Tunable sulphur doping on CuFe2O4 nanostructures for the selective elimination of organic dyes from water

In this work, sulphur doped copper ferrites (S-CuFe 2 O 4 ) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results r...

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Published inScientific reports Vol. 13; no. 1; pp. 6306 - 13
Main Authors Aslam, Anam, Abid, Muhammad Zeeshan, Rafiq, Khezina, Rauf, Abdul, Hussain, Ejaz
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 18.04.2023
Nature Publishing Group
Nature Portfolio
Subjects
639/301
639/638
639/925
Anions
Carcinogens
Dyes
Graphene
Humanities and Social Sciences
Morphology
multidisciplinary
Photocatalysis
Pollutants
Quantum dots
Radiation
Recombination
Science
Science (multidisciplinary)
Sulfur
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Abstract In this work, sulphur doped copper ferrites (S-CuFe 2 O 4 ) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe 2 O 4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe 2 O 4 over pristine CuFe 2 O 4 . On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
AbstractList Abstract In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe2O4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe2O4 over pristine CuFe2O4. On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe2O4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe2O4 over pristine CuFe2O4. On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV-Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe2O4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV-Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe2O4 over pristine CuFe2O4. On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV-Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe2O4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV-Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe2O4 over pristine CuFe2O4. On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
In this work, sulphur doped copper ferrites (S-CuFe 2 O 4 ) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe 2 O 4 nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe 2 O 4 over pristine CuFe 2 O 4 . On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
ArticleNumber 6306
Author Rafiq, Khezina
Rauf, Abdul
Aslam, Anam
Abid, Muhammad Zeeshan
Hussain, Ejaz
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  organization: Institute of Chemistry, Inorganic Materials Laboratory 52S, The Islamia University of Bahawalpur
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  organization: Institute of Chemistry, Inorganic Materials Laboratory 52S, The Islamia University of Bahawalpur
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  givenname: Ejaz
  surname: Hussain
  fullname: Hussain, Ejaz
  email: ejaz.hussain@iub.edu.pk
  organization: Institute of Chemistry, Inorganic Materials Laboratory 52S, The Islamia University of Bahawalpur
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Snippet In this work, sulphur doped copper ferrites (S-CuFe 2 O 4 ) photocatalysts were successfully synthesized for the first time using the facile hydrothermal...
In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method....
Abstract In this work, sulphur doped copper ferrites (S-CuFe2O4) photocatalysts were successfully synthesized for the first time using the facile hydrothermal...
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StartPage 6306
SubjectTerms 639/301
639/638
639/925
Anions
Carcinogens
Dyes
Graphene
Humanities and Social Sciences
Morphology
multidisciplinary
Photocatalysis
Pollutants
Quantum dots
Radiation
Recombination
Science
Science (multidisciplinary)
Sulfur
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Title Tunable sulphur doping on CuFe2O4 nanostructures for the selective elimination of organic dyes from water
URI https://link.springer.com/article/10.1038/s41598-023-33185-0
https://www.proquest.com/docview/2802688151
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https://pubmed.ncbi.nlm.nih.gov/PMC10113332
https://doaj.org/article/d4cf6c2fb85b4b8baa1faa3a0abd2eb0
Volume 13
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