Bifunctional Molecular Photoswitches Based on Overcrowded Alkenes for Dynamic Control of Catalytic Activity in Michael Addition Reactions

The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light‐responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal‐catalysed transformations. While our group has already disclosed systems featur...

Full description

Saved in:
Bibliographic Details
Published inChemistry : a European journal Vol. 23; no. 25; pp. 6174 - 6184
Main Authors Pizzolato, Stefano F., Collins, Beatrice S. L., van Leeuwen, Thomas, Feringa, Ben L.
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 02.05.2017
Wiley Subscription Services, Inc
Subjects
activity control
Alkenes
Amination
Beta rays
Catalysis
Catalytic activity
Chemistry
Chemistry, Multidisciplinary
Coupling (molecular)
Dynamic control
Functional groups
Irradiation
Isomers
Metastable state
Michael addition
Michael reaction
Molecular machines
Molecular motors
molecular switches
photochemistry
photoswitchable catalysts
Physical Sciences
Science & Technology
Selectivity
Switches
Thiourea
Thioureas
Michael addition
ASYMMETRIC CATALYSIS
activity control
LIGHT
BAYLIS-HILLMAN REACTION
ROTAXANE
AMINE-THIOUREAS
photoswitchable catalysts
CHEMICAL-REACTIONS
BOND DONORS
photochemistry
SWITCHABLE ORGANOCATALYST
BETA-CYCLODEXTRIN
MOTORS
molecular switches
Online AccessGet full text

Cover

Abstract The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light‐responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal‐catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen‐donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light‐responsive central cores were synthesized by a Barton–Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald–Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)‐3‐bromo‐β‐nitrostyrene and 2,4‐pentanedione is achieved upon irradiation of stable‐(E) and stable‐(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches. Clap on, clap off: The synthesis of two bifunctional molecular switches and the experimental study of their photochemical and catalytic behaviour is presented. Dynamic control of catalytic activity of the Michael addition reaction is achieved upon irradiation of stable‐(E)‐1 and stable‐(Z)‐1. This demonstrates that both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
AbstractList The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo--nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light‐responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal‐catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen‐donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light‐responsive central cores were synthesized by a Barton–Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald–Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)‐3‐bromo‐β‐nitrostyrene and 2,4‐pentanedione is achieved upon irradiation of stable‐(E) and stable‐(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches. Clap on, clap off: The synthesis of two bifunctional molecular switches and the experimental study of their photochemical and catalytic behaviour is presented. Dynamic control of catalytic activity of the Michael addition reaction is achieved upon irradiation of stable‐(E)‐1 and stable‐(Z)‐1. This demonstrates that both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo-[beta]-nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo-β-nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo-β-nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light‐responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal‐catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen‐donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light‐responsive central cores were synthesized by a Barton–Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald–Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between ( E )‐3‐bromo‐β‐nitrostyrene and 2,4‐pentanedione is achieved upon irradiation of stable‐( E ) and stable‐( Z ) isomers of the bifunctional catalyst 1 . Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo-β-nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches.
Author Pizzolato, Stefano F.
Collins, Beatrice S. L.
Feringa, Ben L.
van Leeuwen, Thomas
Author_xml – sequence: 1
  givenname: Stefano F.
  surname: Pizzolato
  fullname: Pizzolato, Stefano F.
  organization: University of Groningen
– sequence: 2
  givenname: Beatrice S. L.
  surname: Collins
  fullname: Collins, Beatrice S. L.
  organization: University of Groningen
– sequence: 3
  givenname: Thomas
  surname: van Leeuwen
  fullname: van Leeuwen, Thomas
  organization: University of Groningen
– sequence: 4
  givenname: Ben L.
  surname: Feringa
  fullname: Feringa, Ben L.
  email: b.l.feringa@rug.nl
  organization: University of Groningen
BackLink https://www.ncbi.nlm.nih.gov/pubmed/27880015$$D View this record in MEDLINE/PubMed
BookMark eNqNkk1vEzEQhi1URNPClSOyxKUS2mDvh9c-pkuhSI2KEJxXjj2ruDh2sb2N8hP413hJCFIlBCd_Pe-845k5QyfOO0DoJSVzSkj5Vq1hMy8JZaQWjD1BM9qUtKha1pygGRF1W7CmEqfoLMY7QohgVfUMnZYt54TQZoZ-XJphdCoZ76TFS29BjVYG_Gntk49bk7JBxJcygsbe4dsHCCr4rc7Hhf0GLj8OPuB3Oyc3RuHOuxS8xX7AnUzS7lK-XOTwDybtsHF4adRagsULrc1kij-D_OUen6Ong7QRXhzWc_T1_dWX7rq4uf3wsVvcFKqhjBWcaKbFSnA9tLxVbaOp1HqlBONQCRCNgJYI2kKpOaUtk6oEoRpV8zZ_n1fVObrYx70P_vsIMfUbExVYKx34MfaU15WgjFcso68foXd-DLlQEyUawmvOm0y9OlDjagO6vw9mI8Ou_13kDLzZA1tY-SEqA07BEctdqQlpMjrtpvz4_9OdSXKqXudHl7J0vpfmFsUYYDjKKOmncemncemP45IF9SOBOgRMQRr7d5k4pGgs7P5h0nfXV8s_2p84LtL-
CitedBy_id crossref_primary_10_1039_C7CY01614J
crossref_primary_10_1002_ejoc_201701602
crossref_primary_10_1021_acs_organomet_7b00493
crossref_primary_10_1039_D0CY01090A
crossref_primary_10_1039_D2SC05903G
crossref_primary_10_1002_anie_202104285
crossref_primary_10_1021_acsami_8b21719
crossref_primary_10_1039_C9CC01891C
crossref_primary_10_1002_ange_202104285
crossref_primary_10_1002_ange_202302859
crossref_primary_10_1002_ange_201913054
crossref_primary_10_1002_EXP_20210095
crossref_primary_10_1007_s41061_018_0209_0
crossref_primary_10_1021_acscatal_3c04435
crossref_primary_10_1021_acscatal_8b00328
crossref_primary_10_3390_molecules25020401
crossref_primary_10_1021_acs_jcim_3c01953
crossref_primary_10_1002_asia_202300633
crossref_primary_10_1002_anie_202302859
crossref_primary_10_1016_j_tet_2017_05_064
crossref_primary_10_1021_acs_joc_1c02991
crossref_primary_10_1002_anie_201913054
crossref_primary_10_1002_cptc_201900038
crossref_primary_10_1016_j_jphotochemrev_2017_12_004
crossref_primary_10_1021_acs_joc_9b00783
Cites_doi 10.1002/chem.201201383
10.1002/chem.201002384
10.1039/C39800000837
10.1002/anie.201000146
10.1021/ja052511x
10.1039/c3ob41403e
10.1002/ange.200800869
10.1002/chem.200800969
10.1016/S0040-4039(01)98134-1
10.1021/ja509236u
10.1002/ange.200604366
10.1039/c2sc00907b
10.1021/ja029331x
10.1002/chem.201602276
10.1002/anie.200703034
10.1002/anie.201201364
10.1039/c1cy00271f
10.1002/anie.200462538
10.1073/pnas.0903710106
10.1038/nchem.872
10.1039/C4CC03394A
10.1021/ja807694s
10.1039/C6SC02646J
10.1002/anie.201105374
10.1021/ol061298m
10.1002/9780470638859
10.1038/nature01601
10.1002/ange.200601584
10.1038/43646
10.1021/om400348h
10.1002/anie.200604366
10.1039/C1OB06518A
10.1002/1521-3927(20010301)22:6<448::AID-MARC448>3.0.CO;2-W
10.1039/C4SC03279A
10.1002/anie.199504461
10.1002/ange.201201447
10.1002/ange.201201364
10.1039/c4cc00794h
10.1021/ja0707052
10.1039/c2ob06908c
10.1016/j.tetlet.2004.05.137
10.1002/ange.200462538
10.1002/ange.200703034
10.1021/ol051822
10.1039/C5CS00096C
10.1002/ange.201105374
10.1002/chem.201002202
10.1021/ic050429x
10.1021/cr0300993
10.1002/anie.200601584
10.1021/ol902166a
10.1039/C6CC04090J
10.1126/science.1199844
10.1021/jo500411z
10.1002/anie.201201447
10.1021/ja012499i
10.1021/ol500381c
10.1021/cr300192h
10.1002/ange.200802050
10.1021/cr068057c
10.1021/jacs.6b00303
10.1038/ncomms7652
10.1002/anie.200503132
10.1021/acs.chemrev.5b00426
10.1201/9780203495902
10.1002/chem.201602453
10.1021/jo701764e
10.1002/ange.19951070417
10.1021/jo070394d
10.1002/ange.201000146
10.1021/ja983960i
10.1021/jp056906e
10.1021/cr068373r
10.1021/ja304067k
10.1002/anie.200802050
10.1038/nature10587
10.1246/cl.140680
10.1039/c3cs60383k
10.1039/b501779c
10.1002/ejoc.201200739
10.1002/chem.201600776
10.1007/978-3-642-20731-0
10.1126/science.1229753
10.1002/ange.200503132
10.1039/c29700001225
10.1039/c3cc42424c
10.1021/ja510700j
10.1248/cpb.58.593
10.1039/c6sc02646j
10.1039/c6cc04090j
10.1039/c1ob06518a
10.1021/ol051822+
10.1039/c4sc03279a
10.1039/c5cs00096c
10.1039/c4cc03394a
10.1038/NCHEM.872
ContentType Journal Article
Copyright 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright_xml – notice: 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
– notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
– notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
DBID AAYXX
CITATION
17B
1KM
95M
AGFEH
BLEPL
DTL
EGQ
GYRTJ
NPM
7SR
8BQ
8FD
JG9
K9.
