Isomer-free: Precise Positioning of Chlorine-Induced Interpenetrating Charge Transfer for Elevated Solar Conversion

The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a...

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Published iniScience Vol. 17; pp. 302 - 314
Main Authors Lai, Hanjian, Chen, Hui, Zhou, Jiadong, Qu, Jianfei, Chao, Pengjie, Liu, Tao, Chang, Xiaoyong, Zheng, Nan, Xie, Zengqi, He, Feng
Format Journal Article
LanguageEnglish
Published United States Elsevier Inc 26.07.2019
Elsevier
Subjects
Chemical Synthesis
Energy Storage
Materials Characterization Techniques
Energy Storage
Chemical Synthesis
Materials Characterization Techniques
Online AccessGet full text
ISSN2589-0042
2589-0042
DOI10.1016/j.isci.2019.06.033

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Abstract The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells. [Display omitted] •Isomer-free: improved phase purity for high-performance non-fullerene acceptor•Chlorine-substitution fine-tuned the configurations and properties of molecules•Precise Cl-atom substitution induced 3D interpenetrating network charge transfer•ITIC-2Cl-γ exhibited higher PCE of 13.03% and better stability Energy Storage; Chemical Synthesis; Materials Characterization Techniques
AbstractList The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells.The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells.
The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors ( ITIC-2Cl-δ and ITIC-2Cl-γ ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ . The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl- m -based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ -based device. In addition, the ITIC-2Cl-γ -based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells. • Isomer-free: improved phase purity for high-performance non-fullerene acceptor • Chlorine-substitution fine-tuned the configurations and properties of molecules • Precise Cl-atom substitution induced 3D interpenetrating network charge transfer • ITIC-2Cl-γ exhibited higher PCE of 13.03% and better stability Energy Storage; Chemical Synthesis; Materials Characterization Techniques
The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells. [Display omitted] •Isomer-free: improved phase purity for high-performance non-fullerene acceptor•Chlorine-substitution fine-tuned the configurations and properties of molecules•Precise Cl-atom substitution induced 3D interpenetrating network charge transfer•ITIC-2Cl-γ exhibited higher PCE of 13.03% and better stability Energy Storage; Chemical Synthesis; Materials Characterization Techniques
The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells.
The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated. The single-crystal structures show that ITIC-2Cl-γ has a better molecular planarity and closer π-π interaction distance. More importantly, a 3D rectangle-like interpenetrating network is formed in ITIC-2Cl-γ and is beneficial to rapid charge transfer along multiple directions, whereas only a linear stacked structure could be observed in ITIC-2Cl-δ. The two acceptor-based solar cells show power conversion efficiencies (PCEs) over 11%, higher than that of the ITIC-2Cl-m-based device (10.85%). An excellent PCE of 13.03% is obtained by the ITIC-2Cl-γ-based device. In addition, the ITIC-2Cl-γ-based device also shows the best device stability. This study indicates that chlorine positioning has a great impact on the acceptors; more importantly, the 3D network structure may be a promising strategy for non-fullerene acceptors to improve the PCE and stability of organic solar cells. : Energy Storage; Chemical Synthesis; Materials Characterization Techniques Subject Areas: Energy Storage, Chemical Synthesis, Materials Characterization Techniques
Author Zhou, Jiadong
Chen, Hui
Chang, Xiaoyong
Zheng, Nan
Chao, Pengjie
Lai, Hanjian
Xie, Zengqi
He, Feng
Qu, Jianfei
Liu, Tao
AuthorAffiliation 2 School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
3 Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
1 Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, China
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/31323476$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1021/acsami.8b15923
