Formal aryne/ethylene copolymerization to form polyethylene containing o-arylene units in the main chain

As chain-growth polymerization generally forms aliphatic main chains containing units such as alkylene and alkenylene, the method has rarely been applied to the construction of arylene units. Thus, the formation/introduction of arylene groups via chain-growth polymerization remains a challenging sub...

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Published inPolymer journal Vol. 47; no. 7; pp. 474 - 480
Main Authors Ito, Shingo, Wang, Wenhan, Nozaki, Kyoko
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 01.07.2015
Nature Publishing Group
Subjects
140/131
639/638/455/941
Addition polymerization
Aliphatic compounds
Alkenes
Biomaterials
Bioorganic Chemistry
Chains (polymeric)
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Copolymers
Dehydration
Equivalence
Ethylene
Ligands
Organic chemistry
original-article
Palladium
Phosphines
Polyethylenes
Polymer chemistry
Polymer Sciences
Polymerization
Surfaces and Interfaces
Thin Films
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Abstract As chain-growth polymerization generally forms aliphatic main chains containing units such as alkylene and alkenylene, the method has rarely been applied to the construction of arylene units. Thus, the formation/introduction of arylene groups via chain-growth polymerization remains a challenging subject in polymer chemistry. In this study, we report a formal aryne/ethylene copolymerization using [2.2.1]oxabicyclic alkenes as aryne equivalents. A palladium-catalyzed copolymerization of [2.2.1]oxabicyclic alkenes with ethylene followed by acid-promoted dehydration produced novel aryne/ethylene copolymers. The use of a bulky phosphine–sulfonate ligand was essential to obtain the desired copolymers with high molecular weight. We report a formal aryne/ethylene copolymerization using [2.2.1]oxabicyclic alkenes as aryne equivalents. A palladium-catalyzed copolymerization of [2.2.1]oxabicyclic alkenes with ethylene followed by acid-promoted dehydration produced novel aryne/ethylene copolymers. The use of a bulky phosphine–sulfonate ligand was essential to obtain the desired copolymers with high molecular weight. The present study provides a useful method for the introduction of o -arylene units into the main chains of polyethylene.
AbstractList As chain-growth polymerization generally forms aliphatic main chains containing units such as alkylene and alkenylene, the method has rarely been applied to the construction of arylene units. Thus, the formation/introduction of arylene groups via chain-growth polymerization remains a challenging subject in polymer chemistry. In this study, we report a formal aryne/ethylene copolymerization using [2.2.1]oxabicyclic alkenes as aryne equivalents. A palladium-catalyzed copolymerization of [2.2.1]oxabicyclic alkenes with ethylene followed by acid-promoted dehydration produced novel aryne/ethylene copolymers. The use of a bulky phosphine–sulfonate ligand was essential to obtain the desired copolymers with high molecular weight.
As chain-growth polymerization generally forms aliphatic main chains containing units such as alkylene and alkenylene, the method has rarely been applied to the construction of arylene units. Thus, the formation/introduction of arylene groups via chain-growth polymerization remains a challenging subject in polymer chemistry. In this study, we report a formal aryne/ethylene copolymerization using [2.2.1]oxabicyclic alkenes as aryne equivalents. A palladium-catalyzed copolymerization of [2.2.1]oxabicyclic alkenes with ethylene followed by acid-promoted dehydration produced novel aryne/ethylene copolymers. The use of a bulky phosphine–sulfonate ligand was essential to obtain the desired copolymers with high molecular weight. We report a formal aryne/ethylene copolymerization using [2.2.1]oxabicyclic alkenes as aryne equivalents. A palladium-catalyzed copolymerization of [2.2.1]oxabicyclic alkenes with ethylene followed by acid-promoted dehydration produced novel aryne/ethylene copolymers. The use of a bulky phosphine–sulfonate ligand was essential to obtain the desired copolymers with high molecular weight. The present study provides a useful method for the introduction of o -arylene units into the main chains of polyethylene.
