Polymorphism Control of Layered MoTe2 through Two-Dimensional Solid-Phase Crystallization
Two-dimensional (2D) molybdenum ditelluride (MoTe 2 ) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at room temperature. Polymorphism in MoTe 2 presents new opportunities in developing phase-change memory, high- performance transistors, and spint...
Saved in:
| Published in | Scientific reports Vol. 9; no. 1; pp. 1 - 8 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
19.06.2019
Nature Publishing Group |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Two-dimensional (2D) molybdenum ditelluride (MoTe
2
) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at room temperature. Polymorphism in MoTe
2
presents new opportunities in developing phase-change memory, high- performance transistors, and spintronic devices. However, it also poses challenges in synthesizing homogeneous MoTe
2
with a precisely controlled phase. Recently, a new yet simple method using sputtering and 2D solid-phase crystallization (SPC) is proposed for synthesizing high-quality and large-area MoTe
2
. This study investigates the polymorphism control of MoTe
2
synthesis using 2D SPC. The Te/Mo ratio and oxygen content in the as-sputtered films correlate strongly with the final phase and electrical properties of SPC MoTe
2
. Furthermore, the SPC thermal budget may be exploited for stabilizing a deterministic phase. The comprehensive experiments presented in this work demonstrate the versatile and precise controllability on the MoTe
2
phase by using the simple 2D SPC technique. |
|---|---|
| AbstractList | Two-dimensional (2D) molybdenum ditelluride (MoTe2) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at room temperature. Polymorphism in MoTe2 presents new opportunities in developing phase-change memory, high- performance transistors, and spintronic devices. However, it also poses challenges in synthesizing homogeneous MoTe2 with a precisely controlled phase. Recently, a new yet simple method using sputtering and 2D solid-phase crystallization (SPC) is proposed for synthesizing high-quality and large-area MoTe2. This study investigates the polymorphism control of MoTe2 synthesis using 2D SPC. The Te/Mo ratio and oxygen content in the as-sputtered films correlate strongly with the final phase and electrical properties of SPC MoTe2. Furthermore, the SPC thermal budget may be exploited for stabilizing a deterministic phase. The comprehensive experiments presented in this work demonstrate the versatile and precise controllability on the MoTe2 phase by using the simple 2D SPC technique. Two-dimensional (2D) molybdenum ditelluride (MoTe 2 ) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at room temperature. Polymorphism in MoTe 2 presents new opportunities in developing phase-change memory, high- performance transistors, and spintronic devices. However, it also poses challenges in synthesizing homogeneous MoTe 2 with a precisely controlled phase. Recently, a new yet simple method using sputtering and 2D solid-phase crystallization (SPC) is proposed for synthesizing high-quality and large-area MoTe 2 . This study investigates the polymorphism control of MoTe 2 synthesis using 2D SPC. The Te/Mo ratio and oxygen content in the as-sputtered films correlate strongly with the final phase and electrical properties of SPC MoTe 2 . Furthermore, the SPC thermal budget may be exploited for stabilizing a deterministic phase. The comprehensive experiments presented in this work demonstrate the versatile and precise controllability on the MoTe 2 phase by using the simple 2D SPC technique. Two-dimensional (2D) molybdenum ditelluride (MoTe2) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T' phases at room temperature. Polymorphism in MoTe2 presents new opportunities in developing phase-change memory, high- performance transistors, and spintronic devices. However, it also poses challenges in synthesizing homogeneous MoTe2 with a precisely controlled phase. Recently, a new yet simple method using sputtering and 2D solid-phase crystallization (SPC) is proposed for synthesizing high-quality and large-area MoTe2. This study investigates the polymorphism control of MoTe2 synthesis using 2D SPC. The Te/Mo ratio and oxygen content in the as-sputtered films correlate strongly with the final phase and electrical properties of SPC MoTe2. Furthermore, the SPC thermal budget may