10.1073/pnas.1807535115
10.1021/acs.accounts.5b00199
10.1021/jacs.7b01493
10.1002/adma.201800868
10.1038/s41566-018-0104-9
10.1002/adma.201707150
10.1038/ncomms6293
10.1002/adma.201707508
10.1021/jacs.7b01170
10.1002/aenm.201801203
10.1002/adma.201703527
10.1038/nenergy.2015.27
10.1038/nmat5063
10.1038/s41560-018-0134-z
10.1021/jacs.7b13239
10.1002/adma.201803045
10.1038/nphoton.2015.6
10.1002/solr.201700044
10.1021/jacs.7b11278
10.1021/acs.chemmater.6b04828
10.1021/jacs.6b09110
10.1021/acs.chemmater.7b02853
10.1021/ja508472j
10.1007/s11426-017-9199-1
10.1038/nphoton.2015.126
10.1002/adma.201700144
10.1007/s11426-018-9260-2
10.1021/acs.accounts.6b00576
10.1002/aenm.201702870
10.1016/j.nanoen.2018.04.002
10.1039/C8TA12465E
10.1016/j.scib.2017.10.017
10.1016/j.scib.2018.02.015
10.1039/C7QM00025A
10.1002/adma.201800052
10.1002/adma.201707170
10.1039/C7TA09837E
10.1002/aenm.201800204
10.1021/jacs.8b01463
10.1039/C7TA10461H
10.1002/adma.201702125
10.1002/adma.201701156
10.1021/jacs.8b13653
10.1038/ncomms11585
10.1021/jacs.8b04027
10.1002/adma.201404317
10.1002/adma.201703973
10.1002/adma.201703080
10.1039/C8TA03753A
10.1002/adma.201704904
10.1021/jacs.6b00853
10.1002/adma.201705209
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Keywords Energy Storage
Chemical Synthesis
Materials Characterization Techniques
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References Cha, Wu, Wadsworth, Nagitta, Limbu, Pont, Li, Searle, Wyatt, Baran (bib3) 2017; 29
Li, Lin, Che, Qu, Liu, Liao, Forrest (bib24) 2017; 139
Shi, Zuo, Jo, Gao, Lin, Liu, Jen (bib37) 2017; 29
Li, Xiao, Ding, Wang (bib25) 2018; 63
Zhao, Li, Yang, Jiang, Lin, Ade, Ma, Yan (bib57) 2016; 1
Lin, He, Zhao, Huo, Mai, Lu, Su, Li, Wang, Zhu (bib31) 2016; 138
Zhao, Dai, Wu, Zhang, Wang, Jiang, Ling, Wei, Ma, You (bib58) 2017; 29
Gao, Yao, Jang, Zhu, Yu, Cui, Wang, Hou, Woo, Hou (bib15) 2018; 6
Cheng, Li, Zhan, Yang (bib7) 2018; 12
Kan, Feng, Wan, Liu, Ke, Wang, Wang, Zhang, Li, Hou, Chen (bib20) 2017; 139
Feng, Zhang, Liu, Bi, Zhang, Xu, Ma, Bo (bib13) 2017; 29
Yao, Liao, Gao, Lin, Xu, Shi, Zuo, Liu, Chen, Jen (bib52) 2018; 140
Cui, Yang, Yao, Zhu, Wang, Jia, Gao, Hou (bib9) 2017; 29
Fei, Eisner, Jiao, Azzouzi, Rohr, Han, Shahid, Chesman, Easton, McNeill (bib12) 2018; 30
Lin, Wang, Zhang, Bai, Li, Zhu, Zhan (bib30) 2015; 27
Li, Ye, Li, Yao, Ade, Hou (bib27) 2018; 30
Fan, Zhu, Xu, Su, Chen, Wu, Guo, Ma, Zhang, Li (bib10) 2018; 48
Xie, Liu, Gao, Zhong, Huo, Luo, Wu, Xiong, Liu, Sun, Yang (bib46) 2017; 1
Hou, Inganas, Friend, Gao (bib19) 2018; 17
Wadsworth, Moser, Marks, Little, Gasparini, Brabec, Baran, McCulloch (bib40) 2018
Che, Li, Qu, Forrest (bib5) 2018; 3
Wang, Zhang, Qiu, Feng, Gao, Kan, Ma, Li, Wan, Chen (bib42) 2018; 8
Qu, Chen, Zhou, Lai, Liu, Chao, Li, Xie, He, Ma (bib36) 2018; 10
Yang, Li, Lai, Zhang, Huang, Li (bib51) 2017; 1
Wang, Wang, Wang, Wu, Zhang, Yan, Ma, You, Zhan (bib41) 2017; 29
Yang, Zhang, Bin, Chen, Gao, Xue, Yang, Li (bib50) 2016; 138
Zhang, Yao, Zhang, Qin, Zhang, Yang, Li, Wei, Gao, Hou (bib55) 2018; 61
Gao, Zhang, Liu, Ming, An, Wu, Xie, Luo, Zhong, Liu (bib14) 2018; 30
Holliday, Ashraf, Wadsworth, Baran, Yousaf, Nielsen, Tan, Dimitrov, Shang, Gasparini, Alamoudi (bib18) 2016; 7
Cui, Yao, Gao, Qin, Zhang, Yang, He, Xu, Hou (bib8) 2017; 139
Fan, Su, Wang, Guo, Jiang, Guo, Liu, Russell, Zhang, Li (bib11) 2018; 61
Xu, Yu, Bi, Ma, Li, Peng (bib48) 2018; 30
Kan, Zhang, Liu, Wan, Li, Ke, Wang, Feng, Zhang, Long (bib21) 2017; 30
Swick, Zhu, Matta, Aldrich, Harbuzaru, Lopez Navarrete, Ponce Ortiz, Kohlstedt, Schatz, Facchetti, Marks (bib39) 2018; 115
Wang, Cao, Yu, Zhang, Geng, Yang, Tang (bib44) 2019; 7
Li, Ye, Zhao, Yan, Yang, Liu, Li, Ade, Hou (bib26) 2018; 30
Nielsen, Holliday, Chen, Cryer, McCulloch (bib34) 2015; 48
Ouyang, Peng, Ai, Zhang, Ge (bib35) 2015; 9
He, Xiao, Liu, Wu, Yang, Xiao, Wang, Russell, Cao (bib16) 2015; 9
Xiao, Jia, Li, Wang, Geng, Liu, Chen, Yang, Russell, Ding (bib45) 2017; 62
Wang, Zhang, Xiao, Xiao, Zhu, Yan, Fu, Lu, Lu, Marder, Zhan (bib43) 2018; 140
Zhang, Kan, Sun, Wang, Xia, Ke, Yi, Li, Yip, Wan (bib54) 2018; 30
Li, Earmme, Ren, Saeki, Yoshikawa, Murari, Subramaniyan, Crane, Seki, Jenekhe (bib23) 2014; 136
