Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation

• Published in: iScience Vol. 23; no. 1; p. 100755
• Main Authors: Zhang, Jing, Liu, Dan, Liu, Song, Ge, Yuanyuan, Lan, Yu, Chen, Yiyun
• Format: Journal Article
• Language: English
• Published: United States Elsevier Inc 24.01.2020; Elsevier
• Subjects: Organic Chemistry; Organic Reaction; Physical Organic Chemistry; Organic Reaction; Physical Organic Chemistry; Organic Chemistry

The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theo...