Author Ito, Shingo
Wang, Wenhan
Nozaki, Kyoko
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  fullname: Nozaki, Kyoko
  organization: Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
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Cites_doi 10.1039/c3cc43603a
10.1021/ja502073k
10.1002/pola.24703
10.1002/(SICI)1099-0518(199703)35:4<741::AID-POLA19>3.0.CO;2-N
10.1002/anie.199215091
10.1021/ja964144i
10.1016/S0010-8545(01)00405-2
10.1021/ma2006427
10.1021/jo00162a013
10.1021/ja1092216
10.1021/ar300256h
10.1021/ja953247i
10.1016/j.ccr.2005.06.019
10.1021/ja505558e
10.1016/j.ccr.2007.11.023
10.1002/pola.22428
10.1021/om980176y
10.1021/ma100820z
10.1021/om0607402
10.1021/ma9500143
10.1021/ja9050839
10.1351/PAC-CON-12-03-13
10.1016/S0079-6700(01)00012-0
10.1021/om9503712
10.1002/marc.1985.030060401
10.1126/science.287.5452.460
10.1023/A:1026036100317
10.1021/ja5112207
10.1002/tcr.201000032
10.1021/ma202756y
10.1002/anie.201206096
10.1021/cr940282j
10.1016/j.ccr.2005.08.012
10.1021/ja00103a008
10.1002/marc.201200001
10.1021/ma048668b
10.1021/ma400525m
10.1002/marc.200700370
10.1021/ja00173a070
10.1021/cr990011e
10.1021/ma500034g
10.1021/cr900041c
10.1021/cr900079r
10.1201/9781482295467
10.1039/c2dt31771k
10.3390/catal3010157
10.1007/BF00963127
10.1021/ja00102a018
10.1021/ma061089h
10.1021/ol202236r
10.1021/ja00050a088
10.1021/ja303507t
10.1016/S0014-3057(01)00174-4
10.1016/j.ccr.2007.11.027
10.1016/0022-328X(94)05335-9
10.1295/polymj.20.383
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References Gin, Conticello, Grubbs (CR6) 1994; 116
Drent, Budzelaar (CR35) 1996; 96
Skupov, Marella, Hobbs, McIntosh, Goodall, Claverie (CR52) 2006; 39
Itoh, Matsumura, Kubo (CR15) 1997; 35
Wang, Friedrich, Younkin, Li, Grubbs, Bansleben, Day (CR43) 1998; 17
Conticello, Gin, Grubbs (CR7) 1992; 114
Nakamura, Ito, Nozaki (CR23) 2009; 109
Yokozawa, Nanashima, Kohno, Suzuki, Nojima, Ohta (CR9) 2013; 85
Pu, Wagaman, Grubbs (CR8) 1996; 29
Huang, Cheng (CR49) 1995; 490
Hosoda (CR56) 1988; 20
Durand, Milani (CR37) 2006; 250
Younkin, Connor, Henderson, Friedrich, Grubbs, Bansleben (CR48) 2000; 287
Rodrigues, Carpentier (CR25) 2008; 252
Ito, Ihara, Murakami (CR17) 1992; 31
Nakamura, Anselment, Claverie, Goodall, Jordan, Mecking, Rieger, Sen, van Leeuwen, Nozaki (CR30) 2013; 46
Oshimizu, Takahashi, Higashihara, Ueda (CR12) 2011; 49
LeHoullier, Gribble (CR41) 1983; 48
Skupov, Marella, Sismard, Yap, Allen, Conner, Goodall, Claverie (CR53) 2007; 28
Kalashnikova, Zhukov, Tomilova, Zefirov (CR39) 2003; 52
Li, Hou (CR28) 2008; 252
Segura, Martín (CR20) 1999; 99
Peacock (CR24) 2000
Grinshpun, Rudin (CR46) 1985; 6
Itoh (CR2) 2001; 26
Carrow, Nozaki (CR44) 2012; 134
Quijada, Scipioni, Mauler, Galland, Miranda (CR54) 1995; 35
Pangborn, Giardello, Grubbs, Rosen, Timmers (CR38) 1996; 15
Bunz, Mäker, Porz (CR1) 2012; 33
Gin, Conticello, Grubbs (CR5) 1994; 116
Ito, Ihara, Murakami, Shiro (CR16) 1990; 112
Bianchini, Meli (CR36) 2002; 225
Starck, Löfgren (CR55) 2002; 38
Chino, Endo (CR21) 2008; 46
Yokozawa, Ohta (CR10) 2013; 49
Ihara, Kurokawa, Koda, Muraki, Itoh, Inoue (CR18) 2005; 38