Chen, Liu, Hu, Ma, Lai, Zhang, Ade, Yan (bib6) 2018; 8
Cai, Xie, Zhang, Shi, Yan, Zhao (bib2) 2018; 140
Li, Zhan, Zhao, Zhang, Ali, Fu, Lau, Liu, Shi, Li (bib28) 2018; 6
Zhang, Yao, Hou, Zhu, Zhang, Li, Yu, Gao, Zhang, Hou (bib53) 2018; 30
Yan, Liu, Yao, Zhan (bib49) 2018; 8
Hestand, Spano (bib17) 2017; 50
Zhang, Qin, Zhu, Hou (bib56) 2018; 30
Liu, Zhao, Li, Mu, Ma, Hu, Jiang, Lin, Ade, Yan (bib32) 2014; 5
Sun, Ma, Zhang, Yu, Zhou, Yin, Yang, Geng, Zhu, Zhang, Tang (bib38) 2018; 30
Mo, Wang, Chen, Qu, Chao, Yang, Tian, Su, Gao, Yang (bib33) 2017; 29
Aldrich, Matta, Zhu, Swick, Stern, Schatz, Facchetti, Melkonyan, Marks (bib1) 2019; 141
Xie, Yang, Li, Uddin, Bi, Fan, Cai, Hao, Woo, Li (bib47) 2018; 30
Chao, Wang, Mo, Meng, Chen, He (bib4) 2018; 6
He (10.1016/j.isci.2019.06.033_bib16) 2015; 9
Kan (10.1016/j.isci.2019.06.033_bib20) 2017; 139
Zhao (10.1016/j.isci.2019.06.033_bib58) 2017; 29
Zhang (10.1016/j.isci.2019.06.033_bib56) 2018; 30
Che (10.1016/j.isci.2019.06.033_bib5) 2018; 3
Feng (10.1016/j.isci.2019.06.033_bib13) 2017; 29
Qu (10.1016/j.isci.2019.06.033_bib36) 2018; 10
Lin (10.1016/j.isci.2019.06.033_bib31) 2016; 138
Kan (10.1016/j.isci.2019.06.033_bib21) 2017; 30
Wang (10.1016/j.isci.2019.06.033_bib44) 2019; 7
Sun (10.1016/j.isci.2019.06.033_bib38) 2018; 30
Li (10.1016/j.isci.2019.06.033_bib25) 2018; 63
Xie (10.1016/j.isci.2019.06.033_bib47) 2018; 30
Shi (10.1016/j.isci.2019.06.033_bib37) 2017; 29
Hestand (10.1016/j.isci.2019.06.033_bib17) 2017; 50
Yao (10.1016/j.isci.2019.06.033_bib52) 2018; 140
Ouyang (10.1016/j.isci.2019.06.033_bib35) 2015; 9
Li (10.1016/j.isci.2019.06.033_bib28) 2018; 6
Gao (10.1016/j.isci.2019.06.033_bib15) 2018; 6
Wang (10.1016/j.isci.2019.06.033_bib42) 2018; 8
Fei (10.1016/j.isci.2019.06.033_bib12) 2018; 30
Yang (10.1016/j.isci.2019.06.033_bib50) 2016; 138
Li (10.1016/j.isci.2019.06.033_bib27) 2018; 30
Gao (10.1016/j.isci.2019.06.033_bib14) 2018; 30
Zhang (10.1016/j.isci.2019.06.033_bib55) 2018; 61
Lin (10.1016/j.isci.2019.06.033_bib30) 2015; 27
Zhang (10.1016/j.isci.2019.06.033_bib54) 2018; 30
Xie (10.1016/j.isci.2019.06.033_bib46) 2017; 1
Cai (10.1016/j.isci.2019.06.033_bib2) 2018; 140
Li (10.1016/j.isci.2019.06.033_bib23) 2014; 136
Cui (10.1016/j.isci.2019.06.033_bib9) 2017; 29
Swick (10.1016/j.isci.2019.06.033_bib39) 2018; 115
Fan (10.1016/j.isci.2019.06.033_bib11) 2018; 61
Liu (10.1016/j.isci.2019.06.033_bib32) 2014; 5
Chen (10.1016/j.isci.2019.06.033_bib6) 2018; 8
Mo (10.1016/j.isci.2019.06.033_bib33) 2017; 29
Xiao (10.1016/j.isci.2019.06.033_bib45) 2017; 62
Yan (10.1016/j.isci.2019.06.033_bib49) 2018; 8
Chao (10.1016/j.isci.2019.06.033_bib4) 2018; 6
Li (10.1016/j.isci.2019.06.033_bib24) 2017; 139
Xu (10.1016/j.isci.2019.06.033_bib48) 2018; 30
Wang (10.1016/j.isci.2019.06.033_bib41) 2017; 29
Zhang (10.1016/j.isci.2019.06.033_bib53) 2018; 30
Cheng (10.1016/j.isci.2019.06.033_bib7) 2018; 12
Hou (10.1016/j.isci.2019.06.033_bib19) 2018; 17
Holliday (10.1016/j.isci.2019.06.033_bib18) 2016; 7
Fan (10.1016/j.isci.2019.06.033_bib10) 2018; 48
Cui (10.1016/j.isci.2019.06.033_bib8) 2017; 139
Wang (10.1016/j.isci.2019.06.033_bib43) 2018; 140
Zhao (10.1016/j.isci.2019.06.033_bib57) 2016; 1
Aldrich (10.1016/j.isci.2019.06.033_bib1) 2019; 141
Li (10.1016/j.isci.2019.06.033_bib26) 2018; 30
Nielsen (10.1016/j.isci.2019.06.033_bib34) 2015; 48
Cha (10.1016/j.isci.2019.06.033_bib3) 2017; 29
Yang (10.1016/j.isci.2019.06.033_bib51) 2017; 1
Wadsworth (10.1016/j.isci.2019.06.033_bib40) 2018
References_xml – volume: 7
  start-page: 4313
  year: 2019
  end-page: 4333
  ident: bib44
  article-title: Molecular engineering of central fused-ring cores of non-fullerene acceptors for high-efficiency organic solar cells
  publication-title: J. Mater. Chem. A
– volume: 1
  start-page: 1700044
  year: 2017
  ident: bib46
  article-title: A novel thiophene-fused ending group enabling an excellent small molecule acceptor for high-performance fullerene-free polymer solar cells with 11.8% efficiency
  publication-title: Solar RRL
– volume: 138
  start-page: 15011
  year: 2016
  end-page: 15018
  ident: bib50
  article-title: Side-chain isomerization on an n-type organic semiconductor ITIC acceptor makes 11.77% high efficiency polymer solar cells
  publication-title: J. Am. Chem. Soc.