7X8
DOI 10.1002/chem.201604966
DatabaseName CrossRef
Web of Knowledge
Index Chemicus
Conference Proceedings Citation Index - Science (CPCI-S)
Conference Proceedings Citation Index - Science (CPCI-S) 2017
Web of Science Core Collection
Science Citation Index Expanded
Web of Science Primary (SCIE, SSCI & AHCI)
Web of Science - Science Citation Index Expanded - 2017
PubMed
Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
MEDLINE - Academic
DatabaseTitle CrossRef
Web of Science
PubMed
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
Engineered Materials Abstracts
Technology Research Database
METADEX
MEDLINE - Academic
DatabaseTitleList Web of Science

Materials Research Database
MEDLINE - Academic
CrossRef
PubMed
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
– sequence: 2
  dbid: 1KM
  name: Index Chemicus
  url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC
  sourceTypes:
    Enrichment Source
    Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1521-3765
EndPage 6184
ExternalDocumentID 27880015
000400580000043
10_1002_chem_201604966
CHEM201604966
Genre article
Journal Article
GrantInformation_xml – fundername: Rijksuniversiteit Groningen
– fundername: The Royal Netherlands Academy of Arts and Sciences (KNAW)
– fundername: Ministry of Education, Culture and Science (Gravitation program)
  funderid: 024.001.035
– fundername: The Netherlands Organization for Scientific Research (NWO-CW)
– fundername: Foundation for Fundamental Research on Matter
– fundername: Zernike Institute for Advanced Materials
– fundername: European Research Council
  funderid: 227897
– fundername: Ministry of Education, Culture and Science; Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)
  grantid: 024.001.035
– fundername: University of Groningen
– fundername: European Research Council; European Research Council (ERC)
  grantid: 227897
– fundername: Royal Netherlands Academy of Arts and Sciences (KNAW)
– fundername: Foundation for Fundamental Research on Matter (FOM, a subsidiary of NWO)
– fundername: Netherlands Organization for Scientific Research (NWO-CW); Netherlands Organization for Scientific Research (NWO)
– fundername: European Research Council
  grantid: 227897
GroupedDBID ---
-DZ
-~X
.3N
.GA
05W
0R~
10A
1L6
1OB
1OC
1ZS
29B
33P
3SF
3WU
4.4
4ZD
50Y
50Z
51W
51X
52M
52N
52O
52P
52S
52T
52U
52W
52X
53G
5GY
5VS
66C
6J9
702
77Q
7PT
8-0
8-1
8-3
8-4
8-5
8UM
930
A03
AAESR
AAEVG
AAHHS
AAHQN
AAMNL
AANLZ
AAONW
AASGY
AAXRX
AAYCA
AAZKR
ABCQN
ABCUV
ABDBF
ABIJN
ABJNI
ABLJU
ABPVW
ACAHQ
ACCFJ
ACCZN
ACGFS
ACIWK
ACNCT
ACPOU
ACUHS
ACXBN
ACXQS
ADBBV
ADEOM
ADIZJ
ADKYN
ADMGS
ADOZA
ADXAS
ADZMN
ADZOD
AEEZP
AEGXH
AEIGN
AEIMD
AEQDE
AEUQT
AEUYR
AFBPY
AFFPM
AFGKR
AFPWT
AFRAH
AFWVQ
AFZJQ
AHBTC
AHMBA
AITYG
AIURR
AIWBW
AJBDE
AJXKR
ALAGY
ALMA_UNASSIGNED_HOLDINGS
ALVPJ
AMBMR
AMYDB
ATUGU
AUFTA
AZBYB
AZVAB
BAFTC
BDRZF
BFHJK
BHBCM
BMNLL
BMXJE
BNHUX
BROTX
BRXPI
BY8
CS3
D-E
D-F
DCZOG
DPXWK
DR2
DRFUL
DRSTM
EBD
EBS
EJD
F00
F01
F04
F5P
G-S
G.N
GNP
GODZA
H.T
H.X
HBH
HGLYW
HHY
HHZ
HZ~
IX1
J0M
JPC
KQQ
LATKE
LAW
LC2
LC3
LEEKS
LH4
LITHE
LOXES
LP6
LP7
LUTES
LW6
LYRES
MEWTI
MK4
MRFUL
MRSTM
MSFUL
MSSTM
MXFUL
MXSTM
N04
N05
N9A
NF~
NNB
O66
O9-
OIG
P2W
P2X
P4D
PQQKQ
Q.N
Q11
QB0
QRW
R.K
RGC
RNS
ROL
RWI
RX1
RYL
SUPJJ
TN5
TWZ
UB1
UPT
V2E
V8K
W8V
W99
WBFHL
WBKPD
WH7
WIB
WIH
WIK
WJL
WOHZO
WQJ
WRC
WXSBR
WYISQ
XG1
XPP
XV2
YZZ
ZZTAW
~IA
~WT
AAYXX
AEYWJ
AGHNM
AGYGG
CITATION
17B
1KM
95M
AGFEH
BLEPL
DTL
GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED
GROUPED_WOS_WEB_OF_SCIENCE
NPM
7SR
8BQ
8FD
JG9
K9.