be exploited for stabilizing a deterministic phase. The comprehensive experiments presented in this work demonstrate the versatile and precise controllability on the MoTe2 phase by using the simple 2D SPC technique.Two-dimensional (2D) molybdenum ditelluride (MoTe2) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T' phases at room temperature. Polymorphism in MoTe2 presents new opportunities in developing phase-change memory, high- performance transistors, and spintronic devices. However, it also poses challenges in synthesizing homogeneous MoTe2 with a precisely controlled phase. Recently, a new yet simple method using sputtering and 2D solid-phase crystallization (SPC) is proposed for synthesizing high-quality and large-area MoTe2. This study investigates the polymorphism control of MoTe2 synthesis using 2D SPC. The Te/Mo ratio and oxygen content in the as-sputtered films correlate strongly with the final phase and electrical properties of SPC MoTe2. Furthermore, the SPC thermal budget may be exploited for stabilizing a deterministic phase. The comprehensive experiments presented in this work demonstrate the versatile and precise controllability on the MoTe2 phase by using the simple 2D SPC technique. |
| ArticleNumber | 8810 |
| Author | Lee, Yao-Jen Hou, Tuo-Hung Cheng, Chun-Cheng Wang, Ding Lin, Wei-Ting Hsu, Hao-Hua Huang, Jyun-Hong |
| Author_xml | – sequence: 1 givenname: Jyun-Hong surname: Huang fullname: Huang, Jyun-Hong organization: Department of Electronics Engineering and Institute of Electronics, National Chiao Tung University – sequence: 2 givenname: Hao-Hua surname: Hsu fullname: Hsu, Hao-Hua organization: Department of Electronics Engineering and Institute of Electronics, National Chiao Tung University – sequence: 3 givenname: Ding surname: Wang fullname: Wang, Ding organization: Advanced Technology Research Center, AU Optronics Corporation – sequence: 4 givenname: Wei-Ting surname: Lin fullname: Lin, Wei-Ting organization: Advanced Technology Research Center, AU Optronics Corporation – sequence: 5 givenname: Chun-Cheng surname: Cheng fullname: Cheng, Chun-Cheng organization: Advanced Technology Research Center, AU Optronics Corporation – sequence: 6 givenname: Yao-Jen surname: Lee fullname: Lee, Yao-Jen organization: National Nano Device Laboratories, Department of Physics, National Chung Hsing University – sequence: 7 givenname: Tuo-Hung orcidid: 0000-0002-9686-7076 surname: Hou fullname: Hou, Tuo-Hung email: thhou@mail.nctu.edu.tw organization: Department of Electronics Engineering and Institute of Electronics, National Chiao Tung University |
| BookMark | eNp9UU1P3DAQtSoQX-UP9BSpl15c_JnEl0rV9gOkRUXq9sDJ8jqTjZETb-2kZfvrMbsgCgd88Ujz3puZ947R3hAGQOgdJR8p4fVZElSqGhOqsJBUMHz7Bh0xIiRmnLG9_-pDdJrSDclPMiWoOkCHnDJaCc6O0PVV8Js-xHXnUl_MwjDG4IvQFnOzgQhNcRkWwIqxi2FadcXib8BfXA9DcmEwvvgZvGvwVWcSFLO4SaPx3v0zY-6-Rfut8QlOH_4T9Ovb18XsHM9_fL-YfZ5jK2k1Ys6UBcilVQ2xS9YqInItwTbLtjKlVXUpTAV1KUta1VRVpLQlZ8JkPjcVP0GfdrrradlDYyGfYLxeR9ebuNHBOP28M7hOr8IfXcpaSCmywIcHgRh-T5BG3btkwXszQJiSZkwImh0j97Pev4DehClmI7YoLkpWU5ZR9Q5lY0gpQqutG7ee5PnOa0r0fYR6F6HOEepthPo2U9kL6uMdr5L4jpQyeFhBfNrqFdYdl2CwSQ |
| CitedBy_id | crossref_primary_10_1039_D1CE00275A crossref_primary_10_1063_5_0166502 crossref_primary_10_1016_j_jcrysgro_2022_126806 crossref_primary_10_1021_acsanm_1c01504 crossref_primary_10_1021_acs_jpcc_3c03752 crossref_primary_10_1038_s41467_024_53371_6 crossref_primary_10_1039_D4NR00687A crossref_primary_10_1021_acsnano_0c08069 crossref_primary_10_1016_j_apmt_2021_101017 crossref_primary_10_1039_D1TC02497C crossref_primary_10_1063_5_0106886 crossref_primary_10_1021_acsnano_4c13915 crossref_primary_10_1016_j_jmst_2024_01_066 crossref_primary_10_1007_s12274_020_2724_x crossref_primary_10_1021_acsami_9b20041 crossref_primary_10_1016_j_cej_2024_153936 crossref_primary_10_1016_j_jclepro_2023_139127 crossref_primary_10_1002_admt_202402036 crossref_primary_10_1002_aelm_202300880 crossref_primary_10_1021_acsami_2c08842 crossref_primary_10_1016_j_apsusc_2025_162925 crossref_primary_10_1038_s44160_022_00154_w crossref_primary_10_1039_D2TC01281B crossref_primary_10_1021_acs_cgd_1c01504 crossref_primary_10_1039_D1TC03123F crossref_primary_10_1016_j_jmst_2023_03_046 crossref_primary_10_1021_acs_cgd_4c01737 crossref_primary_10_1039_D4TC01666A crossref_primary_10_1016_j_chip_2023_100057 crossref_primary_10_1016_j_ceramint_2022_07_236 crossref_primary_10_1016_j_microc_2022_108134 crossref_primary_10_1021_acsaelm_5c00012 crossref_primary_10_1002_aelm_202300457 crossref_primary_10_1039_D2MA00150K crossref_primary_10_1038_s41586_024_07209_2 |
