Luminescent tungsten() complexes as photocatalysts for light-driven C-C and C-B bond formation reactions

The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-s...

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Published inChemical science (Cambridge) Vol. 11; no. 25; pp. 637 - 6382
Main Authors Yu, Daohong, To, Wai-Pong, Tong, Glenna So Ming, Wu, Liang-Liang, Chan, Kaai-Tung, Du, Lili, Phillips, David Lee, Liu, Yungen, Che, Chi-Ming
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.07.2020
Royal Society of Chemistry
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Abstract The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance.
AbstractList The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance.
A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional group tolerance. The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten( vi ) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
Author Che, Chi-Ming
Liu, Yungen
Yu, Daohong
To, Wai-Pong
Du, Lili
Chan, Kaai-Tung
Phillips, David Lee
Wu, Liang-Liang
Tong, Glenna So Ming
AuthorAffiliation Department of Chemistry
Southern University of Science and Technology
The University of Hong Kong
State Key Laboratory of Synthetic Chemistry
HKU-CAS Joint Laboratory on New Materials
HKU Shenzhen Institute of Research and Innovation Shenzhen
AuthorAffiliation_xml – name: State Key Laboratory of Synthetic Chemistry
– name: Southern University of Science and Technology
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– name: The University of Hong Kong
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– name: a Department of Chemistry , Southern University of Science and Technology , Shenzhen , Guangdong 518055 , China . Email: cmche@hku.hk
– name: c HKU Shenzhen Institute of Research and Innovation Shenzhen , Guangdong 518055 , China
– name: b State Key Laboratory of Synthetic Chemistry , HKU-CAS Joint Laboratory on New Materials , Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/32874518$$D View this record in MEDLINE/PubMed
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Issue 25
Keywords CROSS-COUPLING REACTIONS
ELECTRON-TRANSFER
ARYL HALIDES
IRON COMPLEXES
TRANSFER RADICAL-ADDITION
EMISSION QUANTUM YIELDS
DECARBOXYLATIVE ALKYLATION
LIVED EXCITED-STATES
METAL-FREE
PHOTOREDOX CATALYSIS
Language English
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Electronic supplementary information (ESI) available: Experimental details, photophysical data, DFT calculations and NMR spectral data. See DOI
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Snippet The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large...
A luminescent tungsten( vi ) complex catalyses a broad spectrum of light-driven organic transformation reactions with high product yields and good functional...
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SubjectTerms Aromatic compounds
Bonding
Bromides
Carboxylic acids
Chemistry
Chemistry, Multidisciplinary
Coupling
Covalent bonds
Electromagnetic absorption
Esters
Functional groups
Halides
NMR
Nuclear magnetic resonance
Photocatalysis
Photocatalysts
Photochemical reactions
Photoluminescence
Physical Sciences
Science & Technology
Tungsten
Title Luminescent tungsten() complexes as photocatalysts for light-driven C-C and C-B bond formation reactions
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https://www.ncbi.nlm.nih.gov/pubmed/32874518
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Volume 11
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