7X8
ID FETCH-LOGICAL-c5166-80d6d9b98df787c75d1addbc968e39e959e70917e2d81176ac2e9c5c487009833
IEDL.DBID DR2
ISICitedReferencesCount 23
ISICitedReferencesURI https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000400580000043
ISSN 0947-6539
1521-3765
IngestDate Fri Jul 11 04:58:33 EDT 2025
Fri Jul 25 10:08:58 EDT 2025
Mon Jul 21 06:01:41 EDT 2025
Fri Aug 29 16:18:07 EDT 2025
Wed Jul 09 19:14:33 EDT 2025
Thu Apr 24 22:51:32 EDT 2025
Tue Jul 01 02:47:35 EDT 2025
Wed Jan 22 16:27:17 EST 2025
IsDoiOpenAccess false
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 25
Keywords Michael addition
ASYMMETRIC CATALYSIS
activity control
LIGHT
BAYLIS-HILLMAN REACTION
ROTAXANE
AMINE-THIOUREAS
photoswitchable catalysts
CHEMICAL-REACTIONS
BOND DONORS
photochemistry
SWITCHABLE ORGANOCATALYST
BETA-CYCLODEXTRIN
MOTORS
molecular switches
Language English
License http://onlinelibrary.wiley.com/termsAndConditions#vor
2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
LinkModel DirectLink
LogoURL https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg
MergedId FETCHMERGED-LOGICAL-c5166-80d6d9b98df787c75d1addbc968e39e959e70917e2d81176ac2e9c5c487009833
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ORCID 0000-0002-2545-3458
OpenAccessLink https://research.rug.nl/en/publications/bbe5bcbc-b886-42f7-9f99-e2aa259d6747
PMID 27880015
PQID 1895084885
PQPubID 986340
PageCount 11
ParticipantIDs proquest_journals_1895084885
webofscience_primary_000400580000043
proquest_miscellaneous_1843916836
webofscience_primary_000400580000043CitationCount
wiley_primary_10_1002_chem_201604966_CHEM201604966
crossref_primary_10_1002_chem_201604966
pubmed_primary_27880015
crossref_citationtrail_10_1002_chem_201604966
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate May 2, 2017
PublicationDateYYYYMMDD 2017-05-02
PublicationDate_xml – month: 05
  year: 2017
  text: May 2, 2017
  day: 02
PublicationDecade 2010
PublicationPlace WEINHEIM
PublicationPlace_xml – name: WEINHEIM
– name: Germany
– name: Weinheim
PublicationSubtitle A European Journal
PublicationTitle Chemistry : a European journal
PublicationTitleAbbrev CHEM-EUR J
PublicationTitleAlternate Chemistry
PublicationYear 2017
Publisher Wiley
Wiley Subscription Services, Inc
Publisher_xml – name: Wiley
– name: Wiley Subscription Services, Inc
References 2011; 479
2017; 8
2007; 107
2010; 16
2010; 58
1999; 121
2012; 18
2007; 72
1970
2008 2008; 47 120
2011; 17
1999; 401
2012; 10
2014; 136
2009; 11
2012; 134
2013; 11
2005; 100
2012 2012; 51 124
2015; 44
2005; 105
2014; 16
2005 2005; 44 117
2013; 113
2016; 116
1980
2003; 125
2014; 50
2007; 129
2015; 6
2013; 49
2011; 1
2012
2011
2010
2004; 45
2008; 14
1970; 11
2006; 8
2006; 110
2010 2010; 49 122
2003
2009; 131
2001; 22
2011; 3
2008; 120
2005; 44
2011; 331
2014; 43
2006 2006; 45 118
2012; 3
2013; 32
2013; 339
1995 1995; 34 107
2002; 124
2005; 127
2007 2007; 46 119
2005; 7
2014; 79
2011 2011; 50 123
2016; 138
2016 2016; 52 52
2003; 422
2009; 109
2016; 22
2009; 106
e_1_2_5_27_1
e_1_2_5_25_1
e_1_2_5_48_1
e_1_2_5_23_1
e_1_2_5_46_1
e_1_2_5_21_1
e_1_2_5_44_1
e_1_2_5_65_1
e_1_2_5_67_1
e_1_2_5_69_1
e_1_2_5_29_1
e_1_2_5_61_1
e_1_2_5_61_2
e_1_2_5_63_1
e_1_2_5_42_1
e_1_2_5_15_1
e_1_2_5_38_1
e_1_2_5_17_1
e_1_2_5_36_1
e_1_2_5_59_1
e_1_2_5_9_1
e_1_2_5_11_1
e_1_2_5_34_1
e_1_2_5_57_1
e_1_2_5_7_1
e_1_2_5_34_2
e_1_2_5_13_1
e_1_2_5_32_1
e_1_2_5_55_1
e_1_2_5_5_1
e_1_2_5_76_1
e_1_2_5_3_1
e_1_2_5_1_2
e_1_2_5_78_1
e_1_2_5_1_1
e_1_2_5_19_1
e_1_2_5_17_2
e_1_2_5_70_1
e_1_2_5_72_1
e_1_2_5_74_1
e_1_2_5_30_1
e_1_2_5_53_1
e_1_2_5_30_2
Horspool W. M. (e_1_2_5_40_1) 2003
e_1_2_5_51_1
e_1_2_5_28_1
e_1_2_5_49_1
e_1_2_5_26_1
e_1_2_5_47_1
e_1_2_5_22_2
e_1_2_5_24_1
e_1_2_5_45_1
e_1_2_5_22_1
e_1_2_5_43_1
e_1_2_5_66_1
e_1_2_5_68_1
e_1_2_5_60_1
e_1_2_5_62_1
e_1_2_5_64_1
e_1_2_5_20_1
e_1_2_5_41_1
e_1_2_5_14_1
e_1_2_5_39_1
e_1_2_5_16_2
e_1_2_5_8_2
e_1_2_5_16_1
e_1_2_5_37_1
e_1_2_5_58_1
e_1_2_5_8_1
e_1_2_5_33_2
e_1_2_5_56_2
e_1_2_5_6_2
e_1_2_5_10_1
e_1_2_5_35_1
e_1_2_5_56_1
e_1_2_5_6_1
e_1_2_5_12_1
e_1_2_5_33_1
e_1_2_5_54_1
e_1_2_5_4_1
e_1_2_5_77_1
e_1_2_5_2_1
e_1_2_5_77_2
e_1_2_5_79_1
e_1_2_5_18_1
e_1_2_5_71_1
e_1_2_5_73_1
e_1_2_5_75_1
e_1_2_5_31_1
e_1_2_5_52_1
e_1_2_5_50_1
Samachetty, HD (WOS:000229440800022) 2005
Kottas, GS (WOS:000228412800006) 2005; 105
Lemieux, V (WOS:000241637500006) 2006; 45
Neilson, BM (WOS:000319650300030) 2013; 32
Neilson, BM (WOS:000306942600064) 2012; 134
Horspool, W. M. (000400580000043.35) 2003; 1
UENO, A (WOS:A1980KH22000031) 1980
(000400580000043.9) 2011; 123
Bauer, J (WOS:000336199800022) 2014; 79
Blanco, V (WOS:000344516600050) 2014; 136
Sud, D (WOS:000231255300001) 2005; 44
Declerck, V (WOS:000262482500001) 2009; 109
Siau, WY (WOS:000296026000002) 2011; 1
Osorio-Planes, L (WOS:000333477400043) 2014; 16
KELLOGG, RM (WOS:A1970G211900007) 1970
Wang, J (WOS:000231858100058) 2005; 7
Vlatkovic, M (WOS:000387854800002) 2016; 22
Wilson, D (WOS:000304345800030) 2012; 51
(000400580000043.2) 2010; 122
Fuerst, DE (WOS:000230010600032) 2005; 127
Wezenberg, SJ (WOS:000345883900022) 2014; 136
Geertsema, EM (WOS:000270537500009) 2009; 106
Sud, D (WOS:000250488400018) 2007; 46
BARTON, DHR (WOS:A1970H532200001) 1970
Wang, Z. (000400580000043.83) 2010
(000400580000043.10) 2008; 120
Taylor, MS (WOS:000235752600004) 2006; 45
Wei, Y (WOS:000323301200018) 2013; 113
(000400580000043.6) 2012; 124
Masson, G (WOS:000247558200002) 2007; 46
(000400580000043.8) 1995; 107
Stoll, RS (WOS:000262483100068) 2009; 131
Feringa, BL (WOS:000248978900001) 2007; 72
Sashuk, V (WOS:000374694500016) 2016; 22
Allen, AE (WOS:000299949500001) 2012; 3
Schliwa, M (WOS:000182272300050) 2003; 422
Zhao, DP (WOS:000353041200005) 2015; 6
Erno, Z (WOS:000301585600010) 2012; 10
Cakmak, Y (WOS:000370582900002) 2016; 138
Chen, CT (WOS:000391454500061) 2017; 8
Koumura, N (WOS:000082458800050) 1999; 401
(000400580000043.1) 2006; 118
(000400580000043.11) 2007; 119
Teator, AJ (WOS:000371106000007) 2016; 116
Vlatkovic, M (WOS:000338296300004) 2014; 50
Lippert, KM (WOS:000309923400006) 2012; 2012
Beswick, J (WOS:000345901600009) 2015; 6
Kudernac, T (WOS:000298030800037) 2011; 479
Doyle, AG (WOS:000251583300009) 2007; 107
Lewandowski, B (WOS:000313328200040) 2013; 339
Stoll, RS (WOS:000271097100007) 2009; 11
Klok, M (WOS:000261933000037) 2008; 14
Göstl, R (WOS:000332037200014) 2014; 43
Lee, WS (WOS:000168097600016) 2001; 22
Horspool, W. M. (000400580000043.36) 2003; 2
Stoll, RS (WOS:000280432100005) 2010; 49
Neilson, BM (WOS:000319226700005) 2013; 49
Imahori, T (WOS:000307782800003) 2012; 18
(000400580000043.4) 2006; 118
Blanco, V (WOS:000358219300017) 2015; 44
Koumura, N (WOS:000175369100031) 2002; 124
Lemieux, V. (000400580000043.49) 2008; 120
Peters, MV (WOS:000258165400006) 2008; 47
Ruangsupapichat, N (WOS:000285336900017) 2011; 3
(000400580000043.5) 2007; 119
Takemoto, Y (WOS:000277019100001) 2010; 58
Ikariya, T. (000400580000043.37) 2011
(000400580000043.7) 2005; 117
Cacciapaglia, R (WOS:000181088200045) 2003; 125
Serdyuk, OV (WOS:000326010300002) 2013; 11
Sohtome, Y (WOS:000222562100008) 2004; 45
Kistemaker, JCM (WOS:000383755200002) 2016; 22
Dai, ZR (WOS:000379481800009) 2016; 52
Bryantsev, VS (WOS:000236773100009) 2006; 110
Sud, D (WOS:000227997200028) 2005; 44
Wang, JB (WOS:000288504000039) 2011; 331
Samanta, M (WOS:000340899500004) 2014; 50
Shi, M (WOS:000251313600051) 2007; 72
Gao, YJ (WOS:000285230000010) 2010; 16
Li, X (WOS:000298555700030) 2012; 10
Imahori, T (WOS:000343272600001) 2014; 43
Yu, CG (WOS:000287259700006) 2011; 17
Niazov, T (WOS:000246535300015) 2007; 129
Blanco, V (WOS:000304044900024) 2012; 51
Berryman, OB (WOS:000296071700023) 2011; 50
(000400580000043.3) 2012; 124
WURTHNER, F (WOS:A1995QM40400008) 1995; 34
Sugimoto, H (WOS:000079242800044) 1999; 121
Berkessel, A (WOS:000240339700006) 2006; 8
References_xml – year: 2011
– volume: 45 118
  start-page: 1520 1550
  year: 2006 2006
  end-page: 1543 1573
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 18
  start-page: 10802
  year: 2012
  end-page: 10807
  publication-title: Chem. Eur. J.