| Cites_doi | 10.1021/acsnano.5b00736 10.1039/c6ta08206h 10.1021/acsnano.5b02511 10.1021/cm5025662 10.1088/0022-3727/19/8/025 10.1021/la902678x 10.1002/adma.201606433 10.1021/nl502557g 10.1038/nphys3933 10.1179/1432891714z.0000000001097 10.1021/acs.nanolett.6b03300 10.1038/nphys3314 10.1038/nnano.2017.161 10.1021/acs.nanolett.5b03481 10.7567/apex.8.095201 10.1039/c5cp06706e 10.1021/acsnano.6b08109 10.1063/1.4941001 10.1038/ncomms10671 10.1007/s12274-014-0532-x 10.1103/PhysRevB.64.235305 10.1002/admi.201700157 10.1126/science.aab3175 10.1002/adma.201602687 10.1021/acsnano.6b07499 10.1088/2053-1583/3/3/031010 10.1002/adma.201305845 10.1038/ncomms5214 10.1021/acsnano.5b00985 10.1002/adma.201603471 10.1021/jacs.5b07452 10.4067/S0717-97072016000100014 10.1021/jp400363a 10.1016/B978-0-8155-2031-3.00005-3 10.1103/PhysRevB.92.161107 |
| ContentType | Journal Article |
| Copyright | The Author(s) 2019 2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| Copyright_xml | – notice: The Author(s) 2019 – notice: 2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| DBID | C6C AAYXX CITATION 3V. 7X7 7XB 88A 88E 88I 8FE 8FH 8FI 8FJ 8FK ABUWG AEUYN AFKRA AZQEC BBNVY BENPR BHPHI CCPQU DWQXO FYUFA GHDGH GNUQQ HCIFZ K9. LK8 M0S M1P M2P M7P PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQGLB PQQKQ PQUKI Q9U 7X8 5PM |
| DOI | 10.1038/s41598-019-45142-x |
| DatabaseName | Springer Nature OA Free Journals CrossRef ProQuest Central (Corporate) Health & Medical Collection ProQuest Central (purchase pre-March 2016) Biology Database (Alumni Edition) Medical Database (Alumni Edition) Science Database (Alumni Edition) ProQuest SciTech Collection ProQuest Natural Science Collection Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) ProQuest One Sustainability ProQuest Central UK/Ireland ProQuest Central Essentials Biological Science Collection ProQuest Central Natural Science Collection ProQuest One Community College ProQuest Central Korea Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Central Student ProQuest SciTech Premium Collection ProQuest Health & Medical Complete (Alumni) Biological Sciences Health & Medical Collection (Alumni) Medical Database Science Database Biological Science Database ProQuest Central Premium ProQuest One Academic Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) ProQuest One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Applied & Life Sciences ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central Basic MEDLINE - Academic PubMed Central (Full Participant titles) |
| DatabaseTitle | CrossRef Publicly Available Content Database ProQuest Central Student ProQuest One Academic Middle East (New) ProQuest Central Essentials ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) SciTech Premium Collection ProQuest One Community College ProQuest One Health & Nursing ProQuest Natural Science Collection ProQuest Biology Journals (Alumni Edition) ProQuest Central ProQuest One Applied & Life Sciences ProQuest One Sustainability ProQuest Health & Medical Research Collection Health Research Premium Collection Health and Medicine Complete (Alumni Edition) Natural Science Collection ProQuest Central Korea Health & Medical Research Collection Biological Science Collection ProQuest Central (New) ProQuest Medical Library (Alumni) ProQuest Science Journals (Alumni Edition) ProQuest Biological Science Collection ProQuest Central Basic ProQuest Science Journals ProQuest One Academic Eastern Edition ProQuest Hospital Collection Health Research Premium Collection (Alumni) Biological Science Database ProQuest SciTech Collection ProQuest Hospital Collection (Alumni) ProQuest Health & Medical Complete ProQuest Medical Library ProQuest One Academic UKI Edition ProQuest One Academic ProQuest One Academic (New) ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | Publicly Available Content Database MEDLINE - Academic CrossRef |
| Database_xml | – sequence: 1 dbid: C6C name: Springer Nature OA Free Journals url: http://www.springeropen.com/ sourceTypes: Publisher – sequence: 2 dbid: BENPR name: ProQuest Central url: https://www.proquest.com/central sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Biology |
| EISSN | 2045-2322 |
