Ag nanoparticles immobilized on new magnetic alginate halloysite as a recoverable catalyst for reduction of nitroaromatics in aqueous media

Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalyti...

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Published inScientific reports Vol. 11; no. 1; pp. 17124 - 10
Main Authors Mohammadi, Pourya, Heravi, Majid, Daraie, Mansoureh
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 24.08.2021
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Abstract Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe 3 O 4 ]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe 3 O 4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe 3 O 4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH 4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.
AbstractList Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe 3 O 4 ]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe 3 O 4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe 3 O 4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH 4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.
Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe3O4]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe3O4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe3O4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe3O4]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe3O4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe3O4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.
Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe3O4]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe3O4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe3O4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.
Abstract Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe3O4]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe3O4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe3O4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.
ArticleNumber 17124
Author Heravi, Majid
Daraie, Mansoureh
Mohammadi, Pourya
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  surname: Daraie
  fullname: Daraie, Mansoureh
  organization: Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University
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SSID ssj0000529419
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Snippet Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active...
Abstract Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active...
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SubjectTerms 639/638
639/638/77
639/638/77/884
Alginic acid
Amines
Biological activity
Catalysts
Humanities and Social Sciences
Iron oxides
multidisciplinary
Nanocatalysis
Nanoparticles
Polymers
Science
Science (multidisciplinary)
Silver
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Title Ag nanoparticles immobilized on new magnetic alginate halloysite as a recoverable catalyst for reduction of nitroaromatics in aqueous media
URI https://link.springer.com/article/10.1038/s41598-021-96421-5
https://www.proquest.com/docview/2563935860
https://www.proquest.com/docview/2564487229
https://pubmed.ncbi.nlm.nih.gov/PMC8384888
https://doaj.org/article/ef9a51cd34df4a05be12f61111793aad
Volume 11
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