Ito, Kanazawa, Munakata, Kuroda, Okumura, Nozaki (CR32) 2011; 133
Ito, Nozaki (CR29) 2010; 10
Mizukoshi, Mikami, Uchiyama (CR19) 2015; 137
Johnson, Mecking, Brookhart (CR42) 1996; 118
Nanashima, Yokoyama, Yokozawa (CR13) 2012; 45
Liu, Borkar, Newsham, Yennawar, Sen (CR50) 2007; 26
Ito, Munakata, Nakamura, Nozaki (CR45) 2009; 131
Mecking, Johnson, Wang, Brookhart (CR47) 1998; 120
Ito, Ota, Nozaki (CR33) 2012; 41
Carrow, Nozaki (CR31) 2014; 47
Ito, Takahashi, Nozaki (CR22) 2014; 136
Ota, Ito, Kuroda, Okumura, Nozaki (CR34) 2014; 136
Murarka, Studer (CR14) 2012; 51
Waghray, Nulens, Dehaen (CR40) 2011; 13
Yokozawa, Yokoyama (CR11) 2009; 109
Ravasio, Boggioni, Tritto (CR51) 2011; 44
Mori, Tando, Tanaka (CR3) 2010; 43
Nakabayashi, Inoue, Abiko, Mori (CR4) 2013; 46
Nomura (CR26) 2013; 3
Tritto, Boggioni, Ferro (CR27) 2006; 250
S Murarka (BFpj201527_CR14) 2012; 51
LK Johnson (BFpj201527_CR42) 1996; 118
DL Gin (BFpj201527_CR6) 1994; 116
A Nakamura (BFpj201527_CR23) 2009; 109
T Yokozawa (BFpj201527_CR9) 2013; 85
S Liu (BFpj201527_CR50) 2007; 26
L Pu (BFpj201527_CR8) 1996; 29
I Tritto (BFpj201527_CR27) 2006; 250
BP Carrow (BFpj201527_CR44) 2012; 134
KM Skupov (BFpj201527_CR53) 2007; 28
S Mecking (BFpj201527_CR47) 1998; 120
H Mori (BFpj201527_CR3) 2010; 43
VP Conticello (BFpj201527_CR7) 1992; 114
T Yokozawa (BFpj201527_CR10) 2013; 49
D-J Huang (BFpj201527_CR49) 1995; 490
AB Pangborn (BFpj201527_CR38) 1996; 15
S Ito (BFpj201527_CR45) 2009; 131
D Waghray (BFpj201527_CR40) 2011; 13
CS LeHoullier (BFpj201527_CR41) 1983; 48
C Wang (BFpj201527_CR43) 1998; 17
K Nakabayashi (BFpj201527_CR4) 2013; 46
P Starck (BFpj201527_CR55) 2002; 38
Y Ota (BFpj201527_CR34) 2014; 136
J Durand (BFpj201527_CR37) 2006; 250
T Yokozawa (BFpj201527_CR11) 2009; 109
S Ito (BFpj201527_CR29) 2010; 10
A-S Rodrigues (BFpj201527_CR25) 2008; 252
AJ Peacock (BFpj201527_CR24) 2000
E Drent (BFpj201527_CR35) 1996; 96
K Nomura (BFpj201527_CR26) 2013; 3
KM Skupov (BFpj201527_CR52) 2006; 39
R Quijada (BFpj201527_CR54) 1995; 35
T Itoh (BFpj201527_CR15) 1997; 35
IP Kalashnikova (BFpj201527_CR39) 2003; 52
Y Nanashima (BFpj201527_CR13) 2012; 45
JL Segura (BFpj201527_CR20) 1999; 99
C Bianchini (BFpj201527_CR36) 2002; 225
X Li (BFpj201527_CR28) 2008; 252
E Ihara (BFpj201527_CR18) 2005; 38
A Nakamura (BFpj201527_CR30) 2013; 46
S Ito (BFpj201527_CR32) 2011; 133
K Chino (BFpj201527_CR21) 2008; 46
S Ito (BFpj201527_CR22) 2014; 136
A Ravasio (BFpj201527_CR51) 2011; 44
UHF Bunz (BFpj201527_CR1) 2012; 33
V Grinshpun (BFpj201527_CR46) 1985; 6
Y Ito (BFpj201527_CR16) 1990; 112
Y Ito (BFpj201527_CR17) 1992; 31
Y Mizukoshi (BFpj201527_CR19) 2015; 137
T Itoh (BFpj201527_CR2) 2001; 26
DL Gin (BFpj201527_CR5) 1994; 116
K Oshimizu (BFpj201527_CR12) 2011; 49
S Ito (BFpj201527_CR33) 2012; 41
S Hosoda (BFpj201527_CR56) 1988; 20
BP Carrow (BFpj201527_CR31) 2014; 47
TR Younkin (BFpj201527_CR48) 2000; 287
References_xml – volume: 49
  start-page: 8281
  year: 2013
  end-page: 8310
  ident: CR10
  article-title: Scope of controlled synthesis via chain-growth condensation polymerization: from aromatic polyamides to π-conjugated polymers
  publication-title: Chem. Commun.