– volume: 134
  start-page: 12693
  year: 2012
  end-page: 126939
  publication-title: J. Am. Chem. Soc.
– volume: 45 118
  start-page: 6820 6974
  year: 2006 2006
  end-page: 6824 6978
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 422
  start-page: 759
  year: 2003
  end-page: 765
  publication-title: Nature
– volume: 11
  start-page: 7051
  year: 2013
  end-page: 7071
  publication-title: Org. Biomol. Chem.
– volume: 131
  start-page: 357
  year: 2009
  end-page: 367
  publication-title: J. Am. Chem. Soc.
– volume: 16
  start-page: 13068
  year: 2010
  end-page: 13071
  publication-title: Chem. Eur. J.
– volume: 10
  start-page: 413
  year: 2012
  end-page: 420
  publication-title: Org. Biomol. Chem.
– volume: 51 124
  start-page: 5166 5256
  year: 2012 2012
  end-page: 5169 5259
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 136
  start-page: 15775
  year: 2014
  end-page: 15780
  publication-title: J. Am. Chem. Soc.
– volume: 22
  start-page: 13478
  year: 2016
  end-page: 13487
  publication-title: Chem. Eur. J.
– volume: 3
  start-page: 53
  year: 2011
  end-page: 60
  publication-title: Nat. Chem.
– start-page: 575
  year: 2010
  end-page: 581
– volume: 8
  start-page: 524
  year: 2017
  end-page: 529
  publication-title: Chem. Sci.
– volume: 32
  start-page: 3121
  year: 2013
  end-page: 3128
  publication-title: Organometallics
– volume: 109
  start-page: 1
  year: 2009
  end-page: 48
  publication-title: Chem. Rev.
– volume: 136
  start-page: 16784
  year: 2014
  end-page: 16787
  publication-title: J. Am. Chem. Soc.
– volume: 339
  start-page: 189
  year: 2013
  end-page: 193
  publication-title: Science
– volume: 11
  start-page: 1987
  year: 1970
  end-page: 1990
  publication-title: Tetrahedron Lett.
– volume: 11
  start-page: 4790
  year: 2009
  end-page: 4793
  publication-title: Org. Lett.
– volume: 106
  start-page: 16919
  year: 2009
  end-page: 16924
  publication-title: Proc. Natl. Acad. Sci. USA
– volume: 50
  start-page: 7773
  year: 2014
  end-page: 7775
  publication-title: Chem. Commun.
– volume: 107
  start-page: 5713
  year: 2007
  end-page: 5743
  publication-title: Chem. Rev.
– volume: 44 117
  start-page: 2019 2055
  year: 2005 2005
  end-page: 2021 2057
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 479
  start-page: 208
  year: 2011
  end-page: 211
  publication-title: Nature
– volume: 72
  start-page: 9779
  year: 2007
  end-page: 9781
  publication-title: J. Org. Chem.
– volume: 46 119
  start-page: 8017 8163
  year: 2007 2007
  end-page: 8019 8165
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 127
  start-page: 8964
  year: 2005
  end-page: 8965
  publication-title: J. Am. Chem. Soc.
– volume: 45
  start-page: 5589
  year: 2004
  end-page: 5592
  publication-title: Tetrahedron Lett.
– volume: 121
  start-page: 2325
  year: 1999
  end-page: 2326
  publication-title: J. Am. Chem. Soc.
– volume: 79
  start-page: 4446
  year: 2014
  end-page: 4455
  publication-title: J. Org. Chem.
– volume: 138
  start-page: 1749
  year: 2016
  end-page: 1751
  publication-title: J. Am. Chem. Soc.
– volume: 51 124
  start-page: 5431 5527
  year: 2012 2012
  end-page: 5434 5530
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– start-page: 1225
  year: 1970
  end-page: 1226
  publication-title: J. Chem. Soc. D
– volume: 50 123
  start-page: 9400 9572
  year: 2011 2011
  end-page: 9403 9575
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 10
  start-page: 2787
  year: 2012
  end-page: 2792
  publication-title: Org. Biomol. Chem.
– volume: 116
  start-page: 1969
  year: 2016
  end-page: 1992
  publication-title: Chem. Rev.
– volume: 124
  start-page: 5037
  year: 2002
  end-page: 5051
  publication-title: J. Am. Chem. Soc.
– start-page: 837
  year: 1980
  end-page: 838
  publication-title: J. Chem. Soc. Chem. Commun.
– volume: 6
  start-page: 6652
  year: 2015
  publication-title: Nat. Commun.
– volume: 401
  start-page: 152
  year: 1999
  end-page: 155
  publication-title: Nature
– volume: 129
  start-page: 6374
  year: 2007
  end-page: 6375
  publication-title: J. Am. Chem. Soc.
– volume: 49 122
  start-page: 5054 5176
  year: 2010 2010
  end-page: 5075 5200
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 17
  start-page: 770
  year: 2011
  end-page: 774
  publication-title: Chem. Eur. J.
– volume: 110
  start-page: 4678
  year: 2006
  end-page: 4688
  publication-title: J. Phys. Chem. A
– volume: 16
  start-page: 1704
  year: 2014
  end-page: 1707
  publication-title: Org. Lett.
– volume: 22
  start-page: 6528
  year: 2016
  end-page: 6531
  publication-title: Chem. Eur. J.
– volume: 72
  start-page: 6635
  year: 2007
  end-page: 6652
  publication-title: J. Org. Chem.
– year: 2003
– volume: 6
  start-page: 140
  year: 2015
  end-page: 143
  publication-title: Chem. Sci.
– volume: 113
  start-page: 6659
  year: 2013
  end-page: 6690
  publication-title: Chem. Rev.
– volume: 22
  start-page: 448
  year: 2001
  end-page: 450
  publication-title: Macromol. Rapid Commun.
– volume: 8
  start-page: 4195
  year: 2006
  end-page: 4198
  publication-title: Org. Lett.
– volume: 34 107
  start-page: 446 503
  year: 1995 1995
  end-page: 448 505
  publication-title: Angew. Chem. Int. Ed. Engl. Angew. Chem.
– volume: 331
  start-page: 1429
  year: 2011
  end-page: 1432
  publication-title: Science
– volume: 14
  start-page: 11183
  year: 2008
  end-page: 11193
  publication-title: Chem. Eur. J.
– start-page: 5919
  year: 2012
  end-page: 5927
  publication-title: Eur. J. Org. Chem.
– volume: 43
  start-page: 1982
  year: 2014
  end-page: 1996
  publication-title: Chem. Soc. Rev.
– volume: 52 52
  start-page: 8826 8826
  year: 2016 2016
  end-page: 8829 8829
  publication-title: Chem. Commun. Chem. Commun.
– volume: 120
  start-page: 5112
  year: 2008
  end-page: 5115
  publication-title: Angew. Chem.
– volume: 44
  start-page: 5960
  year: 2005
  end-page: 5962
  publication-title: Inorg. Chem.
– volume: 7
  start-page: 4293
  year: 2005
  end-page: 4296
  publication-title: Org. Lett.
– volume: 47 120
  start-page: 5968 6056
  year: 2008 2008
  end-page: 5972 6060
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 58
  start-page: 593
  year: 2010
  end-page: 601
  publication-title: Chem. Pharm. Bull.
– volume: 50
  start-page: 10577
  year: 2014
  end-page: 10579
  publication-title: Chem. Commun.
