Methyl Viologen@β-Zeolite with Absorption/Fluorescence Dual-Mode and Photo/Chemical Synergistic Stimuli-Responsive Chromism

In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the c...

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Published inMolecules (Basel, Switzerland) Vol. 30; no. 13; p. 2872
Main Authors Han, Jingxuan, Li, Shaoning, Li, Huihui, Li, Yu, Qin, Jiaqiao, Wang, Fuxiang, Pan, Qinhe
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 06.07.2025
MDPI
Subjects
absorption/fluorescence dual-mode
Adsorption
Aluminum
Counterfeiting
Electricity
Electron transport
Electrons
Ethanol
Fluorescence
Information storage
methyl viologen
Optical properties
photo/chemical synergistic
Porous materials
Solvents
stimuli-responsive chromism
Zeolites
β-zeolite
China
β-zeolite
absorption/fluorescence dual-mode
stimuli-responsive chromism
methyl viologen
photo/chemical synergistic
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Abstract In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na2SO3). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
AbstractList In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na SO ). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na2SO3). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na2SO3). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na[sub.2]SO[sub.3]). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na2SO3). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed absorption/fluorescence dual-mode and photo/chemical synergistic stimuli-responsive chromism. Owing to the acidic surrounding provided by β-zeolite, the chromism of MV required the synergistic stimuli of UV irradiation and a chemical reductant (such as Na 2 SO 3 ). UV irradiation induced single electron transfer from the chemical reductant to MV@β-zeolite, leading to enhanced absorption at 610 nm together with a daylight color change from pale yellow to blue. Meanwhile, the nanopores of β-zeolite inhibited aggregation-caused quenching of MV, enabling MV to emit cyan fluorescence at 500 nm. After the single electron transfer of the chemical reductant under UV irradiation, the cyan fluorescence of MV@β-zeolite was quenched. Additionally, MV@β-zeolite exhibited a short stimulus response time (250 s) and good color change reversibility. These findings in this work provide valuable insights into the design of multi-mode and synergistic stimuli-responsive viologen-based chromic materials, particularly for applications in secure high-throughput information storage, high-level anti-counterfeiting and multi-target multi-mode sensing.
Audience Academic
Author Li, Yu
Qin, Jiaqiao
Han, Jingxuan
Pan, Qinhe
Li, Huihui
Wang, Fuxiang
Li, Shaoning
AuthorAffiliation 2 School of Physics and Optoelectronic Engineering, Hainan University, Haikou 570228, China; fuxiang.wang@hainanu.edu.cn
1 Key Laboratory of Advanced Materials of Tropical Island Resources of Ministry of Education, School of Chemistry and Chemical Engineering, Hainan University, Haikou 570228, China; 15560867778@163.com (J.H.); 18289247353@163.com (S.L.); liyu12303@163.com (Y.L.); 17880957798@163.com (J.Q.)
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Cites_doi 10.3390/catal13121486
10.1016/j.solmat.2019.110020
10.1016/j.cej.2024.149551
10.1007/s12039-018-1556-7
10.1016/j.inoche.2022.110139
10.1002/adom.202400839
10.1016/j.micromeso.2017.12.023
10.1021/acscatal.3c02270
10.1016/j.dyepig.2023.111510
10.1021/acs.chemmater.2c02251
10.3390/molecules25153434
10.1002/adfm.202305796
10.1016/j.snb.2024.137081
10.1021/acsami.8b01314
10.1039/C5SC00291E
10.1016/j.cattod.2016.08.010
10.1039/C8CP06975A
10.3390/ma14071702
10.1016/j.solmat.2019.04.004
10.1016/j.ccr.2023.215526
10.1007/s10118-022-2885-z
10.1021/jp8111556
10.1002/anie.202421744