  doi: 10.1039/c3cc43603a
– volume: 136
  start-page: 7547
  year: 2014
  end-page: 7550
  ident: CR22
  article-title: Formal aryne polymerization: use of [2.2.1]oxabicyclic alkenes as aryne equivalents
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja502073k
– volume: 49
  start-page: 2709
  year: 2011
  end-page: 2714
  ident: CR12
  article-title: Synthesis of poly( -phenylene) and poly( -phenylene)- -poly(3-hexylthiophene) with low polydispersities
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/pola.24703
– volume: 35
  start-page: 741
  year: 1997
  end-page: 746
  ident: CR15
  article-title: Polymerization of -naphthoquinone methide: 3,4-benzo-6-methylenebicyclo [3.1.0] hex-3-ene-2-one
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/(SICI)1099-0518(199703)35:4<741::AID-POLA19>3.0.CO;2-N
– volume: 31
  start-page: 1509
  year: 1992
  end-page: 1510
  ident: CR17
  article-title: Enantioselective polymerization of 1,2-diisocyanoarenes—synthesis of optically active, helical poly(quinoxaline-2,3-diyl)s
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.199215091
– volume: 120
  start-page: 888
  year: 1998
  end-page: 899
  ident: CR47
  article-title: Mechanistic studies of the palladium-catalyzed copolymerization of ethylene and α-olefins with methyl acrylate
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja964144i
– volume: 225
  start-page: 35
  year: 2002
  end-page: 66
  ident: CR36
  article-title: Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/S0010-8545(01)00405-2
– volume: 44
  start-page: 4180
  year: 2011
  end-page: 4186
  ident: CR51
  article-title: Copolymerization of ethylene with norbornene by neutral aryl phosphine sulfonate palladium catalyst
  publication-title: Macromolecules
  doi: 10.1021/ma2006427
– volume: 48
  start-page: 2364
  year: 1983
  end-page: 2366
  ident: CR41
  article-title: A convenient generation of 2,3-naphthalyne. Linear annulation of naphthalene and a new naphthacene synthesis
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00162a013
– volume: 133
  start-page: 1232
  year: 2011
  end-page: 1235
  ident: CR32
  article-title: Coordination−insertion copolymerization of allyl monomers with ethylene
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja1092216
– volume: 46
  start-page: 1438
  year: 2013
  end-page: 1449
  ident: CR30
  article-title: -phosphinobenzenesulfonate: a superb ligand for palladium-catalyzed coordination–insertion copolymerization of polar vinyl monomers
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar300256h
– volume: 118
  start-page: 267
  year: 1996
  end-page: 268
  ident: CR42
  article-title: Copolymerization of ethylene and propylene with functionalized vinyl monomers by palladium(II) catalysts
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja953247i
– volume: 250
  start-page: 212
  year: 2006
  end-page: 241
  ident: CR27
  article-title: Metallocene catalyzed ethene- and propene co-norbornene polymerization: mechanisms from a detailed microstructural analysis
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2005.06.019
– volume: 136
  start-page: 11898
  year: 2014
  end-page: 11901
  ident: CR34
  article-title: Quantification of the steric influence of alkylphosphine–sulfonate ligands on polymerization, leading to high-molecular-weight copolymers of ethylene and polar monomers
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja505558e
– volume: 252
  start-page: 2137
  year: 2008
  end-page: 2154
  ident: CR25
  article-title: Groups 3 and 4 single-site catalysts for styrene–ethylene and styrene–α-olefin copolymerization
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2007.11.023
– volume: 46
  start-page: 844
  year: 2008
  end-page: 850
  ident: CR21
  article-title: Polymerization of -quinodimethanes. V. Ionic polymerization of -quinodimethanes generated by thermal isomerization of corresponding benzocyclobutenes
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/pola.22428
– volume: 17
  start-page: 3149
  year: 1998
  end-page: 3151
  ident: CR43
  article-title: Neutral nickel(II)-based catalysts for ethylene polymerization
  publication-title: Organometallics
  doi: 10.1021/om980176y
– volume: 43
  start-page: 7011
  year: 2010
  end-page: 7020
  ident: CR3
  article-title: Synthesis and optoelectronic properties of alternating copolymers containing anthracene unit in the main chain by radical ring-opening polymerization
  publication-title: Macromolecules
  doi: 10.1021/ma100820z
– volume: 26
  start-page: 210
  year: 2007
  end-page: 216
  ident: CR50
  article-title: Synthesis of palladium complexes with an anionic P~O chelate and their use in copolymerization of ethene with functionalized norbornene derivatives: unusual functionality tolerance
  publication-title: Organometallics
  doi: 10.1021/om0607402
– volume: 29
  start-page: 1138
  year: 1996
  end-page: 1143
  ident: CR8
  article-title: Synthesis of poly(1,4-naphthylenevinylenes): metathesis polymerization of benzobarrelenes
  publication-title: Macromolecules
  doi: 10.1021/ma9500143
– volume: 131
  start-page: 14606
  year: 2009
  end-page: 14607
  ident: CR45
  article-title: Copolymerization of vinyl acetate with ethylene by palladium/alkylphosphine-sulfonate catalysts
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja9050839
– volume: 85
  start-page: 573
  year: 2013
  end-page: 587
  ident: CR9
  article-title: Catalyst-transfer condensation polymerization for precision synthesis of π-conjugated polymers
  publication-title: Pure Appl. Chem.