| EndPage | 8 |
| ExternalDocumentID | PMC6584554 10_1038_s41598_019_45142_x |
| GrantInformation_xml | – fundername: Ministry of Science and Technology, Taiwan (Ministry of Science and Technology of Taiwan) grantid: 107-2633-E-009-003 funderid: https://doi.org/10.13039/501100004663 – fundername: AU Optronics (AU Optronics Corp.) funderid: https://doi.org/10.13039/501100007634 – fundername: ; – fundername: ; grantid: 107-2633-E-009-003 |
| GroupedDBID | 0R~ 3V. 4.4 53G 5VS 7X7 88A 88E 88I 8FE 8FH 8FI 8FJ AAFWJ AAJSJ AAKDD ABDBF ABUWG ACGFS ACSMW ACUHS ADBBV ADRAZ AENEX AEUYN AFKRA AJTQC ALIPV ALMA_UNASSIGNED_HOLDINGS AOIJS AZQEC BAWUL BBNVY BCNDV BENPR BHPHI BPHCQ BVXVI C6C CCPQU DIK DWQXO EBD EBLON EBS EJD ESX FYUFA GNUQQ GROUPED_DOAJ GX1 HCIFZ HH5 HMCUK HYE KQ8 LK8 M0L M1P M2P M48 M7P M~E NAO OK1 PIMPY PQQKQ PROAC PSQYO RNT RNTTT RPM SNYQT UKHRP AASML AAYXX AFPKN CITATION PHGZM PHGZT 7XB 8FK AARCD K9. PJZUB PKEHL PPXIY PQEST PQGLB PQUKI Q9U 7X8 5PM |
| ID | FETCH-LOGICAL-c517t-329cee517c9d0cb2f9047c95ecdbf7a6c9864a7e865617819706c6324ac513a73 |
| IEDL.DBID | M48 |
| ISSN | 2045-2322 |
| IngestDate | Thu Aug 21 18:29:30 EDT 2025 Tue Aug 05 09:29:20 EDT 2025 Wed Aug 13 09:12:45 EDT 2025 Tue Jul 01 03:08:53 EDT 2025 Thu Apr 24 22:51:39 EDT 2025 Fri Feb 21 02:38:54 EST 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Language | English |
| License | Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c517t-329cee517c9d0cb2f9047c95ecdbf7a6c9864a7e865617819706c6324ac513a73 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0000-0002-9686-7076 |
| OpenAccessLink | http://journals.scholarsportal.info/openUrl.xqy?doi=10.1038/s41598-019-45142-x |
| PMID | 31217432 |
| PQID | 2243462812 |
| PQPubID | 2041939 |
| PageCount | 8 |
| ParticipantIDs | pubmedcentral_primary_oai_pubmedcentral_nih_gov_6584554 proquest_miscellaneous_2244131207 proquest_journals_2243462812 crossref_citationtrail_10_1038_s41598_019_45142_x crossref_primary_10_1038_s41598_019_45142_x springer_journals_10_1038_s41598_019_45142_x |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2019-06-19 |
| PublicationDateYYYYMMDD | 2019-06-19 |
| PublicationDate_xml | – month: 06 year: 2019 text: 2019-06-19 day: 19 |
| PublicationDecade | 2010 |
| PublicationPlace | London |
| PublicationPlace_xml | – name: London |
| PublicationTitle | Scientific reports |
| PublicationTitleAbbrev | Sci Rep |
| PublicationYear | 2019 |
| Publisher | Nature Publishing Group UK Nature Publishing Group |
| Publisher_xml | – name: Nature Publishing Group UK – name: Nature Publishing Group |
| References | Zhang, Huang, Zhang, Li (CR3) 2014; 7 Ohsugi, Tokunaga, Kato, Yoneda, Isoda (CR33) 2015; 19 Song (CR19) 2016; 16 Liu (CR29) 2017; 5 Riley, Johnson, Schaef, Sundaram (CR34) 2013; 117 Bichsel, Buffat, Levy (CR31) 1986; 19 Yin (CR8) 2016; 108 CR15 Ruppert, Aslan, Heinz (CR1) 2014; 14 Zhou (CR12) 2016; 28 Duerloo, Li, Reed (CR11) 2014; 5 Huang (CR16) 2016; 18 Yang (CR22) 2017; 11 CR32 Lin (CR36) 2014; 26 Empante (CR14) 2017; 11 Huang (CR24) 2017; 4 Zhou (CR21) 2016; 29 Qu, Liu, Huang, Lee, Ahmed, Kim, Ruoff, Hone, Yoo (CR35) 2017; 29 Böker (CR4) 2001; 64 Sacher (CR28) 2010; 26 Han (CR30) 2016; 3 Sung (CR20) 2017; 12 Li, Duerloo, Wauson, Reed (CR18) 2016; 7 Nakaharai (CR7) 2015; 9 Keum (CR2) 2015; 11 Zhou (CR5) 2015; 137 MacNeill (CR9) 2016; 13 Chen (CR25) 2015; 9 Shao (CR10) 2016; 16 CR26 Park (CR13) 2015; 9 Wang (CR23) 2014; 26 Castillo (CR27) 2016; 61 Cho (CR6) 2015; 349 Ueno, Fukushima (CR17) 2015; 8 L Yang (45142_CR22) 2017; 11 Q Shao (45142_CR10) 2016; 16 DH Keum (45142_CR2) 2015; 11 45142_CR15 S Wang (45142_CR23) 2014; 26 L Yin (45142_CR8) 2016; 108 E Sacher (45142_CR28) 2010; 26 W Zhang (45142_CR3) 2014; 7 S Cho (45142_CR6) 2015; 349 K Ueno (45142_CR17) 2015; 8 Deshun Qu (45142_CR35) 2017; 29 JH Sung (45142_CR20) 2017; 12 C Castillo (45142_CR27) 2016; 61 S Song (45142_CR19) 2016; 16 M Liu (45142_CR29) 2017; 5 C Ruppert (45142_CR1) 2014; 14 Y Li (45142_CR18) 2016; 7 45142_CR26 R Bichsel (45142_CR31) 1986; 19 J-H Huang (45142_CR24) 2017; 4 IJ Ohsugi (45142_CR33) 2015; 19 BJ Riley (45142_CR34) 2013; 117 T Böker (45142_CR4) 2001; 64 GH Han (45142_CR30) 2016; 3 TA Empante (45142_CR14) 2017; 11 L Zhou (45142_CR12) 2016; 28 L Zhou (45142_CR5) 2015; 137 D MacNeill (45142_CR9) 2016; 13 S Nakaharai (45142_CR7) 2015; 9 HH Huang (45142_CR16) 2016; 18 J Zhou (45142_CR21) 2016; 29 JC Park (45142_CR13) 2015; 9 K-AN Duerloo (45142_CR11) 2014; 5 B Chen (45142_CR25) 2015; 9 45142_CR32 Y-F Lin (45142_CR36) 2014; 26 |