– volume: 29
  start-page: 1701156
  year: 2017
  ident: bib3
  article-title: An efficient, “Burn in” free organic solar cell employing a nonfullerene electron acceptor
  publication-title: Adv. Mater.
– volume: 29
  start-page: 1702125
  year: 2017
  ident: bib41
  article-title: Enhancing performance of nonfullerene acceptors via side-chain conjugation strategy
  publication-title: Adv. Mater.
– volume: 140
  start-page: 5764
  year: 2018
  end-page: 5773
  ident: bib2
  article-title: Concurrent cooperative J-aggregates and anticooperative H-aggregates
  publication-title: J. Am. Chem. Soc.
– volume: 141
  start-page: 3274
  year: 2019
  end-page: 3287
  ident: bib1
  article-title: Fluorination effects on indacenodithienothiophene acceptor packing and electronic structure, end-group redistribution, and solar cell photovoltaic response
  publication-title: J. Am. Chem. Soc.
– volume: 30
  start-page: 1707508
  year: 2018
  ident: bib54
  article-title: Nonfullerene tandem organic solar cells with high performance of 14.11
  publication-title: Adv. Mater.
– volume: 139
  start-page: 7302
  year: 2017
  end-page: 7309
  ident: bib8
  article-title: Fine-tuned photoactive and interconnection layers for achieving over 13% efficiency in a fullerene-free tandem organic solar cell
  publication-title: J. Am. Chem. Soc.
– volume: 5
  start-page: 5293
  year: 2014
  ident: bib32
  article-title: Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells
  publication-title: Nat. Commun.
– volume: 63
  start-page: 340
  year: 2018
  end-page: 342
  ident: bib25
  article-title: Thermostable single-junction organic solar cells with a power conversion efficiency of 14.62%
  publication-title: Sci. Bull.
– volume: 140
  start-page: 2054
  year: 2018
  end-page: 2057
  ident: bib52
  article-title: Dithienopicenocarbazole-based acceptors for efficient organic solar cells with optoelectronic response over 1000 nm and an extremely low energy loss
  publication-title: J. Am. Chem. Soc.
– volume: 8
  start-page: 1801203
  year: 2018
  ident: bib6
  article-title: Modulation of end groups for low-bandgap nonfullerene acceptors enabling high-performance organic solar cells
  publication-title: Adv. Energy Mater.
– volume: 6
  start-page: 2664
  year: 2018
  end-page: 2670
  ident: bib15
  article-title: The crucial role of intermolecular π–π interactions in A–D–A-type electron acceptors and their effective modulation
  publication-title: J. Mater. Chem. A
– volume: 29
  start-page: 1700144
  year: 2017
  ident: bib58
  article-title: Single-junction binary-blend nonfullerene polymer solar cells with 12.1% efficiency
  publication-title: Adv. Mater.
– volume: 29
  start-page: 1703527
  year: 2017
  ident: bib13
  article-title: Fused-ring acceptors with asymmetric side chains for high-performance thick-film organic solar cells
  publication-title: Adv. Mater.
– volume: 50
  start-page: 341
  year: 2017
  end-page: 350
  ident: bib17
  article-title: Molecular aggregate photophysics beyond the Kasha Model: novel design principles for organic materials
  publication-title: Acc. Chem. Res.
– volume: 140
  start-page: 9140
  year: 2018
  end-page: 9147
  ident: bib43
  article-title: Effect of isomerization on high-performance nonfullerene electron acceptors
  publication-title: J. Am. Chem. Soc.
– volume: 30
  start-page: 1704904
  year: 2017
  ident: bib21
  article-title: Fine-tuning the energy levels of a nonfullerene small-molecule acceptor to achieve a high short-circuit current and a power conversion efficiency over 12% in organic solar cells
  publication-title: Adv. Mater.