– volume: 46 119
  start-page: 4614 4698
  year: 2007 2007
  end-page: 4628 4712
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 1
  start-page: 1298
  year: 2011
  end-page: 1310
  publication-title: Catal. Sci. Technol.
– volume: 22
  start-page: 17080
  year: 2016
  end-page: 17111
  publication-title: Chem. Eur. J.
– volume: 49
  start-page: 5453
  year: 2013
  end-page: 5455
  publication-title: Chem. Commun.
– volume: 100
  start-page: 2840
  year: 2005
  end-page: 2842
  publication-title: Chem. Commun.
– volume: 105
  start-page: 1281
  year: 2005
  end-page: 1376
  publication-title: Chem. Rev.
– volume: 3
  start-page: 633
  year: 2012
  end-page: 658
  publication-title: Chem. Sci.
– volume: 43
  start-page: 1524
  year: 2014
  end-page: 1531
  publication-title: Chem. Lett.
– volume: 44
  start-page: 5341
  year: 2015
  end-page: 5370
  publication-title: Chem. Soc. Rev.
– volume: 125
  start-page: 2224
  year: 2003
  end-page: 2227
  publication-title: J. Am. Chem. Soc.
– ident: e_1_2_5_10_1
  doi: 10.1002/chem.201201383
– ident: e_1_2_5_64_1
  doi: 10.1002/chem.201002384
– ident: e_1_2_5_13_1
  doi: 10.1039/C39800000837
– ident: e_1_2_5_1_1
  doi: 10.1002/anie.201000146
– ident: e_1_2_5_68_1
  doi: 10.1021/ja052511x
– ident: e_1_2_5_45_1
  doi: 10.1039/c3ob41403e
– ident: e_1_2_5_27_1
  doi: 10.1002/ange.200800869
– ident: e_1_2_5_50_1
  doi: 10.1002/chem.200800969
– ident: e_1_2_5_70_1
  doi: 10.1016/S0040-4039(01)98134-1
– ident: e_1_2_5_57_1
  doi: 10.1021/ja509236u
– ident: e_1_2_5_77_2
  doi: 10.1002/ange.200604366
– ident: e_1_2_5_46_1
  doi: 10.1039/c2sc00907b
– ident: e_1_2_5_7_1
  doi: 10.1021/ja029331x
– ident: e_1_2_5_55_1
  doi: 10.1002/chem.201602276
– ident: e_1_2_5_33_1
  doi: 10.1002/anie.200703034
– ident: e_1_2_5_56_1
  doi: 10.1002/anie.201201364
– ident: e_1_2_5_44_1
  doi: 10.1039/c1cy00271f
– ident: e_1_2_5_8_1
  doi: 10.1002/anie.200462538
– ident: e_1_2_5_51_1
  doi: 10.1073/pnas.0903710106
– ident: e_1_2_5_52_1
  doi: 10.1038/nchem.872
– ident: e_1_2_5_11_1
  doi: 10.1039/C4CC03394A
– ident: e_1_2_5_18_1
  doi: 10.1021/ja807694s
– ident: e_1_2_5_26_1
  doi: 10.1039/C6SC02646J
– ident: e_1_2_5_17_1
  doi: 10.1002/anie.201105374
– ident: e_1_2_5_76_1
  doi: 10.1021/ol061298m
– ident: e_1_2_5_71_1
  doi: 10.1002/9780470638859
– ident: e_1_2_5_39_1
  doi: 10.1038/nature01601
– ident: e_1_2_5_30_2
  doi: 10.1002/ange.200601584
– ident: e_1_2_5_48_1
  doi: 10.1038/43646
– ident: e_1_2_5_25_1
  doi: 10.1021/om400348h
– ident: e_1_2_5_77_1
  doi: 10.1002/anie.200604366
– ident: e_1_2_5_66_1
  doi: 10.1039/C1OB06518A
– ident: e_1_2_5_14_1
  doi: 10.1002/1521-3927(20010301)22:6<448::AID-MARC448>3.0.CO;2-W
– ident: e_1_2_5_59_1
  doi: 10.1039/C4SC03279A
– ident: e_1_2_5_6_1
  doi: 10.1002/anie.199504461
– ident: e_1_2_5_22_2
  doi: 10.1002/ange.201201447
– ident: e_1_2_5_56_2
  doi: 10.1002/ange.201201364
– ident: e_1_2_5_12_1
  doi: 10.1039/c4cc00794h
– ident: e_1_2_5_21_1
  doi: 10.1021/ja0707052
– ident: e_1_2_5_32_1
  doi: 10.1039/c2ob06908c
– ident: e_1_2_5_75_1
  doi: 10.1016/j.tetlet.2004.05.137
– ident: e_1_2_5_8_2
  doi: 10.1002/ange.200462538
– ident: e_1_2_5_33_2
  doi: 10.1002/ange.200703034
– ident: e_1_2_5_73_1
– ident: e_1_2_5_67_1
  doi: 10.1021/ol051822
– ident: e_1_2_5_4_1
  doi: 10.1039/C5CS00096C
– ident: e_1_2_5_17_2
  doi: 10.1002/ange.201105374
– ident: e_1_2_5_63_1
  doi: 10.1002/chem.201002202
– ident: e_1_2_5_29_1
  doi: 10.1021/ic050429x
– ident: e_1_2_5_41_1
  doi: 10.1021/cr0300993
– ident: e_1_2_5_30_1
  doi: 10.1002/anie.200601584
– ident: e_1_2_5_19_1
  doi: 10.1021/ol902166a
– ident: e_1_2_5_34_2
  doi: 10.1039/C6CC04090J
– ident: e_1_2_5_9_1
  doi: 10.1126/science.1199844
– ident: e_1_2_5_54_1
  doi: 10.1021/jo500411z
– ident: e_1_2_5_22_1
  doi: 10.1002/anie.201201447
– ident: e_1_2_5_49_1
  doi: 10.1021/ja012499i
– ident: e_1_2_5_20_1
  doi: 10.1021/ol500381c
– ident: e_1_2_5_74_1
  doi: 10.1021/cr300192h
– ident: e_1_2_5_16_2
  doi: 10.1002/ange.200802050
– ident: e_1_2_5_78_1
  doi: 10.1021/cr068057c
– ident: e_1_2_5_60_1
  doi: 10.1021/jacs.6b00303
– ident: e_1_2_5_37_1
  doi: 10.1038/ncomms7652
– ident: e_1_2_5_61_1
  doi: 10.1002/anie.200503132
– ident: e_1_2_5_36_1
  doi: 10.1021/acs.chemrev.5b00426
– volume-title: CRC Handbook of Organic Photochemistry and Photobiology, Vols. 1, 2
  year: 2003
  ident: e_1_2_5_40_1
  doi: 10.1201/9780203495902
– ident: e_1_2_5_5_1
  doi: 10.1002/chem.201602453
– ident: e_1_2_5_31_1
  doi: 10.1021/jo701764e
– ident: e_1_2_5_6_2
  doi: 10.1002/ange.19951070417
– ident: e_1_2_5_42_1
  doi: 10.1021/jo070394d
– ident: e_1_2_5_1_2
  doi: 10.1002/ange.201000146
– ident: e_1_2_5_15_1
  doi: 10.1021/ja983960i
– ident: e_1_2_5_79_1
  doi: 10.1021/jp056906e
– ident: e_1_2_5_72_1
– ident: e_1_2_5_47_1
  doi: 10.1021/cr068373r
– ident: e_1_2_5_23_1
  doi: 10.1021/ja304067k
– ident: e_1_2_5_16_1
  doi: 10.1002/anie.200802050
– ident: e_1_2_5_53_1
  doi: 10.1038/nature10587
– ident: e_1_2_5_3_1
  doi: 10.1246/cl.140680
– ident: e_1_2_5_2_1
  doi: 10.1039/c3cs60383k
– ident: e_1_2_5_28_1
  doi: 10.1039/b501779c
– ident: e_1_2_5_65_1
  doi: 10.1002/ejoc.201200739
– ident: e_1_2_5_35_1
  doi: 10.1002/chem.201600776
– ident: e_1_2_5_43_1
  doi: 10.1007/978-3-642-20731-0
– ident: e_1_2_5_58_1
  doi: 10.1126/science.1229753
– ident: e_1_2_5_61_2
  doi: 10.1002/ange.200503132
– ident: e_1_2_5_69_1
  doi: 10.1039/c29700001225
– ident: e_1_2_5_34_1
  doi: 10.1039/C6CC04090J
– ident: e_1_2_5_24_1
  doi: 10.1039/c3cc42424c
– ident: e_1_2_5_38_1
  doi: 10.1021/ja510700j
– ident: e_1_2_5_62_1
  doi: 10.1248/cpb.58.593
– volume: 122
  start-page: 5176
  year: 2010
  ident: 000400580000043.2
  publication-title: Angew. Chem
– volume: 119
  start-page: 8163
  year: 2007
  ident: 000400580000043.5
  publication-title: Angew. Chem
– volume: 116
  start-page: 1969
  year: 2016
  ident: WOS:000371106000007
  article-title: Switchable Polymerization Catalysts
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/acs.chemrev.5b00426
– volume: 422
  start-page: 759
  year: 2003
  ident: WOS:000182272300050
  article-title: Molecular motors
  publication-title: NATURE
  doi: 10.1038/nature01601
– volume: 8
  start-page: 524
  year: 2017
  ident: WOS:000391454500061
  article-title: Enantiodivergent Steglich rearrangement of O-carboxylazlactones catalyzed by a chirality switchable helicene containing a 4-aminopyridine unit
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c6sc02646j
– volume: 11
  start-page: 4790
  year: 2009
  ident: WOS:000271097100007
  article-title: Immobilization of a Photoswitchable Piperidine Base
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol902166a
– start-page: 2840
  year: 2005
  ident: WOS:000229440800022
  article-title: Photomodulation of Lewis basicity in a pyridine-functionalized 1,2-dithienylcyclopentene
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/b501779c
– volume: 52
  start-page: 8826
  year: 2016
  ident: WOS:000379481800009
  article-title: Photoswitchable ring-opening polymerization of lactide catalyzed by azobenzene-based thiourea
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c6cc04090j
– volume: 479
  start-page: 208
  year: 2011
  ident: WOS:000298030800037
  article-title: Electrically driven directional motion of a four-wheeled molecule on a metal surface
  publication-title: NATURE
  doi: 10.1038/nature10587
– volume: 124
  start-page: 5256
  year: 2012
  ident: 000400580000043.3
  publication-title: Angew. Chem.