| References_xml | – volume: 9 start-page: 5976 year: 2015 end-page: 5983 ident: CR7 article-title: Electrostatically reversible polarity of ambipolar alpha-MoTe transistors publication-title: ACS Nano doi: 10.1021/acsnano.5b00736 – volume: 5 start-page: 1035 year: 2017 end-page: 1042 ident: CR29 article-title: Synthesis of few-layer 1T′-MoTe ultrathin nanosheets for high-performance pseudocapacitors publication-title: J. Mater. Chem. A doi: 10.1039/c6ta08206h – volume: 9 start-page: 6548 year: 2015 end-page: 6554 ident: CR13 article-title: Phase-engineered synthesis of centimeter-scale 1T′- and 2H-molybdenum ditelluride thin films publication-title: ACS Nano doi: 10.1021/acsnano.5b02511 – volume: 26 start-page: 6371 year: 2014 end-page: 6379 ident: CR23 article-title: Shape evolution of monolayer MoS crystals grown by chemical vapor deposition publication-title: Chemistry of Materials doi: 10.1021/cm5025662 – volume: 19 start-page: 1575 year: 1986 ident: CR31 article-title: Correlation between process conditions, chemical composition and morphology of MoS films prepared by RF planar magnetron sputtering publication-title: J. Phys. D: Appl. Phys. doi: 10.1088/0022-3727/19/8/025 – volume: 26 start-page: 3807 year: 2010 end-page: 3814 ident: CR28 article-title: Asymmetries in transition metal XPS spectra: metal nanoparticle structure, and interaction with the graphene-structured substrate surface publication-title: Langmuir doi: 10.1021/la902678x – volume: 29 start-page: 1606433 issue: 39 year: 2017 ident: CR35 article-title: Carrier-Type Modulation and Mobility Improvement of Thin MoTe2 publication-title: Advanced Materials doi: 10.1002/adma.201606433 – volume: 14 start-page: 6231 year: 2014 end-page: 6236 ident: CR1 article-title: Optical properties and band gap of single- and few-layer MoTe crystals publication-title: Nano Lett. doi: 10.1021/nl502557g – volume: 13 start-page: 300 year: 2016 end-page: 305 ident: CR9 article-title: Control of spin–orbit torques through crystal symmetry in WTe /ferromagnet bilayers publication-title: Nat. Phys. doi: 10.1038/nphys3933 – volume: 19 start-page: S5-301-S305-303 year: 2015 ident: CR33 article-title: Dissociation and sublimation of tellurium from the thermoelectric tellurides publication-title: Mater. Res. Innov. doi: 10.1179/1432891714z.0000000001097 – volume: 16 start-page: 7514 year: 2016 end-page: 7520 ident: CR10 article-title: Strong Rashba-Edelstein effect-induced spin-orbit torques in monolayer transition metal dichalcogenide/ferromagnet bilayers publication-title: Nano Lett. doi: 10.1021/acs.nanolett.6b03300 – volume: 11 start-page: 482 year: 2015 end-page: 486 ident: CR2 article-title: Bandgap opening in few-layered monoclinic MoTe publication-title: Nat. Phys. doi: 10.1038/nphys3314 – volume: 12 start-page: 1064 year: 2017 end-page: 1070 ident: CR20 article-title: Coplanar semiconductor-metal circuitry defined on few-layer MoTe via polymorphic heteroepitaxy publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2017.161 – volume: 16 start-page: 188 year: 2016 end-page: 193 ident: CR19 article-title: Room temperature semiconductor-metal transition of MoTe thin films engineered by strain publication-title: Nano Lett. doi: 10.1021/acs.nanolett.5b03481 – volume: 8 start-page: 095201 year: 2015 ident: CR17 article-title: Changes in structure and chemical composition of α-MoTe and β-MoTe during heating in vacuum conditions publication-title: Appl. Phys. Express doi: 10.7567/apex.8.095201 – volume: 18 start-page: 4086 year: 2016 end-page: 4094 ident: CR16 article-title: Controlling phase transition for single-layer MTe (M = Mo and W): Modulation of the potential barrier under strain publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/c5cp06706e – volume: 11 start-page: 1964 year: 2017 end-page: 1972 ident: CR22 article-title: Tellurization velocity-dependent metallic–semiconducting–metallic phase evolution in chemical vapor deposition growth of large-area, few-layer MoTe publication-title: ACS Nano doi: 10.1021/acsnano.6b08109 – volume: 108 start-page: 043503 year: 2016 ident: CR8 article-title: Ultrahigh sensitive MoTe phototransistors driven by carrier tunneling publication-title: Appl. Phys. Lett. doi: 10.1063/1.4941001 – volume: 7 year: 2016 ident: CR18 article-title: