Luminescent tungsten() complexes as photocatalysts for light-driven C-C and C-B bond formation reactions
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-s...
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Published in | Chemical science (Cambridge) Vol. 11; no. 25; pp. 637 - 6382 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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Royal Soc Chemistry
07.07.2020
Royal Society of Chemistry |
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Abstract | The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(
vi
) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
A luminescent tungsten(
vi
) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance. |
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AbstractList | The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance. A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. |
Author | Che, Chi-Ming Liu, Yungen Yu, Daohong To, Wai-Pong Du, Lili Chan, Kaai-Tung Phillips, David Lee Wu, Liang-Liang Tong, Glenna So Ming |
AuthorAffiliation | Department of Chemistry Southern University of Science and Technology The University of Hong Kong State Key Laboratory of Synthetic Chemistry HKU-CAS Joint Laboratory on New Materials HKU Shenzhen Institute of Research and Innovation Shenzhen |
AuthorAffiliation_xml | – name: State Key Laboratory of Synthetic Chemistry – name: Southern University of Science and Technology – name: Department of Chemistry – name: HKU Shenzhen Institute of Research and Innovation Shenzhen – name: The University of Hong Kong – name: HKU-CAS Joint Laboratory on New Materials – name: a Department of Chemistry , Southern University of Science and Technology , Shenzhen , Guangdong 518055 , China . Email: cmche@hku.hk – name: c HKU Shenzhen Institute of Research and Innovation Shenzhen , Guangdong 518055 , China – name: b State Key Laboratory of Synthetic Chemistry , HKU-CAS Joint Laboratory on New Materials , Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China |
Author_xml | – sequence: 1 givenname: Daohong surname: Yu fullname: Yu, Daohong – sequence: 2 givenname: Wai-Pong surname: To fullname: To, Wai-Pong – sequence: 3 givenname: Glenna So Ming surname: Tong fullname: Tong, Glenna So Ming – sequence: 4 givenname: Liang-Liang surname: Wu fullname: Wu, Liang-Liang – sequence: 5 givenname: Kaai-Tung surname: Chan fullname: Chan, Kaai-Tung – sequence: 6 givenname: Lili surname: Du fullname: Du, Lili – sequence: 7 givenname: David Lee surname: Phillips fullname: Phillips, David Lee – sequence: 8 givenname: Yungen surname: Liu fullname: Liu, Yungen – sequence: 9 givenname: Chi-Ming surname: Che fullname: Che, Chi-Ming |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32874518$$D View this record in MEDLINE/PubMed |
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Keywords | CROSS-COUPLING REACTIONS ELECTRON-TRANSFER ARYL HALIDES IRON COMPLEXES TRANSFER RADICAL-ADDITION EMISSION QUANTUM YIELDS DECARBOXYLATIVE ALKYLATION LIVED EXCITED-STATES METAL-FREE PHOTOREDOX CATALYSIS |
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Snippet | The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large... A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional... |
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SubjectTerms | Aromatic compounds Bonding Bromides Carboxylic acids Chemistry Chemistry, Multidisciplinary Coupling Covalent bonds Electromagnetic absorption Esters Functional groups Halides NMR Nuclear magnetic resonance Photocatalysis Photocatalysts Photochemical reactions Photoluminescence Physical Sciences Science & Technology Tungsten |
Title | Luminescent tungsten() complexes as photocatalysts for light-driven C-C and C-B bond formation reactions |
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