– volume: 72
  start-page: 6635
  year: 2007
  ident: WOS:000248978900001
  article-title: The art of building small: From molecular switches to molecular motors
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo070394d
– volume: 17
  start-page: 770
  year: 2011
  ident: WOS:000287259700006
  article-title: Interplay of Direct Stereocontrol and Dynamic Kinetic Resolution in a Bifunctional Amine Thiourea Catalyzed Highly Enantioselective Cascade Michael-Michael Reaction
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201002384
– volume: 119
  start-page: 4698
  year: 2007
  ident: 000400580000043.11
  publication-title: Angew. Chem.
– volume: 125
  start-page: 2224
  year: 2003
  ident: WOS:000181088200045
  article-title: The bis-barium complex of a butterfly crown ether as a phototunable supramolecular catalyst
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja029331x
– volume: 45
  start-page: 1520
  year: 2006
  ident: WOS:000235752600004
  article-title: Asymmetric catalysis by chiral hydrogen-bond donors
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200503132
– year: 2011
  ident: 000400580000043.37
  publication-title: Bifunctional Molecular Catalysis
– volume: 127
  start-page: 8964
  year: 2005
  ident: WOS:000230010600032
  article-title: Thiourea-catalyzed enantioselective cyanosilylation of ketones
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja052511x
– volume: 22
  start-page: 6528
  year: 2016
  ident: WOS:000374694500016
  article-title: A Thermo- and Photo-Switchable Ruthenium Initiator For Olefin Metathesis
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201600776
– volume: 58
  start-page: 593
  year: 2010
  ident: WOS:000277019100001
  article-title: Development of Chiral Thiourea Catalysts and Its Application to Asymmetric Catalytic Reactions
  publication-title: CHEMICAL & PHARMACEUTICAL BULLETIN
– volume: 49
  start-page: 5453
  year: 2013
  ident: WOS:000319226700005
  article-title: Photoswitchable NHC-promoted ring-opening polymerizations
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c3cc42424c
– volume: 22
  start-page: 13478
  year: 2016
  ident: WOS:000383755200002
  article-title: Spectroscopic and Theoretical Identification of Two Thermal Isomerization Pathways for Bistable Chiral Overcrowded Alkenes
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201602276
– start-page: 575
  year: 2010
  ident: 000400580000043.83
  publication-title: Comprehensive Organic Name Reactions and Reagents
– volume: 118
  start-page: 6974
  year: 2006
  ident: 000400580000043.1
  publication-title: Angew. Chem
– volume: 46
  start-page: 4614
  year: 2007
  ident: WOS:000247558200002
  article-title: The enantioselective morita-baylis-hiliman reaction and its aza counterpart
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200604366
– volume: 120
  start-page: 6056
  year: 2008
  ident: 000400580000043.10
  publication-title: Angew. Chem
– volume: 136
  start-page: 16784
  year: 2014
  ident: WOS:000345883900022
  article-title: Multi-State Regulation of the Dihydrogen Phosphate Binding Affinity to a Light- and Heat-Responsive Bis-Urea Receptor
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja510700j
– volume: 72
  start-page: 9779
  year: 2007
  ident: WOS:000251313600051
  article-title: Chiral bifunctional organocatalysts in asymmetric aza-Morita-Baylis-Hillman reactions of ethyl (Arylimino)acetates with methyl vinyl ketone and ethyl vinyl ketone
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo701764e
– volume: 113
  start-page: 6659
  year: 2013
  ident: WOS:000323301200018
  article-title: Recent Advances in Organocatalytic Asymmetric Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman Reactions
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/cr300192h
– volume: 22
  start-page: 448
  year: 2001
  ident: WOS:000168097600016
  article-title: Photocontrol of the catalytic activity of a β-cyclodextrin bearing azobenzene and histidine moieties as a pendant group
  publication-title: MACROMOLECULAR RAPID COMMUNICATIONS
– volume: 10
  start-page: 413
  year: 2012
  ident: WOS:000298555700030
  article-title: Asymmetric Michael addition reactions of 3-substituted benzofuran-2(3H)-ones to nitroolefins catalyzed by a bifunctional tertiary-amine thiourea
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c1ob06518a
– volume: 118
  start-page: 1550
  year: 2006
  ident: 000400580000043.4
  publication-title: Angew. Chem.