Structural semiconductor-to-semimetal phase transition in two-dimensional materials induced by electrostatic gating publication-title: Nat. Commun. doi: 10.1038/ncomms10671 – volume: 7 start-page: 1731 year: 2014 end-page: 1737 ident: CR3 article-title: Two-dimensional semiconductors with possible high room temperature mobility publication-title: Nano Res. doi: 10.1007/s12274-014-0532-x – volume: 64 start-page: 235305 year: 2001 ident: CR4 article-title: Band structure of MoS , MoSe , and a-MoTe : angle-resolved photoelectron spectroscopy and ab initio calculations publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.64.235305 – volume: 4 start-page: 1700157 year: 2017 ident: CR24 article-title: Large-area 2D layered MoTe by physical vapor deposition and solid-phase crystallization in a tellurium-free atmosphere publication-title: Adv. Mater. Interfaces doi: 10.1002/admi.201700157 – volume: 349 start-page: 625 year: 2015 end-page: 628 ident: CR6 article-title: Phase patterning for ohmic homojunction contact in MoTe publication-title: Science doi: 10.1126/science.aab3175 – volume: 28 start-page: 9526 year: 2016 end-page: 9531 ident: CR12 article-title: Synthesis of high-quality large-area homogenous 1T′ MoTe from chemical vapor deposition publication-title: Adv. Mater. doi: 10.1002/adma.201602687 – volume: 11 start-page: 900 year: 2017 end-page: 905 ident: CR14 article-title: Chemical vapor deposition growth of few-layer MoTe in the 2H, 1T′, and 1T phases: Tunable properties of MoTe films publication-title: ACS Nano doi: 10.1021/acsnano.6b07499 – ident: CR15 – volume: 3 start-page: 031010 year: 2016 ident: CR30 article-title: Absorption dichroism of monolayer 1T′-MoTe in visible range publication-title: 2D Materials doi: 10.1088/2053-1583/3/3/031010 – volume: 26 start-page: 3263 year: 2014 end-page: 3269 ident: CR36 article-title: Ambipolar MoTe transistors and their applications in logic circuits publication-title: Adv. Mater. doi: 10.1002/adma.201305845 – volume: 5 year: 2014 ident: CR11 article-title: Structural phase transitions in two-dimensional Mo- and W-dichalcogenide monolayers publication-title: Nat. Commun. doi: 10.1038/ncomms5214 – volume: 9 start-page: 5326 year: 2015 end-page: 5332 ident: CR25 article-title: Environmental changes in MoTe excitonic dynamics by defects-activated molecular interaction publication-title: ACS Nano doi: 10.1021/acsnano.5b00985 – ident: CR32 – volume: 29 start-page: 1603471 year: 2016 ident: CR21 article-title: Large-area and high-quality 2D transition metal telluride publication-title: Adv. Mater. doi: 10.1002/adma.201603471 – volume: 137 start-page: 11892 year: 2015 end-page: 11895 ident: CR5 article-title: Large-area synthesis of high-quality uniform few-layer MoTe publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b07452 – volume: 61 start-page: 2816 year: 2016 end-page: 2820 ident: CR27 article-title: Molybdenum trioxide thin films doped with gold nanoparticles grown by a sequential methodology: Photochemical metal-organic deposition (PMOD) and DC-magnetron sputtering publication-title: J. Chil. Chem. Soc. doi: 10.4067/S0717-97072016000100014 – ident: CR26 – volume: 117 start-page: 10128 year: 2013 end-page: 10134 ident: CR34 article-title: Sublimation–condensation of multiscale tellurium structures publication-title: J. Phys. Chem. C doi: 10.1021/jp400363a – ident: 45142_CR26 – volume: 117 start-page: 10128 year: 2013 ident: 45142_CR34 publication-title: J. Phys. Chem. C doi: 10.1021/jp400363a – volume: 9 start-page: 5976 year: 2015 ident: 45142_CR7 publication-title: ACS Nano doi: 10.1021/acsnano.5b00736 – volume: 9 start-page: 5326 year: 2015 ident: 45142_CR25 publication-title: ACS Nano doi: 10.1021/acsnano.5b00985 – ident: 45142_CR32 doi: 10.1016/B978-0-8155-2031-3.00005-3 – volume: 108 start-page: 043503 year: 2016 ident: 45142_CR8 publication-title: Appl. Phys. Lett. doi: 10.1063/1.4941001 – volume: 13 start-page: 300 year: 2016 ident: 45142_CR9 publication-title: Nat. Phys. doi: 10.1038/nphys3933 – volume: 11 start-page: 1964 year: 2017 ident: 45142_CR22 publication-title: ACS Nano doi: 10.1021/acsnano.6b08109 – volume: 26 start-page: 3807 year: 2010 ident: 45142_CR28 publication-title: Langmuir doi: 10.1021/la902678x – volume: 349 start-page: 625 year: 2015 ident: 45142_CR6 publication-title: Science doi: 10.1126/science.aab3175 – volume: 5 start-page: 1035 year: 