Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper–dye conjugation

• Published in: Nature communications Vol. 11; no. 1; p. 5384
• Main Authors: Shi, Yusheng, Zhang, Tiexin, Jiang, Xiao-Ming, Xu, Gang, He, Cheng, Duan, Chunying
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 23.10.2020; Nature Publishing Group; Nature Portfolio
• Subjects: 140/131; 140/58; 639/638/77/887; 639/638/77/890; 639/638/911; Adaptability; Catalysis; Circuits; Conjugation; Coordination polymers; Copper; Couplings; Dyes; Electron transfer; Fluorescence; Humanities and Social Sciences; Ligands; multidisciplinary; Nucleophiles; Photoreduction; Polymers; Quenching; Science; Science (multidisciplinary)

Synergistic photoredox and copper catalysis confers new synthetic possibilities in the pharmaceutical field, but is seriously affected by the consumptive fluorescence quenching of Cu(II). By decorating bulky auxiliaries into a photoreductive triphenylamine-based ligand to twist the conjugation betwe...