– volume: 136
  start-page: 15775
  year: 2014
  ident: WOS:000344516600050
  article-title: Exploring the Activation Modes of a Rotaxane-Based Switchable Organocatalyst
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja509236u
– volume: 7
  start-page: 4293
  year: 2005
  ident: WOS:000231858100058
  article-title: Chiral binaphthyl-derived amine-thiourea organocatalyst-promoted asymmetric Morita-Baylis-Hillman reaction
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol051822+
– volume: 109
  start-page: 1
  year: 2009
  ident: WOS:000262482500001
  article-title: aza-Baylis-Hillman Reaction
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/cr068057c
– volume: 3
  start-page: 633
  year: 2012
  ident: WOS:000299949500001
  article-title: Synergistic catalysis: A powerful synthetic strategy for new reaction development
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c2sc00907b
– volume: 6
  start-page: 140
  year: 2015
  ident: WOS:000345901600009
  article-title: Selecting reactions and reactants using a switchable rotaxane organocatalyst with two different active sites
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c4sc03279a
– volume: 10
  start-page: 2787
  year: 2012
  ident: WOS:000301585600010
  article-title: Using light and a molecular switch to 'lock' and 'unlock' the Diels-Alder reaction
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c2ob06908c
– volume: 16
  start-page: 1704
  year: 2014
  ident: WOS:000333477400043
  article-title: Photoswitchable Thioureas for the External Manipulation of Catalytic Activity
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol500381c
– volume: 44
  start-page: 2019
  year: 2005
  ident: WOS:000227997200028
  article-title: Photoswitching of stereoselectivity in catalysis using a copper dithienylethene complex
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200462538
– volume: 120
  start-page: 5112
  year: 2008
  ident: 000400580000043.49
  publication-title: Angew. Chem
– volume: 14
  start-page: 11183
  year: 2008
  ident: WOS:000261933000037
  article-title: New Mechanistic Insight in the Thermal Helix Inversion of Second-Generation Molecular Motors
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.200800969
– volume: 50
  start-page: 9400
  year: 2011
  ident: WOS:000296071700023
  article-title: Switchable Catalysis with a Light-Responsive Cavitand
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201105374
– volume: 105
  start-page: 1281
  year: 2005
  ident: WOS:000228412800006
  article-title: Artificial molecular rotors
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/cr0300993
– volume: 22
  start-page: 17080
  year: 2016
  ident: WOS:000387854800002
  article-title: Dynamic Responsive Systems for Catalytic Function
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201602453
– start-page: 1225
  year: 1970
  ident: WOS:A1970H532200001
  article-title: OLEFIN SYNTHESIS BY TWOFOLD EXTRUSION PROCESSES
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS
– volume: 79
  start-page: 4446
  year: 2014
  ident: WOS:000336199800022
  article-title: Tuning the Rotation Rate of Light-Driven Molecular Motors
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo500411z
– volume: 131
  start-page: 357
  year: 2009
  ident: WOS:000262483100068
  article-title: Photoswitchable Catalysts: Correlating Structure and Conformational Dynamics with Reactivity by a Combined Experimental and Computational Approach
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja807694s
– volume: 1
  start-page: 1298
  year: 2011
  ident: WOS:000296026000002
  article-title: Asymmetric organocatalytic reactions by bifunctional amine-thioureas
  publication-title: CATALYSIS SCIENCE & TECHNOLOGY
  doi: 10.1039/c1cy00271f
– volume: 106
  start-page: 16919
  year: 2009
  ident: WOS:000270537500009
  article-title: Optimizing rotary processes in synthetic molecular motors
  publication-title: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
  doi: 10.1073/pnas.0903710106
– volume: 18
  start-page: 10802
  year: 2012
  ident: WOS:000307782800003
  article-title: Azobenzene-Tethered Bis(Trityl Alcohol) as a Photoswitchable Cooperative Acid Catalyst for Morita-Baylis-Hillman Reactions
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201201383
– volume: 44
  start-page: 5341
  year: 2015
  ident: WOS:000358219300017
  article-title: Artificial switchable catalysts
  publication-title: CHEMICAL SOCIETY REVIEWS
  doi: 10.1039/c5cs00096c
– volume: 123
  start-page: 9572
  year: 2011
  ident: 000400580000043.9
  publication-title: Angew. Chem
– volume: 49
  start-page: 5054
  year: 2010
  ident: WOS:000280432100005
  article-title: Artificial Light-Gated Catalyst Systems
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201000146
– volume: 50
  start-page: 10577
  year: 2014
  ident: WOS:000340899500004
  article-title: A photoresponsive glycosidase mimic
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c4cc03394a
– volume: 8
  start-page: 4195
  year: 2006
  ident: WOS:000240339700006
  article-title: Asymmetric Morita-Baylis-Hillman reaction catalyzed by isophoronediamine-derived bis(thio)urea organocatalysts
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol061298m
– volume: 107
  start-page: 5713
  year: 2007
  ident: WOS:000251583300009
  article-title: Small-molecule H-bond donors in asymmetric catalysis
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/cr068373r
– volume: 47
  start-page: 5968
  year: 2008
  ident: WOS:000258165400006
  article-title: Photoswitching of basicity
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200802050
– volume: 44
  start-page: 5960
  year: 2005
  ident: WOS:000231255300001
  article-title: Synthesis and coordination chemistry of a photoswitchable bis(phosphine) ligand
  publication-title: INORGANIC CHEMISTRY
  doi: 10.1021/ic050429x
– volume: 124
  start-page: 5037
  year: 2002
  ident: WOS:000175369100031
  article-title: Second generation light-driven molecular motors. unidirectional rotation controlled by a single stereogenic center with near-perfect photoequilibria and acceleration of the speed of rotation by structural modification
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja012499i
– volume: 107
  start-page: 503
  year: 1995
  ident: 000400580000043.8
  publication-title: Angew. Chem
– volume: 129
  start-page: 6374
  year: 2007
  ident: WOS:000246535300015
  article-title: Photoswitchable electrocatalysis and catalyzed chemiluminescence using photoisomerizable monolayer-functionalized surfaces and Pt nanoparticles
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja0707052
– volume: 117
  start-page: 2055
  year: 2005
  ident: 000400580000043.7
  publication-title: Angew. Chem
– volume: 43
  start-page: 1524
  year: 2014
  ident: WOS:000343272600001
  article-title: Stimuli-responsive Cooperative Catalysts Based on Dynamic Conformational Changes toward Spatiotemporal Control of Chemical Reactions
  publication-title: CHEMISTRY LETTERS
  doi: 10.1246/cl.140680
– volume: 45
  start-page: 5589
  year: 2004
  ident: WOS:000222562100008
  article-title: Development of bis-thiourea-type organocatalyst for asymmetric Baylis-Hillman reaction
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2004.05.137
– volume: 51
  start-page: 5166
  year: 2012
  ident: WOS:000304044900024
  article-title: A Rotaxane-Based Switchable Organocatalyst
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201201364
– start-page: 837
  year: 1980
  ident: WOS:A1980KH22000031
  article-title: PHOTOREGULATION OF CATALYTIC ACTIVITY OF BETA-CYCLODEXTRIN BY AN AZO INHIBITOR
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
– volume: 46
  start-page: 8017
  year: 2007
  ident: WOS:000250488400018
  article-title: Creating a reactive enediyne by using visible light: Photocontrol of the bergman cyclization
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200703034
– volume: 43
  start-page: 1982
  year: 2014
  ident: WOS:000332037200014
  article-title: Remote-controlling chemical reactions by light: Towards chemistry with high spatio-temporal resolution
  publication-title: CHEMICAL SOCIETY REVIEWS
  doi: 10.1039/c3cs60383k
– volume: 331
  start-page: 1429
  year: 2011
  ident: WOS:000288504000039
  article-title: Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor
  publication-title: SCIENCE
  doi: 10.1126/science.1199844
– volume: 134
  start-page: 12693
  year: 2012
  ident: WOS:000306942600064
  article-title: Photoswitchable Organocatalysis: Using Light To Modulate the Catalytic Activities of N-Heterocyclic Carbenes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja304067k
– volume: 32
  start-page: 3121
  year: 2013
  ident: WOS:000319650300030
  article-title: Photoswitchable Metal-Mediated Catalysis: Remotely Tuned Alkene and Alkyne Hydroborations
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om400348h
– volume: 34
  start-page: 446
  year: 1995
  ident: WOS:A1995QM40400008
  article-title: LIGHT-SWITCHABLE CATALYSIS IN SYNTHETIC RECEPTORS
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
– volume: 2
  year: 2003
  ident: 000400580000043.36
  publication-title: CRC Handbook of Organic Photochemistry and Photobiology
– volume: 1
  year: 2003
  ident: 000400580000043.35
  publication-title: CRC Handbook of Organic Photochemistry and Photobiology
– volume: 401
  start-page: 152
  year: 1999
  ident: WOS:000082458800050
  article-title: Light-driven monodirectional molecular rotor
  publication-title: NATURE
– volume: 11
  start-page: 7051
  year: 2013
  ident: WOS:000326010300002
  article-title: Bifunctional primary amine-thioureas in asymmetric organocatalysis
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c3ob41403e
– volume: 51
  start-page: 5431
  year: 2012
  ident: WOS:000304345800030
  article-title: Turning "On" and "Off" a Pyridoxal 5'-Phosphate Mimic Using Light
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201201447
– volume: 45
  start-page: 6820
  year: 2006
  ident: WOS:000241637500006
  article-title: Selective and sequential photorelease using molecular switches
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200601584
– volume: 6
  start-page: ARTN 6652
  year: 2015
  ident: WOS:000353041200005
  article-title: Dynamic control of chirality in phosphine ligands for enantioselective catalysis
  publication-title: NATURE COMMUNICATIONS
  doi: 10.1038/ncomms7652
– volume: 2012
  start-page: 5919
  year: 2012
  ident: WOS:000309923400006
  article-title: Hydrogen-Bonding Thiourea Organocatalysts: The Privileged 3,5-Bis(trifluoromethyl)phenyl Group
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1002/ejoc.201200739
– start-page: 1987
  year: 1970
  ident: WOS:A1970G211900007
  article-title: THIOCARBONYL YLIDES - AN APPROACH TO TETRAVALENT-SULFUR COMPOUNDS
  publication-title: TETRAHEDRON LETTERS
– volume: 138
  start-page: 1749
  year: 2016
  ident: WOS:000370582900002
  article-title: Asymmetric Catalysis with a Mechanically Point-Chiral Rotaxane
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/jacs.6b00303
– volume: 50
  start-page: 7773
  year: 2014
  ident: WOS:000338296300004
  article-title: Dual stereocontrol over the Henry reaction using a light- and heat-triggered organocatalyst
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c4cc00794h
– volume: 121
  start-page: 2325
  year: 1999
  ident: WOS:000079242800044
  article-title: Photoresponsive molecular switch to control chemical fixation of CO2
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 110
  start-page: 4678
  year: 2006
  ident: WOS:000236773100009
  article-title: Conformational preferences and internal rotation in alkyl- and phenyl-substituted thiourea derivatives
  publication-title: JOURNAL OF PHYSICAL CHEMISTRY A
  doi: 10.1021/jp056906e
– volume: 124
  start-page: 5527
  year: 2012
  ident: 000400580000043.6
  publication-title: Angew. Chem
– volume: 16
  start-page: 13068
  year: 2010
  ident: WOS:000285230000010
  article-title: Enantioselective Synthesis of Coumarins Catalyzed by a Bifunctional Amine-Thiourea Catalyst
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201002202
– volume: 339
  start-page: 189
  year: 2013
  ident: WOS:000313328200040
  article-title: Sequence-Specific Peptide Synthesis by an Artificial Small-Molecule Machine
  publication-title: SCIENCE
  doi: 10.1126/science.1229753
– volume: 3
  start-page: 53
  year: 2011
  ident: WOS:000285336900017
  article-title: Reversing the direction in a light-driven rotary molecular motor
  publication-title: NATURE CHEMISTRY
  doi: 10.1038/NCHEM.872
SSID ssj0009633
Score 2.345667
Snippet The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light‐responsive systems allowing for dynamic...