  doi: 10.1351/PAC-CON-12-03-13
– volume: 26
  start-page: 1019
  year: 2001
  end-page: 1059
  ident: CR2
  article-title: Polymerizations and polymers of quinonoid monomers
  publication-title: Prog. Polym. Sci.
  doi: 10.1016/S0079-6700(01)00012-0
– volume: 15
  start-page: 1518
  year: 1996
  end-page: 1520
  ident: CR38
  article-title: Safe and convenient procedure for solvent purification
  publication-title: Organometallics
  doi: 10.1021/om9503712
– volume: 6
  start-page: 219
  year: 1985
  end-page: 223
  ident: CR46
  article-title: Measurement of Mark-Houwink constants by size exclusion chromatography with a low angle laser light scattering detector
  publication-title: Makromol. Chem. Rapid
  doi: 10.1002/marc.1985.030060401
– volume: 287
  start-page: 460
  year: 2000
  end-page: 462
  ident: CR48
  article-title: Neutral, single-component nickel (II) polyolefin catalysts that tolerate heteroatoms
  publication-title: Science
  doi: 10.1126/science.287.5452.460
– volume: 52
  start-page: 1709
  year: 2003
  end-page: 1714
  ident: CR39
  article-title: Hexadecapropyloxy-substituted diphthalocyanine complexes of rare-earth elements: synthesis, spectroscopic and electrochemical studies
  publication-title: Russ. Chem. Bull.
  doi: 10.1023/A:1026036100317
– volume: 137
  start-page: 74
  year: 2015
  end-page: 77
  ident: CR19
  article-title: Aryne polymerization enabling straightforward synthesis of elusive poly( -arylene)s
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja5112207
– volume: 10
  start-page: 315
  year: 2010
  end-page: 325
  ident: CR29
  article-title: Coordination–insertion copolymerization of polar vinyl monomers by palladium catalysts
  publication-title: Chem. Rec.
  doi: 10.1002/tcr.201000032
– volume: 45
  start-page: 2609
  year: 2012
  end-page: 2613
  ident: CR13
  article-title: Synthesis of well-defined poly(2-alkoxypyridine-3,5-diyl) via Ni-catalyst-transfer condensation polymerization
  publication-title: Macromolecules
  doi: 10.1021/ma202756y
– volume: 51
  start-page: 12362
  year: 2012
  end-page: 12366
  ident: CR14
  article-title: Radical/anionic S 1-type polymerization for preparation of oligoarenes
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.201206096
– volume: 96
  start-page: 663
  year: 1996
  end-page: 682
  ident: CR35
  article-title: Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide
  publication-title: Chem. Rev.
  doi: 10.1021/cr940282j
– volume: 250
  start-page: 542
  year: 2006
  end-page: 560
  ident: CR37
  article-title: The role of nitrogen-donor ligands in the palladium-catalyzed polyketones synthesis
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2005.08.012
– volume: 116
  start-page: 10934
  year: 1994
  end-page: 10947
  ident: CR6
  article-title: Stereoregular precursors to poly( -phenylene) via transition-metal-catalyzed polymerization. 2. the effects of polymer stereochemistry and acid catalysts on precursor aromatization: a characterization study
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00103a008
– volume: 33
  start-page: 886
  year: 2012
  end-page: 910
  ident: CR1
  article-title: Alkene metathesis—a tool for the synthesis of conjugated polymers
  publication-title: Macromol. Rapid Commun.
  doi: 10.1002/marc.201200001
– volume: 38
  start-page: 2167
  year: 2005
  end-page: 2172
  ident: CR18
  article-title: Benzyne as a monomer for polymerization: alternating copolymerization of benzyne and pyridine to give novel polymers with -phenylene and 2,3-dihydropyridine units in the main chain
  publication-title: Macromolecules
  doi: 10.1021/ma048668b
– volume: 46
  start-page: 4790
  year: 2013
  end-page: 4798
  ident: CR4
  article-title: Polymers composed of alternating anthracene and pyridine containing units by radical ring-opening polymerization: controlled synthesis, optical properties, and metal complexes
  publication-title: Macromolecules
  doi: 10.1021/ma400525m
– volume: 28
  start-page: 2033
  year: 2007
  end-page: 2038
  ident: CR53
  article-title: Palladium aryl sulfonate phosphine catalysts for the copolymerization of acrylates with ethene
  publication-title: Macromol. Rapid Commun.