– volume: 6
  start-page: 2942
  year: 2018
  end-page: 2951
  ident: bib4
  article-title: Synergistic effects of chlorination and a fully two-dimensional side-chain design on molecular energy level modulation toward non-fullerene photovoltaics
  publication-title: J. Mater. Chem. A
– volume: 17
  start-page: 119
  year: 2018
  end-page: 128
  ident: bib19
  article-title: Organic solar cells based on non-fullerene acceptors
  publication-title: Nat. Mater.
– volume: 30
  start-page: 1800868
  year: 2018
  ident: bib56
  article-title: Over 14% efficiency in polymer solar cells enabled by a chlorinated polymer donor
  publication-title: Adv. Mater.
– volume: 30
  start-page: 1800052
  year: 2018
  ident: bib14
  article-title: Asymmetrical ladder-type donor-induced polar small molecule acceptor to promote fill factors approaching 77% for high-performance nonfullerene polymer solar cells
  publication-title: Adv. Mater.
– volume: 139
  start-page: 4929
  year: 2017
  end-page: 4934
  ident: bib20
  article-title: Small-molecule acceptor based on the heptacyclic benzodi(cyclopentadithiophene) unit for highly efficient nonfullerene organic solar cells
  publication-title: J. Am. Chem. Soc.
– volume: 9
  start-page: 520
  year: 2015
  end-page: 524
  ident: bib35
  article-title: Efficient polymer solar cells employing a non-conjugated small-molecule electrolyte
  publication-title: Nat. Photonics
– volume: 136
  start-page: 14589
  year: 2014
  end-page: 14597
  ident: bib23
  article-title: Beyond fullerenes: design of nonfullerene acceptors for efficient organic photovoltaics
  publication-title: J. Am. Chem. Soc.
– volume: 8
  start-page: 1702870
  year: 2018
  ident: bib42
  article-title: A halogenation strategy for over 12% efficiency nonfullerene organic solar cells
  publication-title: Adv. Energy Mater.
– volume: 27
  start-page: 1170
  year: 2015
  end-page: 1174
  ident: bib30
  article-title: An electron acceptor challenging fullerenes for efficient polymer solar cells
  publication-title: Adv. Mater.
– volume: 10
  start-page: 39992
  year: 2018
  end-page: 40000
  ident: bib36
  article-title: Chlorine atom-induced molecular interlocked network in a non-fullerene acceptor
  publication-title: ACS Appl. Mater. Interfaces
– volume: 29
  start-page: 2819
  year: 2017
  end-page: 2830
  ident: bib33
  article-title: Chlorination of low-band-gap polymers: toward high-performance polymer solar cells
  publication-title: Chem. Mater.
– volume: 29
  start-page: 8369
  year: 2017
  end-page: 8376
  ident: bib37
  article-title: Design of a highly crystalline low-band gap fused-ring electron acceptor for high-efficiency solar cells with low energy loss
  publication-title: Chem. Mater.
– volume: 61
  start-page: 531
  year: 2018
  end-page: 537
  ident: bib11
  article-title: Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency
  publication-title: Sci. China Chem.
– volume: 139
  start-page: 17114
  year: 2017
  end-page: 17119
  ident: bib24
  article-title: High efficiency near-infrared and semitransparent non-fullerene acceptor organic photovoltaic cells
  publication-title: J. Am. Chem. Soc.
– volume: 30
  start-page: 1707150
  year: 2018
  ident: bib38
  article-title: Dithieno[3,2-b:2',3'-d]pyrrol fused nonfullerene acceptors enabling over 13% efficiency for organic solar cells
  publication-title: Adv. Mater.
– volume: 61
  start-page: 1328
  year: 2018
  end-page: 1337
  ident: bib55
  article-title: Fluorination vs. chlorination: a case study on high performance organic photovoltaic materials
  publication-title: Sci. China Chem.
– volume: 29
  start-page: 1703080
  year: 2017
  ident: bib9
  article-title: Efficient semitransparent organic solar cells with tunable color enabled by an ultralow-bandgap nonfullerene acceptor
  publication-title: Adv. Mater.
– volume: 7
  start-page: 11585
  year: 2016
  ident: bib18
  article-title: High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor
  publication-title: Nat. Commun.
– volume: 30
  start-page: 1707508
  year: 2018
  ident: bib26
  article-title: A wide band gap polymer with a deep highest occupied molecular orbital level enables 14.2% efficiency in polymer solar cells
  publication-title: J. Am. Chem. Soc.
– volume: 8
  start-page: 1800204
  year: 2018
  ident: bib49
  article-title: Fused-ring nonfullerene acceptor forming interpenetrating J-architecture for fullerene-free polymer solar cells
  publication-title: Adv. Energy Mater.
– volume: 9
  start-page: 174
  year: 2015
  end-page: 179
  ident: bib16
  article-title: Single-junction polymer solar cells with high efficiency and photovoltage
  publication-title: Nat. Photonics
– volume: 115
  start-page: E8341
  year: 2018
  end-page: E8348
  ident: bib39
  article-title: Closely packed, low reorganization energy pi-extended postfullerene acceptors for efficient polymer solar cells
  publication-title: Proc. Natl. Acad. Sci. U S A
– year: 2018
  ident: bib40
  article-title: Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells
  publication-title: Chem. Soc. Rev.