The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic...
Source Web of Science
SourceID proquest
pubmed
webofscience
crossref
wiley
SourceType Aggregation Database
Index Database
Enrichment Source
Publisher
StartPage 6174
SubjectTerms activity control
Alkenes
Amination
Beta rays
Catalysis
Catalytic activity
Chemistry
Chemistry, Multidisciplinary
Coupling (molecular)
Dynamic control
Functional groups
Irradiation
Isomers
Metastable state
Michael addition
Michael reaction
Molecular machines
Molecular motors
molecular switches
photochemistry
photoswitchable catalysts
Physical Sciences
Science & Technology
Selectivity
Switches
Thiourea
Thioureas
Title Bifunctional Molecular Photoswitches Based on Overcrowded Alkenes for Dynamic Control of Catalytic Activity in Michael Addition Reactions
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201604966
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000400580000043
https://www.ncbi.nlm.nih.gov/pubmed/27880015
https://www.proquest.com/docview/1895084885
https://www.proquest.com/docview/1843916836
Volume 23
WOS 000400580000043
WOSCitedRecordID wos000400580000043
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1ba9VAEB6kL_ri_RKtskLBp7Qnm-wm-3gaLUXwQrHQt7C34KE1EZNDqf_Af-1MNkl7KqLoY9hNwmzm8u1m5huAHZmmGmGtiBe1UHEmjI4L7rNYprR_rTMcHRJk38vD4-ztiTi5UsUf-CHmAzeyjMFfk4Fr0-1dkoaiTFRJnkjEuJI4tylhi1DR0SV_FGpX6CWf5TFxsE6sjQu-t3n7ZlT6BWpei0qbQHaIRAd3QE8yhASU0911b3bt92v0jv8j5F24PcJUtgx6dQ9u-OY-3Cyn7nAP4Mf-ikJiOElk76Ymu-zj57Zvu_MVKUPH9jFGOtY27ANaDIp-7vByeXZKDpYhXGavLxr9ZWVZGTLmWVuzkg6ULvC9bGlDawu2atiY3s-Wzg1JZuzIh5KM7iEcH7z5VB7GY1uH2IpEEv2xk04ZVbgavYXNhUvQyRqrZOFT5ZVQPkcUk3vuqApWasu9ssLi1orYT9P0EWw1beOfADO1R48kfFYjEnLK6yRx1gjtM0ShPDcRxNNnrezIeU6tN86qwNbMK1rgal7gCF7N878Gto_fztyetKQarb6rkoJ66qJLFBG8nIfxw9BPGN34dk1zhlrnIsVHPA7aNb-K5-hNEZ9FsHNV3ebxxeByRRF2dmkEyd9MK0fBieSgj4AP-vYH8Soi5Jivnv7LTc_gFicIRMmhfBu2-m9r_xwBXG9eDEb6E875O8M
linkProvider Wiley-Blackwell
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1Lb9QwEB5V5VAuvB-BAkYq4pR248ROcuCwzVJt6QNUtVJvIbEdsWpJENnVavkH_Bz-Cr-ImThJ2SIEQuqBY2TvZm3P4_PszDcAG9L3M4S1wh0UInYDkWduxE3gSp_ur0WAo02C7KEcnwRvTsXpCnzramEsP0QfcCPNaOw1KTgFpLcuWENxUVRK7kkEuVK2eZV7ZjHHW1v9aneER_yC853Xx8nYbRsLuEp4kgh4tdRxHke6QHlVodAeqnmuYhkZPzaxiE2IfjQ0XFMdpswUN7ESCsE98W9SDBSt_jVqI050_aOjC8YqlGfbvT4IXWJ97XgiB3xr-fcu-8FfwO0lP7gMnRvft3MTvne7ZlNezjZn03xTfblEKPlfbestuNEicTa0qnMbVkx5B9aSrgHeXfi6PSGvb4Ol7KDrI8zefaimVT2fkLzXbBthgGZVyd6iUcC9nmt8HJ6fkQ9heCNgo0WZfZwoltiiAFYVLKGY2QLfy4bKdu9gk5K1FQxsqHWTR8eOjK06qe_ByZXsxH1YLavSPASWFwaNrjBBgWBPxybzPK1ykZkAgTYPcwfcTo5S1dK6U3eR89QSUvOUDjTtD9SBl_38T5bQ5Lcz1zuxTFvDVqdeRG2D0eoLB573w3gw9D9TVppqRnOacu7Ix694YMW5fxUP0WEgBHVg42f57scHjVcRkb28-g54fzMtaRdOPA5TB3gj4H9YXkqcI_3To3_50DNYGx8f7Kf7u4d7j-E6J8RHubB8HVann2fmCeLVaf60sRAM3l-17vwA64qYjg
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1Lb9QwEB5VRQIuvB-BAkYq4pR248ROcuCwzbJqKZSqolJvaWI7YtWSVGxWq-Uf8G_4K_wjZuIkZYsQCKkHjpGdh-15fHZmvgFYl76fIawV7qAQsRuIPHMjbgJX-rR_LQJsbQJk9-T2YfDmSBytwLcuF8byQ_QHbqQZjb0mBT_TxeY5aSiOiTLJPYkYV8o2rHLXLOa4aZu-2hnhCr_gfPz6Q7LttnUFXCU8Sfy7Wuo4jyNdoLiqUGgPtTxXsYyMH5tYxCZENxoarikNU2aKm1gJhdie6DfpCBSN_pVADmIqFjE6OCesQnG2xeuD0CXS144mcsA3l7932Q3-gm0vuMFl5Ny4vvFN-N5Nmo14OdmY1fmG-nKBT_J_mtVbcKPF4WxoFec2rJjyDlxLuvJ3d-Hr1oR8vj0qZe-6KsJs_2NVV9P5hKR9yrYQBGhWlew9mgSc6rnGy-HpCXkQhvsBNlqU2aeJYolNCWBVwRI6MVvge9lQ2dodbFKyNn-BDbVuoujYgbE5J9N7cHgpM3EfVsuqNA-B5YVBkytMUCDU07HJPE-rXGQmQJjNw9wBtxOjVLWk7lRb5DS1dNQ8pQVN-wV14GXf_8zSmfy251onlWlr1qapF1HRYLT5woHnfTMuDP1lykpTzahPk8wd-fiIB1aa-1fxEN0FAlAH1n8W77590PgUEdmtq--A9zfdknbgxOJQO8Ab-f7D8FJiHOmvHv3LTc_g6v5onL7d2dt9DNc5wT0KhOVrsFp_npknCFbr_GljHxgcX7bq_ABuJpc9
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Bifunctional+Molecular+Photoswitches+Based+on+Overcrowded+Alkenes+for+Dynamic+Control+of+Catalytic+Activity+in+Michael+Addition+Reactions&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Pizzolato%2C+Stefano+F.&rft.au=Collins%2C+Beatrice+S.+L.&rft.au=van%E2%80%85Leeuwen%2C+Thomas&rft.au=Feringa%2C+Ben+L.&rft.date=2017-05-02&rft.issn=0947-6539&rft.eissn=1521-3765&rft.volume=23&rft.issue=25&rft.spage=6174&rft.epage=6184&rft_id=info:doi/10.1002%2Fchem.201604966&rft.externalDBID=n%2Fa&rft.externalDocID=10_1002_chem_201604966
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon