Electromagnetic radiation driving of volume changes in nanocomposites made of a thermosensitive hydrogel polymerized around conducting polymer nanoparticles

• Published in: RSC advances Vol. 1; no. 15; pp. 9155 - 9164
• Main Authors: Abel, Silvestre Bongiovanni, Rivarola, Claudia R, Barbero, Cesar A, Molina, Maria
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 03.03.2020; The Royal Society of Chemistry
• Subjects: Acrylamide; Actuators; Chemistry; Conducting polymers; Crosslinking; Electromagnetic radiation; Free radical polymerization; Free radicals; Hydrogels; Irradiation; Isopropylacrylamide; Morphology; Nanocomposites; Nanofibers; Nanoparticles; Nanospheres; Phase transitions; Polyanilines; Polymerization; Polypyrroles; Radio frequency; Sulfonic acid; Thermogravimetric analysis
• DOI: 10.1039/d0ra01329c
• ISSN: 2046-2069

Polymeric nanocomposites were obtained by the formation of a thermosensitive hydrogel matrix around conducting polymer (CP) nanoparticles. The CP is able to absorb electromagnetic radiation which is converted into heat and induces the phase transition of the surrounding hydrogel. The method chosen to form the hydrogel is the free radical polymerization of a copolymer ( N -isopropylacrylamide (NIPAM) and 2-acrylamide-2-methylpropano sulfonic acid (AMPS), PNIPAM- co -2% AMPS) in the presence of bisacrylamide as the crosslinker. The nanoparticles are polypyrrole nanospheres (PPy NP), polyaniline nanofibers (PANI NF), and polyaniline nanospheres (PANI NP). The morphology of the composites was studied using SEM microscopy and the percentage composition of each material was evaluated by thermogravimetric analysis (TGA). The swelling equilibrium capacity and rate are clearly affected by the nanoparticle shape and nature. However, the nanocomposites LCST are similar to that of the matrix. Upon RF irradiation, the three nanocomposites increase the temperature and reach the LCST after 320 seconds of irradiation (320 kJ). Upon MW application, the local temperature reaches the LCST after only 30 s (21 kJ), resulting in a MW more effective than RF to drive the transition. These results demonstrate that the proposed materials are useful as a remotely driven actuator. A novel synthetic method of photothermally activated nanocomposites by in situ formation of hydrogel matrixes around dispersed conducting polymer nanoparticles is described.