  doi: 10.1002/marc.200700370
– volume: 112
  start-page: 6446
  year: 1990
  end-page: 6447
  ident: CR16
  article-title: New living polymerization of 1,2-diisocyanoarenes via (quinoxalinyl)palladium complexes. Synthesis of poly(2,3-quinoxaline)
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00173a070
– volume: 99
  start-page: 3199
  year: 1999
  end-page: 3246
  ident: CR20
  article-title: -Quinodimethanes: efficient intermediates in organic synthesis
  publication-title: Chem. Rev.
  doi: 10.1021/cr990011e
– volume: 47
  start-page: 2541
  year: 2014
  end-page: 2555
  ident: CR31
  article-title: Transition-metal-catalyzed functional polyolefin synthesis: effecting control through chelating ancillary ligand design and mechanistic insights
  publication-title: Macromolecules
  doi: 10.1021/ma500034g
– volume: 109
  start-page: 5595
  year: 2009
  end-page: 5619
  ident: CR11
  article-title: Chain-growth condensation polymerization for the synthesis of well-defined condensation polymers and π-conjugated polymers
  publication-title: Chem. Rev.
  doi: 10.1021/cr900041c
– volume: 109
  start-page: 5215
  year: 2009
  end-page: 5244
  ident: CR23
  article-title: Coordination−insertion copolymerization of fundamental polar monomers
  publication-title: Chem. Rev.
  doi: 10.1021/cr900079r
– year: 2000
  ident: CR24
  publication-title: Handbook of Polyethylene: Structures, Properties, and Applications
  doi: 10.1201/9781482295467
– volume: 41
  start-page: 13807
  year: 2012
  end-page: 13809
  ident: CR33
  article-title: Ethylene/allyl monomer cooligomerization by nickel/phosphine–sulfonate catalysts
  publication-title: Dalton Trans.
  doi: 10.1039/c2dt31771k
– volume: 3
  start-page: 157
  year: 2013
  end-page: 175
  ident: CR26
  article-title: Half-titanocenes containing anionic ancillary donor ligands: effective catalyst precursors for ethylene/styrene copolymerization
  publication-title: Catalyst
  doi: 10.3390/catal3010157
– volume: 35
  start-page: 299
  year: 1995
  end-page: 306
  ident: CR54
  article-title: Synthesis and characterization of ethylene-1-hexene copolymers using homogeneous Ziegler-Natta catalysts
  publication-title: Polym. Bull.
  doi: 10.1007/BF00963127
– volume: 116
  start-page: 10507
  year: 1994
  end-page: 10519
  ident: CR5
  article-title: Stereoregular precursors to poly( -phenylene) via transition-metal-catalyzed polymerization. 1. Precursor design and synthesis
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00102a018
– volume: 39
  start-page: 4279
  year: 2006
  end-page: 4281
  ident: CR52
  article-title: Catalytic copolymerization of ethylene and norbornene in emulsion
  publication-title: Macromolecules
  doi: 10.1021/ma061089h
– volume: 13
  start-page: 5516
  year: 2011
  end-page: 5519
  ident: CR40
  article-title: Efficient synthesis of benzo fused tetrathia[7]helicenes
  publication-title: Org. Lett.
  doi: 10.1021/ol202236r
– volume: 114
  start-page: 9708
  year: 1992
  end-page: 9710
  ident: CR7
  article-title: Ring-opening metathesis polymerization of substituted bicyclo[2.2.2]octadienes: a new precursor route to poly(1,4-phenylenevinylene)
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00050a088
– volume: 134
  start-page: 8802
  year: 2012
  end-page: 8805
  ident: CR44
  article-title: Synthesis of functional polyolefins using cationic bisphosphine monoxide-palladium complexes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja303507t
– volume: 38
  start-page: 97
  year: 2002
  end-page: 107
  ident: CR55
  article-title: Thermal properties of ethylene/long chain α-olefin copolymers produced by metallocenes
  publication-title: Eur. Polym. J.
  doi: 10.1016/S0014-3057(01)00174-4
– volume: 252
  start-page: 1842
  year: 2008
  end-page: 1869
  ident: CR28
  article-title: Organometallic catalysts for copolymerization of cyclic olefins
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2007.11.027
– volume: 490
  start-page: C1
  year: 1995
  end-page: C7
  ident: CR49
  article-title: [2+2] Dimerization of norbornadiene and its derivatives in the presence of nickel complexes and zinc metal
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(94)05335-9
– volume: 20
  start-page: 383
  year: 1988
  end-page: 397
  ident: CR56
  article-title: Structural distribution of linear low-density polyethylenes
  publication-title: Polym. J.
