Calcium polysulfide remediation of hexavalent chromium contamination from chromite ore processing residue
Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O 4 2−. Traditional methods of remediating Cr(VI)...
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| Published in | The Science of the total environment Vol. 364; no. 1; pp. 32 - 44 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Shannon
Elsevier B.V
01.07.2006
Elsevier Science |
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| Abstract | Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O
4
2−. Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS
x
) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8–12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS
x
. The potential for large-scale use of CaS
x
in the remediation of Cr(VI) from COPR is also discussed. |
|---|---|
| AbstractList | Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O
4
2−. Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS
x
) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8–12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS
x
. The potential for large-scale use of CaS
x
in the remediation of Cr(VI) from COPR is also discussed. Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O4(2-). Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS(x)) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS(x). The potential for large-scale use of CaS(x) in the remediation of Cr(VI) from COPR is also discussed.Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O4(2-). Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS(x)) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS(x). The potential for large-scale use of CaS(x) in the remediation of Cr(VI) from COPR is also discussed. Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O sub(4) super(2-). Traditional methods of remediating Cr(VI)- contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS sub(x)) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS sub(x). The potential for large-scale use of CaS sub(x) in the remediation of Cr(VI) from COPR is also discussed. The potential of CaS sub(x) through ha series of laboratory experiments for the treatment of Cr(VI) containing groundwater samples and the remediation of high pH COPR from contaminated sites in the Glasgow area was investigated. Collection of 1-1 groundwater samples from three boreholes was carried out on 1st September 2004. The purge volume, pH, electrical conductivity, depth to groundwater, depth to base of the well, and water sample description were recorded. Each groundwater sample was filtered through 0.45 mu m filters prior to initial analysis for Cr(VI) and total Cr by colorimetry. It was observed that both of the CaS sub(x) treatments were effective in the complete removal of Cr(VI) from BH601 from solution. Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O4 . Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaSx) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaSx. The potential for large-scale use of CaSx in the remediation of Cr(VI) from COPR is also discussed. Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O4(2-). Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS(x)) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS(x). The potential for large-scale use of CaS(x) in the remediation of Cr(VI) from COPR is also discussed. |
| Author | Hillier, Stephen Lumsdon, David G. Paterson, Edward Bewley, Richard J.F. Anderson, Peter Farmer, John G. Graham, Margaret C. |
| Author_xml | – sequence: 1 givenname: Margaret C. surname: Graham fullname: Graham, Margaret C. email: Margaret.Graham@ed.ac.uk organization: School of GeoSciences, Joseph Black Building, University of Edinburgh, Edinburgh EH9 3JJ, Scotland, UK – sequence: 2 givenname: John G. surname: Farmer fullname: Farmer, John G. organization: School of GeoSciences, Joseph Black Building, University of Edinburgh, Edinburgh EH9 3JJ, Scotland, UK – sequence: 3 givenname: Peter surname: Anderson fullname: Anderson, Peter organization: CLARRC, University of Edinburgh, Edinburgh EH9 3JN, Scotland, UK – sequence: 4 givenname: Edward surname: Paterson fullname: Paterson, Edward organization: The Macaulay Institute, Aberdeen AB15 8QH, Scotland, UK – sequence: 5 givenname: Stephen surname: Hillier fullname: Hillier, Stephen organization: The Macaulay Institute, Aberdeen AB15 8QH, Scotland, UK – sequence: 6 givenname: David G. surname: Lumsdon fullname: Lumsdon, David G. organization: The Macaulay Institute, Aberdeen AB15 8QH, Scotland, UK – sequence: 7 givenname: Richard J.F. surname: Bewley fullname: Bewley, Richard J.F. organization: URS Corporation Ltd., Manchester M1 6EJ, England, UK |
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| Keywords | Hexavalent chromium COPR Remediation Groundwater Calcium polysulfide Calcium Polysulfides Reducing agent Chromates Heavy metal Chemical reduction Industrial waste Decontamination Solid waste Water pollution Mining industry Chromium VI Ground water |
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| Snippet | Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and... The potential of CaS sub(x) through ha series of laboratory experiments for the treatment of Cr(VI) containing groundwater samples and the remediation of high... |
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| SubjectTerms | Applied sciences Calcium Compounds - chemistry Calcium polysulfide Carcinogens, Environmental - chemistry Chromium - chemistry COPR Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Exact sciences and technology Groundwater Groundwaters Hexavalent chromium Industrial Waste - analysis Metallurgy Natural water pollution Pollution Pollution, environment geology Remediation Scotland Sulfides - chemistry Thiosulfates - chemistry Waste Disposal, Fluid - methods Water Pollutants, Chemical - analysis Water Supply - analysis Water treatment and pollution |
| Title | Calcium polysulfide remediation of hexavalent chromium contamination from chromite ore processing residue |
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