2017 ident: 45142_CR29 publication-title: J. Mater. Chem. A doi: 10.1039/c6ta08206h – volume: 29 start-page: 1606433 issue: 39 year: 2017 ident: 45142_CR35 publication-title: Advanced Materials doi: 10.1002/adma.201606433 – volume: 19 start-page: 1575 year: 1986 ident: 45142_CR31 publication-title: J. Phys. D: Appl. Phys. doi: 10.1088/0022-3727/19/8/025 – volume: 14 start-page: 6231 year: 2014 ident: 45142_CR1 publication-title: Nano Lett. doi: 10.1021/nl502557g – volume: 137 start-page: 11892 year: 2015 ident: 45142_CR5 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b07452 – volume: 16 start-page: 7514 year: 2016 ident: 45142_CR10 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.6b03300 – volume: 11 start-page: 900 year: 2017 ident: 45142_CR14 publication-title: ACS Nano doi: 10.1021/acsnano.6b07499 – volume: 7 year: 2016 ident: 45142_CR18 publication-title: Nat. Commun. doi: 10.1038/ncomms10671 – volume: 61 start-page: 2816 year: 2016 ident: 45142_CR27 publication-title: J. Chil. Chem. Soc. doi: 10.4067/S0717-97072016000100014 – volume: 7 start-page: 1731 year: 2014 ident: 45142_CR3 publication-title: Nano Res. doi: 10.1007/s12274-014-0532-x – volume: 5 year: 2014 ident: 45142_CR11 publication-title: Nat. Commun. doi: 10.1038/ncomms5214 – volume: 28 start-page: 9526 year: 2016 ident: 45142_CR12 publication-title: Adv. Mater. doi: 10.1002/adma.201602687 – volume: 3 start-page: 031010 year: 2016 ident: 45142_CR30 publication-title: 2D Materials doi: 10.1088/2053-1583/3/3/031010 – volume: 26 start-page: 3263 year: 2014 ident: 45142_CR36 publication-title: Adv. Mater. doi: 10.1002/adma.201305845 – volume: 9 start-page: 6548 year: 2015 ident: 45142_CR13 publication-title: ACS Nano doi: 10.1021/acsnano.5b02511 – volume: 12 start-page: 1064 year: 2017 ident: 45142_CR20 publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2017.161 – volume: 19 start-page: S5-301-S305-303 year: 2015 ident: 45142_CR33 publication-title: Mater. Res. Innov. doi: 10.1179/1432891714z.0000000001097 – volume: 26 start-page: 6371 year: 2014 ident: 45142_CR23 publication-title: Chemistry of Materials doi: 10.1021/cm5025662 – volume: 4 start-page: 1700157 year: 2017 ident: 45142_CR24 publication-title: Adv. Mater. Interfaces doi: 10.1002/admi.201700157 – volume: 11 start-page: 482 year: 2015 ident: 45142_CR2 publication-title: Nat. Phys. doi: 10.1038/nphys3314 – volume: 64 start-page: 235305 year: 2001 ident: 45142_CR4 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.64.235305 – volume: 18 start-page: 4086 year: 2016 ident: 45142_CR16 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/c5cp06706e – volume: 29 start-page: 1603471 year: 2016 ident: 45142_CR21 publication-title: Adv. Mater. doi: 10.1002/adma.201603471 – volume: 16 start-page: 188 year: 2016 ident: 45142_CR19 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.5b03481 – ident: 45142_CR15 doi: 10.1103/PhysRevB.92.161107 – volume: 8 start-page: 095201 year: 2015 ident: 45142_CR17 publication-title: Appl. Phys. Express doi: 10.7567/apex.8.095201 |
| SSID | ssj0000529419 |
| Score | 2.4390435 |
| Snippet | Two-dimensional (2D) molybdenum ditelluride (MoTe
2
) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at... Two-dimensional (2D) molybdenum ditelluride (MoTe2) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T′ phases at room... Two-dimensional (2D) molybdenum ditelluride (MoTe2) exhibits an intriguing polymorphic nature, showing stable semiconducting 2H and metallic 1T' phases at room... |
| SourceID | pubmedcentral proquest crossref springer |
| SourceType | Open Access Repository Aggregation Database Enrichment Source Index Database Publisher |
| StartPage | 1 |
| SubjectTerms | 140/133 140/146 639/301/357/1018 639/301/357/551 639/925/357/1018 639/925/357/551 Crystallization Electrical properties Humanities and Social Sciences Molybdenum multidisciplinary Polymorphism Science Science (multidisciplinary) |