– volume: 12
  start-page: 131
  year: 2018
  end-page: 142
  ident: bib7
  article-title: Next-generation organic photovoltaics based on non-fullerene acceptors
  publication-title: Nat. Photonics
– volume: 30
  start-page: 1703973
  year: 2018
  ident: bib48
  article-title: Realizing over 13% efficiency in green-solvent-processed nonfullerene organic solar cells enabled by 1,3,4-Thiadiazole-Based Wide-Bandgap copolymers
  publication-title: Adv. Mater.
– volume: 30
  start-page: 1707170
  year: 2018
  ident: bib27
  article-title: A high-efficiency organic solar cell enabled by the strong intramolecular electron push-pull effect of the nonfullerene acceptor
  publication-title: Adv. Mater.
– volume: 48
  start-page: 2803
  year: 2015
  end-page: 2812
  ident: bib34
  article-title: Non-fullerene electron acceptors for use in organic solar cells
  publication-title: Acc. Chem. Res.
– volume: 138
  start-page: 2973
  year: 2016
  end-page: 2976
  ident: bib31
  article-title: A facile planar fused-ring electron acceptor for as-cast polymer solar cells with 8.71% efficiency
  publication-title: J. Am. Chem. Soc.
– volume: 30
  start-page: 1800868
  year: 2018
  ident: bib53
  article-title: Over 14% efficiency in organic solar cells enabled by chlorinated nonfullerene small-molecule acceptors
  publication-title: Adv. Mater.
– volume: 6
  start-page: 12132
  year: 2018
  end-page: 12141
  ident: bib28
  article-title: Revealing the effects of molecular packing on the performances of polymer solar cells based on A–D–C–D–A type non-fullerene acceptors
  publication-title: J. Mater. Chem. A
– volume: 48
  start-page: 413
  year: 2018
  end-page: 420
  ident: bib10
  article-title: Chlorine substituted 2D-conjugated polymer for high-performance polymer solar cells with 13.1% efficiency via toluene processing
  publication-title: Nano Energy
– volume: 30
  start-page: 1803045
  year: 2018
  ident: bib47
  article-title: Morphology control enables efficient ternary organic solar cells
  publication-title: Adv. Mater.
– volume: 1
  start-page: 15027
  year: 2016
  ident: bib57
  article-title: Efficient organic solar cells processed from hydrocarbon solvents
  publication-title: Nat. Energy
– volume: 3
  start-page: 422
  year: 2018
  end-page: 427
  ident: bib5
  article-title: High fabrication yield organic tandem photovoltaics combining vacuum- and solution-processed subcells with 15% efficiency
  publication-title: Nat. Energy
– volume: 62
  start-page: 1494
  year: 2017
  end-page: 1496
  ident: bib45
  article-title: 26 mA cm
  publication-title: Sci. Bull.
– volume: 1
  start-page: 1389
  year: 2017
  end-page: 1395
  ident: bib51
  article-title: Halogenated conjugated molecules for ambipolar field-effect transistors and non-fullerene organic solar cells
  publication-title: Mater. Chem. Front.
– volume: 30
  start-page: 1705209
  year: 2018
  ident: bib12
  article-title: An alkylated indacenodithieno[3,2-b]thiophene-based nonfullerene acceptor with high crystallinity exhibiting single junction solar cell efficiencies greater than 13% with low voltage losses
  publication-title: Adv. Mater.
– volume: 10
  start-page: 39992
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib36
  article-title: Chlorine atom-induced molecular interlocked network in a non-fullerene acceptor
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.8b15923
– volume: 115
  start-page: E8341
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib39
  article-title: Closely packed, low reorganization energy pi-extended postfullerene acceptors for efficient polymer solar cells
  publication-title: Proc. Natl. Acad. Sci. U S A
  doi: 10.1073/pnas.1807535115
– volume: 30
  start-page: 1707508
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib26
  article-title: A wide band gap polymer with a deep highest occupied molecular orbital level enables 14.2% efficiency in polymer solar cells
  publication-title: J. Am. Chem. Soc.
– volume: 48
  start-page: 2803
  year: 2015
  ident: 10.1016/j.isci.2019.06.033_bib34
  article-title: Non-fullerene electron acceptors for use in organic solar cells
  publication-title: Acc. Chem. Res.
  doi: 10.1021/acs.accounts.5b00199
– volume: 139
  start-page: 7302
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib8
  article-title: Fine-tuned photoactive and interconnection layers for achieving over 13% efficiency in a fullerene-free tandem organic solar cell
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.7b01493
– volume: 30
  start-page: 1800868
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib56
  article-title: Over 14% efficiency in polymer solar cells enabled by a chlorinated polymer donor
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201800868
– volume: 12
  start-page: 131
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib7
  article-title: Next-generation organic photovoltaics based on non-fullerene acceptors
  publication-title: Nat. Photonics
  doi: 10.1038/s41566-018-0104-9
– volume: 30
  start-page: 1707150
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib38
  article-title: Dithieno[3,2-b:2',3'-d]pyrrol fused nonfullerene acceptors enabling over 13% efficiency for organic solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201707150
– volume: 5
  start-page: 5293
  year: 2014
  ident: 10.1016/j.isci.2019.06.033_bib32
  article-title: Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells
  publication-title: Nat. Commun.
