Post-synthetic modification of covalent organic frameworks for CO2 electroreduction

• Published in: Nature communications Vol. 14; no. 1; pp. 3800 - 11
• Main Authors: Liu, Minghao, Yang, Shuai, Yang, Xiubei, Cui, Cheng-Xing, Liu, Guojuan, Li, Xuewen, He, Jun, Chen, George Zheng, Xu, Qing, Zeng, Gaofeng
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 26.06.2023; Nature Publishing Group; Nature Portfolio
• Subjects: 639/301/299/1013; 639/638/675; 639/638/77/886; Binding; Carbon dioxide; Catalysts; Charge transfer; Chemical reduction; Controllability; Covalence; Efficiency; Electron states; Humanities and Social Sciences; Ions; Linkages; Lithium; multidisciplinary; NMR; Nuclear magnetic resonance; Science; Science (multidisciplinary)

To achieve high-efficiency catalysts for CO 2 reduction reaction, various catalytic metal centres and linker molecules have been assembled into covalent organic frameworks. The amine-linkages enhance the binding ability of CO 2 molecules, and the ionic frameworks enable to improve the electronic con...