| SummonAdditionalLinks | – databaseName: Health & Medical Collection dbid: 7X7 link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3dS8MwED90IvgifmJ1SgTfNNivLc2TyFREVAQnzKfSpg0Oajv3gdt_712bbkzQt0ASEu6S3C-53O8AzihKWatAc-mngvu6LXmgErzzoDXScSS1LKP4n57b92_-Q6_VMw9uI_Otsj4Ty4M6KRS9kV-iqfEojtJxrwZfnLJGkXfVpNBYhTWiLqNVLXpi_sZCXizfkSZWxvaCyxHaK4opcyT3ESq4fLpsjxYg8_cXyV9-0tL83G3BpsGN7LpS9DaspPkOrFeZJGe78P5SZHiLR6H1R5-sU_0_Z4Vmj9GMsnGyp6Kbusxk5WHd74LfEK9_xcnBXousn_CXDzRprDOcIWLMMhOguQdvd7fdzj03WRO4ajlizD1XouHDopKJrWJXS9vHcitVSaxF1FZEyB6JNEAk5wgEBMJuKyJtj7C_FwlvHxp5kacHwOzYI7Z6By89iY8XJ6kVIUapI4WwJVAWOLXsQmUoxSmzRRaWrm0vCCt5hyjvsJR3OLXgfN5nUBFq_Nu6WaskNJtrFC6WggWn82rcFuTriPK0mJRt0Dw7ri0sEEuqnI9KxNrLNXn_oyTYJlSGMMuCi1rpi8H_nuvh_3M9gg2X1h3lPZJNaIyHk_QYAc04PilX7Q8gUPQe priority: 102 providerName: ProQuest – databaseName: Springer Nature HAS Fully OA dbid: AAJSJ link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3dS8MwED9kQ_BF_MTqlAi-abBfW5rHMR0yVAQn6FNp04YNaiv7QPffe5e2k4kKvgWSkHBJer_r3f0O4IyylLUKNJd-KrivO5IHKkGbB7WRjiOppcniv7vv3Dz5g-f28xq4dS6MCdo3lJbmM11Hh11OUdFQMpgjuY863uWIG5tE1Y53u9ntDh4Hyz8r5LvyHVllyNhe8MPkVS30BS2_B0Z-844apdPfgs0KLbJuub9tWEvzHVgv60cuduHlocjQdkdRjaevrFdGnbNCs9toQTU42V0xTF1W1eJhw_eCXxGbf8nEwR6LbJzwhxEqMtabLBAnZlmVlrkHT_3rYe-GV7USuGo7YsY9V6K6w6aSia1iV0vbx3Y7VUmsRdRRRMMeiTRA_OYIhAHC7iiiao9wvhcJbx8aeZGnB8Ds2COOegdNncRHc0lqRThR6kghWAmUBU4tu1BVROJUzyILjUPbC8JS3iHKOzTyDj8sOF_OeStpNP4c3aqPJKye1DRErOFRIq3jWnC67MbHQB6OKE-LuRmDStlxbWGBWDnK5apEp73ak49HhlabsBiCKwsu6kP_Wvz3vR7-b_gRbLh0D6n6kWxBYzaZp8cIa2bxSXWPPwHrR_Pj priority: 102 providerName: Springer Nature |
| Title | Polymorphism Control of Layered MoTe2 through Two-Dimensional Solid-Phase Crystallization |
| URI | https://link.springer.com/article/10.1038/s41598-019-45142-x https://www.proquest.com/docview/2243462812 https://www.proquest.com/docview/2244131207 https://pubmed.ncbi.nlm.nih.gov/PMC6584554 |
| Volume | 9 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1da9swFL10LYO9jHYfzFsXNNjbps2WHct6KCNzW0pYSlgTyJ6MLVs04NptkrLm3-9e2U5J6QZ7svGX7CuZc67lew7AR6pSNjoyXAWF5IEJFY90jjkPopHJUmWUreIfnYdn02A46892oLM7agO4fDS1Iz-p6aL8cnez_oYv_FFTMh59XSIIUaGYp3iA-C84cso9RCZJjgajlu43Wt9CBdbrg0TYOZIJ0dbRPH6Zbay6J6APf598MIdqoel0H563nJINmkFwADtF9QKeNi6T65fwa1yXmOFjQOfLKxY3_6az2rAf6ZqcOtmonhSCtY49bPK75sek-d_odbCLupznfHyJcMfixRrZZFm2xZuvYHp6MonPeOuowHXfkyvuC4WgiKta5a7OhFFugOv9QueZkWmoSaw9lUWELM-TSBakG2oSdE_xfD-V_mvYreqqeAPMzXwKoocJUR5gUqWMJjapTKqR0kTaAa-LXaJbuXFyvSgTO-3tR0kT7wTjndh4J3cOfNqcc92Ibfzz6MOuS5Ju3CTISHwqt_WEAx82u_GVoXmQtCrqW3sMQrcnXOmA3OrKTaskur29p5pfWvFtYmxIwRz43HX6feN_v9e3__Vk7-CZoGFIFknqEHZXi9viPXKfVdaDJ3Ime7A3GAwvhrj8fnI-_olb4zDu2e8JPTvk_wA-xwN2 |
| linkProvider | Scholars Portal |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3da9swED-6jrG9jH1Sr92mwfa0idqyE1kPY4x0JV2TUlgK2ZNmyxYNuFbbpLT-p_Y37s4fCSmsb30T-JO7k36_0-nuAD5SlrI1seUqyiWPbF_x2GTo8yAa2TRRVtVZ_OOj_vAk-jntTTfgb5cLQ8cquzWxXqgzZ2iPfBehJqQ8ykB8O7_g1DWKoqtdC43GLA7z6hpdtvnXgz3U7ych9n9MBkPedhXgphfIBQ-FQmDAoVGZb1JhlR_huJebLLUy6RsqWJ7IPEamE0gETOn3DRU1T_D5MJEhvvcBPETg9cnZk1O53NOhqFkUqDY3xw_j3TniI-WwBYpHSE0Ev1nHvxWpvX0k81Zctoa7_WfwtOWp7HtjWM9hIy9fwKOmc2X1En4fu6I6c6ik2fyMDZrz7sxZNkoq6v7Jxm6SC9Z2AWKTa8f3qI9AUwOE_XLFLOPHpwihbHBZIUMtijYh9BWc3Is8X8Nm6cp8C5ifhlQdP0AnK4vQUVPWEENVNjFIk2LjQdDJTpu2hDl10ih0HUoPY93IW6O8dS1vfePB5-Uz500Bjzvv3ulUotvJPNcr0_Pgw_IyTkOKrSRl7q7qe5AOBMKXHsg1VS6_SoW816-Us9O6oDexQKR1HnzplL76-P__9c3d__oeHg8n45EeHRwdbsMTQTZIPZfUDmwuLq_yt0imFum72oIZ_LnvKfMPVo4wQA |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1LbxMxEB6VVCAuFU-xtICR4ARW9pV4fUAIkkYtbaMIUqmc3F3vWo20XZcmVbt_jV_HzD4SpRK99WZpn5oZe77xeOYD-EBVykZHhsswEzw0fckjnWLMg97IJLE0sqriPxr3947DHye9kw3429bC0LHKdk2sFurUatoj76KrCaiO0vO7pjkWMRmOvl784cQgRZnWlk6jNpGDrLzG8G3-ZX-Iuv7o-6Pd6WCPNwwDXPc8seCBL9FJ4FDL1NWJb6Qb4riX6TQxIu5ral4eiyxC1OMJdJ7C7WtqcB7j80EsAnzvA9gUFBV1YPP77njyc7nDQzm00JNNpY4bRN05ekuqaPMkDxGo-Pxm3RuuIO7tA5q3srSV8xs9ga0GtbJvtZk9hY2seAYPax7L8jn8nti8PLeostn8nA3q0-_MGnYYl8QFyo7sNPNZwwnEpteWD4lVoO4Iwn7ZfJbyyRk6VDa4LBGv5nlTHvoCju9Foi-hU9giewXMTQLqle9hyJWGGLZJowmvShNrBE2RdsBrZad009CceDVyVSXWg0jV8lYob1XJW9048Gn5zEXdzuPOu3dalahmas_VyhAdeL-8jJOSMi1xkdmr6h4EB57vCgfEmiqXX6W23utXitlZ1d6bMCGCPAc-t0pfffz___r67n99B49wuqjD_fHBNjz2yQSJgEnuQGdxeZW9QWS1SN42Jszg9L5nzT-z0zXb |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Polymorphism+Control+of+Layered+MoTe2+through+Two-Dimensional+Solid-Phase+Crystallization&rft.jtitle=Scientific+reports&rft.au=Huang%2C+Jyun-Hong&rft.au=Hsu%2C+Hao-Hua&rft.au=Wang%2C+Ding&rft.au=Lin%2C+Wei-Ting&rft.date=2019-06-19&rft.issn=2045-2322&rft.eissn=2045-2322&rft.volume=9&rft.issue=1&rft_id=info:doi/10.1038%2Fs41598-019-45142-x&rft.externalDBID=n%2Fa&rft.externalDocID=10_1038_s41598_019_45142_x |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2045-2322&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2045-2322&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2045-2322&client=summon |