  doi: 10.1038/ncomms6293
– volume: 30
  start-page: 1707508
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib54
  article-title: Nonfullerene tandem organic solar cells with high performance of 14.11
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201707508
– volume: 139
  start-page: 4929
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib20
  article-title: Small-molecule acceptor based on the heptacyclic benzodi(cyclopentadithiophene) unit for highly efficient nonfullerene organic solar cells
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.7b01170
– volume: 8
  start-page: 1801203
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib6
  article-title: Modulation of end groups for low-bandgap nonfullerene acceptors enabling high-performance organic solar cells
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201801203
– volume: 29
  start-page: 1703527
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib13
  article-title: Fused-ring acceptors with asymmetric side chains for high-performance thick-film organic solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201703527
– volume: 1
  start-page: 15027
  year: 2016
  ident: 10.1016/j.isci.2019.06.033_bib57
  article-title: Efficient organic solar cells processed from hydrocarbon solvents
  publication-title: Nat. Energy
  doi: 10.1038/nenergy.2015.27
– volume: 17
  start-page: 119
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib19
  article-title: Organic solar cells based on non-fullerene acceptors
  publication-title: Nat. Mater.
  doi: 10.1038/nmat5063
– volume: 3
  start-page: 422
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib5
  article-title: High fabrication yield organic tandem photovoltaics combining vacuum- and solution-processed subcells with 15% efficiency
  publication-title: Nat. Energy
  doi: 10.1038/s41560-018-0134-z
– volume: 140
  start-page: 2054
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib52
  article-title: Dithienopicenocarbazole-based acceptors for efficient organic solar cells with optoelectronic response over 1000 nm and an extremely low energy loss
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.7b13239
– volume: 30
  start-page: 1803045
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib47
  article-title: Morphology control enables efficient ternary organic solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201803045
– volume: 9
  start-page: 174
  year: 2015
  ident: 10.1016/j.isci.2019.06.033_bib16
  article-title: Single-junction polymer solar cells with high efficiency and photovoltage
  publication-title: Nat. Photonics
  doi: 10.1038/nphoton.2015.6
– volume: 1
  start-page: 1700044
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib46
  article-title: A novel thiophene-fused ending group enabling an excellent small molecule acceptor for high-performance fullerene-free polymer solar cells with 11.8% efficiency
  publication-title: Solar RRL
  doi: 10.1002/solr.201700044
– volume: 139
  start-page: 17114
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib24
  article-title: High efficiency near-infrared and semitransparent non-fullerene acceptor organic photovoltaic cells
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.7b11278
– volume: 29
  start-page: 2819
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib33
  article-title: Chlorination of low-band-gap polymers: toward high-performance polymer solar cells
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.6b04828
– volume: 30
  start-page: 1800868
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib53
  article-title: Over 14% efficiency in organic solar cells enabled by chlorinated nonfullerene small-molecule acceptors
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201800868
– volume: 138
  start-page: 15011
  year: 2016
  ident: 10.1016/j.isci.2019.06.033_bib50
  article-title: Side-chain isomerization on an n-type organic semiconductor ITIC acceptor makes 11.77% high efficiency polymer solar cells
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.6b09110
– volume: 29
  start-page: 8369
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib37
  article-title: Design of a highly crystalline low-band gap fused-ring electron acceptor for high-efficiency solar cells with low energy loss
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.7b02853
– volume: 136
  start-page: 14589
  year: 2014
  ident: 10.1016/j.isci.2019.06.033_bib23
  article-title: Beyond fullerenes: design of nonfullerene acceptors for efficient organic photovoltaics
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja508472j
– volume: 61
  start-page: 531
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib11
  article-title: Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency
  publication-title: Sci. China Chem.
  doi: 10.1007/s11426-017-9199-1
– volume: 9
  start-page: 520
  year: 2015
  ident: 10.1016/j.isci.2019.06.033_bib35
  article-title: Efficient polymer solar cells employing a non-conjugated small-molecule electrolyte
  publication-title: Nat. Photonics
  doi: 10.1038/nphoton.2015.126
– volume: 29
  start-page: 1700144
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib58
  article-title: Single-junction binary-blend nonfullerene polymer solar cells with 12.1% efficiency
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201700144
– volume: 61
  start-page: 1328
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib55
  article-title: Fluorination vs. chlorination: a case study on high performance organic photovoltaic materials
  publication-title: Sci. China Chem.
  doi: 10.1007/s11426-018-9260-2
– volume: 50
  start-page: 341
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib17
  article-title: Molecular aggregate photophysics beyond the Kasha Model: novel design principles for organic materials
  publication-title: Acc. Chem. Res.
  doi: 10.1021/acs.accounts.6b00576
– volume: 8
  start-page: 1702870
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib42
  article-title: A halogenation strategy for over 12% efficiency nonfullerene organic solar cells
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201702870
– volume: 48
  start-page: 413
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib10
  article-title: Chlorine substituted 2D-conjugated polymer for high-performance polymer solar cells with 13.1% efficiency via toluene processing
  publication-title: Nano Energy
  doi: 10.1016/j.nanoen.2018.04.002
– volume: 7
  start-page: 4313
  year: 2019
  ident: 10.1016/j.isci.2019.06.033_bib44
  article-title: Molecular engineering of central fused-ring cores of non-fullerene acceptors for high-efficiency organic solar cells
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C8TA12465E
– volume: 62
  start-page: 1494
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib45
  article-title: 26 mA cm−2 Jsc from organic solar cells with a low-bandgap nonfullerene acceptor
  publication-title: Sci. Bull.