  doi: 10.1295/polymj.20.383
– volume: 31
  start-page: 1509
  year: 1992
  ident: BFpj201527_CR17
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.199215091
– volume: 20
  start-page: 383
  year: 1988
  ident: BFpj201527_CR56
  publication-title: Polym. J.
  doi: 10.1295/polymj.20.383
– volume: 51
  start-page: 12362
  year: 2012
  ident: BFpj201527_CR14
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.201206096
– volume: 49
  start-page: 2709
  year: 2011
  ident: BFpj201527_CR12
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/pola.24703
– volume: 41
  start-page: 13807
  year: 2012
  ident: BFpj201527_CR33
  publication-title: Dalton Trans.
  doi: 10.1039/c2dt31771k
– volume: 39
  start-page: 4279
  year: 2006
  ident: BFpj201527_CR52
  publication-title: Macromolecules
  doi: 10.1021/ma061089h
– volume: 131
  start-page: 14606
  year: 2009
  ident: BFpj201527_CR45
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja9050839
– volume: 33
  start-page: 886
  year: 2012
  ident: BFpj201527_CR1
  publication-title: Macromol. Rapid Commun.
  doi: 10.1002/marc.201200001
– volume: 116
  start-page: 10507
  year: 1994
  ident: BFpj201527_CR5
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00102a018
– volume: 109
  start-page: 5595
  year: 2009
  ident: BFpj201527_CR11
  publication-title: Chem. Rev.
  doi: 10.1021/cr900041c
– volume: 43
  start-page: 7011
  year: 2010
  ident: BFpj201527_CR3
  publication-title: Macromolecules
  doi: 10.1021/ma100820z
– volume: 38
  start-page: 2167
  year: 2005
  ident: BFpj201527_CR18
  publication-title: Macromolecules
  doi: 10.1021/ma048668b
– volume: 38
  start-page: 97
  year: 2002
  ident: BFpj201527_CR55
  publication-title: Eur. Polym. J.
  doi: 10.1016/S0014-3057(01)00174-4
– volume: 48
  start-page: 2364
  year: 1983
  ident: BFpj201527_CR41
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00162a013
– volume: 28
  start-page: 2033
  year: 2007
  ident: BFpj201527_CR53
  publication-title: Macromol. Rapid Commun.
  doi: 10.1002/marc.200700370
– volume: 26
  start-page: 1019
  year: 2001
  ident: BFpj201527_CR2
  publication-title: Prog. Polym. Sci.
  doi: 10.1016/S0079-6700(01)00012-0
– volume: 99
  start-page: 3199
  year: 1999
  ident: BFpj201527_CR20
  publication-title: Chem. Rev.
  doi: 10.1021/cr990011e
– volume: 109
  start-page: 5215
  year: 2009
  ident: BFpj201527_CR23
  publication-title: Chem. Rev.
  doi: 10.1021/cr900079r
– volume: 134
  start-page: 8802
  year: 2012
  ident: BFpj201527_CR44
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja303507t
– volume: 252
  start-page: 2137
  year: 2008
  ident: BFpj201527_CR25
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2007.11.023
– volume-title: Handbook of Polyethylene: Structures, Properties, and Applications
  year: 2000
  ident: BFpj201527_CR24
  doi: 10.1201/9781482295467
– volume: 116
  start-page: 10934
  year: 1994
  ident: BFpj201527_CR6
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00103a008
– volume: 52
  start-page: 1709
  year: 2003
  ident: BFpj201527_CR39
  publication-title: Russ. Chem. Bull.
  doi: 10.1023/A:1026036100317
– volume: 118
  start-page: 267
  year: 1996
  ident: BFpj201527_CR42
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja953247i
– volume: 137
  start-page: 74
  year: 2015
  ident: BFpj201527_CR19
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja5112207
– volume: 35
  start-page: 741
  year: 1997
  ident: BFpj201527_CR15
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/(SICI)1099-0518(199703)35:4<741::AID-POLA19>3.0.CO;2-N
– volume: 136
  start-page: 7547
  year: 2014
  ident: BFpj201527_CR22
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja502073k
– volume: 3
  start-page: 157
  year: 2013
  ident: BFpj201527_CR26
  publication-title: Catalyst
  doi: 10.3390/catal3010157
– volume: 10
  start-page: 315
  year: 2010
  ident: BFpj201527_CR29
  publication-title: Chem. Rec.
  doi: 10.1002/tcr.201000032
– volume: 96
  start-page: 663
  year: 1996
  ident: BFpj201527_CR35
  publication-title: Chem. Rev.
  doi: 10.1021/cr940282j
– volume: 49
  start-page: 8281
  year: 2013
  ident: BFpj201527_CR10
  publication-title: Chem. Commun.
