ga6UD-Hs8OPph0k-lknIPXqRfW6848ooBHJORRkbXcYC79BPcdwbJZuotFcFjyEaqRpepVBi1VTO102NDY9gp-3a-ARYDFI6UWv6oojaVxWVtqplVRuH1ihm8HotLHsxsGHYFMXmxg6itSham0RrrzJ4T_LcvElM1ulBt5jZcWLYQhUxBO2Dd06UTmO_fFNwf9AUIkrvMtglbVgEBMRq6yn9x_eWgB3nRQZ7ayXZcfIt7e-hksHLTTNOG4qFuDZ2l-mdik4NC5PB40Gnm35SrJV89Qz0lra3fmS7pT2fJ2pu9P4Q8Yin_-_WC7g1OT0-skefTr7swu0DOlFRlHlZ7sFOv7iMzxDn9PXzNJh_AWz_-4U |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1Lb9NAEF5BKxAXxLOYFlgkbsiKXe_LFxCFRuUVRYhKva325aQSskvigtJfz8x6EwhCnCJnLWs9Mzv7jWf2G0JeMG9ry6TIDXc8Z7Y0ueIcq6xk6a0vlRN4OPnzRJycsg9n_CzVPy1TWeXaJ0ZH7TuH38hHgPSVZDU42lGTyiKm78avL77n2EEKM62pncZ1siuZ4GDhu0fHk-mXzRcX5EJXjKWTM0WlRksW_QRWKSDNOc-vtnanSOIPPx0stn8B0L_rKP_YmMZ3yO2EKOmbwQTukmuhvUduDD0mV_fJq2lk0ARvSt1iBVjwG51B6N3PqWk9RVdMf5ofgc4i_zSqiZ63dL7yi24G--YDcjo-_vr2JE9NE3IHMWWfK2cqoQTAOiMCD40sQwFXELWYyinBmyCkE0UVfFBcNFUdE4t1UxtnGwsDD8lO27XhEaHBc26YlfhEFqSra2x0ZXltlQHfFDLyci0sfTFwY-iY066UHkSrQbQ6ilZfZeQI5bm5E3mt4x_dYqbTMtGFKIL30nlnDCuNhHm5pqjcYVOwwJ3JyD5qQwM8QI5bh8VArtcI86qqyMjBWkk6LcWl_m04GXm-GYZFhJkR04buMt5T4xlipjKyN-h0M0_MvGLknhG5pe2tF9keac_nkagbYkHAP-zx_6f1jNwES9af3k8-7pNbh3i8oijzsjwgO_3iMjwB0NPbp8mafwGS8wE3 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Patterned+crystal+growth+and+heat+wave+generation+in+hydrogels&rft.jtitle=Nature+communications&rft.au=Schroeder%2C+Thomas+B.+H.&rft.au=Aizenberg%2C+Joanna&rft.date=2022-01-11&rft.pub=Nature+Publishing+Group+UK&rft.eissn=2041-1723&rft.volume=13&rft_id=info:doi/10.1038%2Fs41467-021-27505-z&rft_id=info%3Apmid%2F35017471&rft.externalDBID=PMC8752664 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2041-1723&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2041-1723&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2041-1723&client=summon |