  doi: 10.1016/j.scib.2017.10.017
– volume: 63
  start-page: 340
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib25
  article-title: Thermostable single-junction organic solar cells with a power conversion efficiency of 14.62%
  publication-title: Sci. Bull.
  doi: 10.1016/j.scib.2018.02.015
– volume: 1
  start-page: 1389
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib51
  article-title: Halogenated conjugated molecules for ambipolar field-effect transistors and non-fullerene organic solar cells
  publication-title: Mater. Chem. Front.
  doi: 10.1039/C7QM00025A
– volume: 30
  start-page: 1800052
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib14
  article-title: Asymmetrical ladder-type donor-induced polar small molecule acceptor to promote fill factors approaching 77% for high-performance nonfullerene polymer solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201800052
– volume: 30
  start-page: 1707170
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib27
  article-title: A high-efficiency organic solar cell enabled by the strong intramolecular electron push-pull effect of the nonfullerene acceptor
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201707170
– volume: 6
  start-page: 2942
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib4
  article-title: Synergistic effects of chlorination and a fully two-dimensional side-chain design on molecular energy level modulation toward non-fullerene photovoltaics
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C7TA09837E
– volume: 8
  start-page: 1800204
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib49
  article-title: Fused-ring nonfullerene acceptor forming interpenetrating J-architecture for fullerene-free polymer solar cells
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201800204
– volume: 140
  start-page: 5764
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib2
  article-title: Concurrent cooperative J-aggregates and anticooperative H-aggregates
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.8b01463
– volume: 6
  start-page: 2664
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib15
  article-title: The crucial role of intermolecular π–π interactions in A–D–A-type electron acceptors and their effective modulation
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C7TA10461H
– year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib40
  article-title: Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells
  publication-title: Chem. Soc. Rev.
– volume: 29
  start-page: 1702125
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib41
  article-title: Enhancing performance of nonfullerene acceptors via side-chain conjugation strategy
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201702125
– volume: 29
  start-page: 1701156
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib3
  article-title: An efficient, “Burn in” free organic solar cell employing a nonfullerene electron acceptor
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201701156
– volume: 141
  start-page: 3274
  year: 2019
  ident: 10.1016/j.isci.2019.06.033_bib1
  article-title: Fluorination effects on indacenodithienothiophene acceptor packing and electronic structure, end-group redistribution, and solar cell photovoltaic response
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.8b13653
– volume: 7
  start-page: 11585
  year: 2016
  ident: 10.1016/j.isci.2019.06.033_bib18
  article-title: High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor
  publication-title: Nat. Commun.
  doi: 10.1038/ncomms11585
– volume: 140
  start-page: 9140
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib43
  article-title: Effect of isomerization on high-performance nonfullerene electron acceptors
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.8b04027
– volume: 27
  start-page: 1170
  year: 2015
  ident: 10.1016/j.isci.2019.06.033_bib30
  article-title: An electron acceptor challenging fullerenes for efficient polymer solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201404317
– volume: 30
  start-page: 1703973
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib48
  article-title: Realizing over 13% efficiency in green-solvent-processed nonfullerene organic solar cells enabled by 1,3,4-Thiadiazole-Based Wide-Bandgap copolymers
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201703973
– volume: 29
  start-page: 1703080
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib9
  article-title: Efficient semitransparent organic solar cells with tunable color enabled by an ultralow-bandgap nonfullerene acceptor
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201703080
– volume: 6
  start-page: 12132
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib28
  article-title: Revealing the effects of molecular packing on the performances of polymer solar cells based on A–D–C–D–A type non-fullerene acceptors
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C8TA03753A
– volume: 30
  start-page: 1704904
  year: 2017
  ident: 10.1016/j.isci.2019.06.033_bib21
  article-title: Fine-tuning the energy levels of a nonfullerene small-molecule acceptor to achieve a high short-circuit current and a power conversion efficiency over 12% in organic solar cells
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201704904
– volume: 138
  start-page: 2973
  year: 2016
  ident: 10.1016/j.isci.2019.06.033_bib31
  article-title: A facile planar fused-ring electron acceptor for as-cast polymer solar cells with 8.71% efficiency
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.6b00853
– volume: 30
  start-page: 1705209
  year: 2018
  ident: 10.1016/j.isci.2019.06.033_bib12
  article-title: An alkylated indacenodithieno[3,2-b]thiophene-based nonfullerene acceptor with high crystallinity exhibiting single junction solar cell efficiencies greater than 13% with low voltage losses
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201705209
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Snippet The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors (ITIC-2Cl-δ and ITIC-2Cl-γ) was intensely investigated....
The influence caused by the position of the chlorine atom on end groups of two non-fullerene acceptors ( ITIC-2Cl-δ and ITIC-2Cl-γ ) was intensely...
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SubjectTerms Chemical Synthesis
Energy Storage
Materials Characterization Techniques
Title Isomer-free: Precise Positioning of Chlorine-Induced Interpenetrating Charge Transfer for Elevated Solar Conversion
URI https://dx.doi.org/10.1016/j.isci.2019.06.033
https://www.ncbi.nlm.nih.gov/pubmed/31323476
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