  doi: 10.1039/c3cc43603a
– volume: 13
  start-page: 5516
  year: 2011
  ident: BFpj201527_CR40
  publication-title: Org. Lett.
  doi: 10.1021/ol202236r
– volume: 114
  start-page: 9708
  year: 1992
  ident: BFpj201527_CR7
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00050a088
– volume: 17
  start-page: 3149
  year: 1998
  ident: BFpj201527_CR43
  publication-title: Organometallics
  doi: 10.1021/om980176y
– volume: 46
  start-page: 4790
  year: 2013
  ident: BFpj201527_CR4
  publication-title: Macromolecules
  doi: 10.1021/ma400525m
– volume: 85
  start-page: 573
  year: 2013
  ident: BFpj201527_CR9
  publication-title: Pure Appl. Chem.
  doi: 10.1351/PAC-CON-12-03-13
– volume: 136
  start-page: 11898
  year: 2014
  ident: BFpj201527_CR34
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja505558e
– volume: 44
  start-page: 4180
  year: 2011
  ident: BFpj201527_CR51
  publication-title: Macromolecules
  doi: 10.1021/ma2006427
– volume: 46
  start-page: 844
  year: 2008
  ident: BFpj201527_CR21
  publication-title: J. Polym. Sci. A: Polym. Chem.
  doi: 10.1002/pola.22428
– volume: 225
  start-page: 35
  year: 2002
  ident: BFpj201527_CR36
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/S0010-8545(01)00405-2
– volume: 47
  start-page: 2541
  year: 2014
  ident: BFpj201527_CR31
  publication-title: Macromolecules
  doi: 10.1021/ma500034g
– volume: 112
  start-page: 6446
  year: 1990
  ident: BFpj201527_CR16
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00173a070
– volume: 250
  start-page: 212
  year: 2006
  ident: BFpj201527_CR27
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2005.06.019
– volume: 6
  start-page: 219
  year: 1985
  ident: BFpj201527_CR46
  publication-title: Makromol. Chem. Rapid
  doi: 10.1002/marc.1985.030060401
– volume: 46
  start-page: 1438
  year: 2013
  ident: BFpj201527_CR30
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar300256h
– volume: 120
  start-page: 888
  year: 1998
  ident: BFpj201527_CR47
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja964144i
– volume: 490
  start-page: C1
  year: 1995
  ident: BFpj201527_CR49
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(94)05335-9
– volume: 250
  start-page: 542
  year: 2006
  ident: BFpj201527_CR37
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2005.08.012
– volume: 15
  start-page: 1518
  year: 1996
  ident: BFpj201527_CR38
  publication-title: Organometallics
  doi: 10.1021/om9503712
– volume: 45
  start-page: 2609
  year: 2012
  ident: BFpj201527_CR13
  publication-title: Macromolecules
  doi: 10.1021/ma202756y
– volume: 26
  start-page: 210
  year: 2007
  ident: BFpj201527_CR50
  publication-title: Organometallics
  doi: 10.1021/om0607402
– volume: 133
  start-page: 1232
  year: 2011
  ident: BFpj201527_CR32
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja1092216
– volume: 35
  start-page: 299
  year: 1995
  ident: BFpj201527_CR54
  publication-title: Polym. Bull.
  doi: 10.1007/BF00963127
– volume: 252
  start-page: 1842
  year: 2008
  ident: BFpj201527_CR28
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2007.11.027
– volume: 287
  start-page: 460
  year: 2000
  ident: BFpj201527_CR48
  publication-title: Science
  doi: 10.1126/science.287.5452.460
– volume: 29
  start-page: 1138
  year: 1996
  ident: BFpj201527_CR8
  publication-title: Macromolecules
  doi: 10.1021/ma9500143
SSID ssj0026504
Score 2.108408
Snippet As chain-growth polymerization generally forms aliphatic main chains containing units such as alkylene and alkenylene, the method has rarely been applied to...
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SubjectTerms 140/131
639/638/455/941
Addition polymerization
Aliphatic compounds
Alkenes
Biomaterials
Bioorganic Chemistry
Chains (polymeric)
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Copolymers
Dehydration
Equivalence
Ethylene
Ligands
Organic chemistry
original-article
Palladium
Phosphines
Polyethylenes
Polymer chemistry
Polymer Sciences
Polymerization
Surfaces and Interfaces
Thin Films
Title Formal aryne/ethylene copolymerization to form polyethylene containing o-arylene units in the main chain
URI https://link.springer.com/article/10.1038/pj.2015.27
https://www.proquest.com/docview/1693687321
https://www.proquest.com/docview/2331642966
https://www.proquest.com/docview/1709767912
Volume 47
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