10.1039/D4DT02513J
10.1016/j.jechem.2024.02.027
10.1016/j.jallcom.2023.173001
10.1016/j.dyepig.2023.111818
10.1016/j.molstruc.2025.141431
10.1039/C9NA00004F
10.1021/acs.inorgchem.5c00609
10.1126/science.1204452
10.1002/anie.202420156
10.1007/s10934-018-0697-x
10.1021/acsami.3c12012
10.1002/adfm.202508216
10.1016/j.cej.2023.142029
10.1016/j.molstruc.2025.141933
10.1039/D4QI03115F
10.1039/D1TA07201C
10.1016/j.molstruc.2024.138478
10.1038/s41586-024-08206-1
10.1016/j.poly.2019.01.014
10.1021/acs.inorgchem.2c00381
10.1016/j.cej.2025.160650
10.1016/j.micromeso.2021.111452
10.1039/D4TC00977K
10.1021/acsami.4c13447
10.1002/adfm.202410233
10.3390/ma17163980
10.1021/acs.inorgchem.3c02070
10.1016/j.ccr.2024.216064
10.1002/tcr.202100082
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Keywords β-zeolite
absorption/fluorescence dual-mode
stimuli-responsive chromism
methyl viologen
photo/chemical synergistic
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References Wu (ref_17) 2024; 93
Lu (ref_21) 2024; 636
Han (ref_41) 2023; 15
Gao (ref_42) 2024; 976
Wang (ref_23) 2019; 21
Chen (ref_29) 2024; 221
Shi (ref_4) 2023; 41
Yang (ref_9) 2023; 218
Sui (ref_19) 2018; 10
Li (ref_44) 2024; 500
Jin (ref_49) 2025; 12
Li (ref_16) 2025; 64
Liu (ref_48) 2019; 26
Fernandez (ref_33) 2018; 263
Xia (ref_45) 2024; 484
Yu (ref_18) 2024; 53
Somjit (ref_38) 2021; 328
Chen (ref_30) 2025; 426
Yu (ref_14) 2019; 200
Liu (ref_43) 2019; 161
Wang (ref_46) 2022; 61
Chen (ref_36) 2022; 146
ref_28
Zhou (ref_51) 2025; 507
Han (ref_40) 2025; 1334
Sagara (ref_13) 2021; 21
Murugavel (ref_8) 2021; 9
Pande (ref_15) 2019; 197
Zhang (ref_50) 2025; 1329
Gao (ref_52) 2025; 64
Haslam (ref_26) 2019; 1
Xiong (ref_27) 2023; 13
Wu (ref_12) 2015; 6
Freitas (ref_24) 2017; 289
Wang (ref_3) 2024; 12
Li (ref_1) 2024; 518
Wang (ref_39) 2024; 12
Feng (ref_11) 2023; 33
Martusciello (ref_6) 2024; 16
ref_47
Zong (ref_32) 2025; 64
Na (ref_22) 2011; 333
Yang (ref_31) 2024; 34
Krishnan (ref_37) 2018; 130
Mantina (ref_34) 2009; 113
Ma (ref_35) 2024; 1312
ref_2
ref_5
Nie (ref_10) 2022; 34
ref_7
Luo (ref_20) 2023; 62
Zou (ref_25) 2023; 462
References_xml – ident: ref_28
  doi: 10.3390/catal13121486
– volume: 200
  start-page: 110020
  year: 2019
  ident: ref_14
  article-title: Effect of trifluoromethyl substituents in benzyl-based viologen on the electrochromic performance: Optical contrast and stability
  publication-title: Sol. Energy Mater. Sol. Cells
  doi: 10.1016/j.solmat.2019.110020
– volume: 484
  start-page: 149551
  year: 2024
  ident: ref_45
  article-title: Chameleon-inspired supramolecular materials based on cucurbit[7]uril and viologens exhibiting full-color tunable photochromic behavior
  publication-title: Chem. Eng. J.
  doi: 10.1016/j.cej.2024.149551
– volume: 130
  start-page: 141
  year: 2018
  ident: ref_37
  article-title: Self-assembly of tetraphenylethylene-based dendron into blue fluorescent nanoparticles with aggregation induced enhanced emission
  publication-title: J. Chem. Sci.
  doi: 10.1007/s12039-018-1556-7
– volume: 146
  start-page: 110139
  year: 2022
  ident: ref_36
  article-title: The effect of alkoxyl groups on the photoproperties of meta-octasubstituted tetraphenyl porphyrins
  publication-title: Inorg. Chem. Commun.
  doi: 10.1016/j.inoche.2022.110139
– volume: 12
  start-page: 2400839
  year: 2024
  ident: ref_3
  article-title: Cucurbit[7]uril-based self-assembled supramolecular complex with reversible multistimuli-responsive chromic behavior and controllable fluorescence
  publication-title: Adv. Opt. Mater.
  doi: 10.1002/adom.202400839
– volume: 263
  start-page: 201
  year: 2018
  ident: ref_33
  article-title: Tailoring the hierarchical architecture of beta zeolites using base leaching and pore-directing agents
  publication-title: Micropor. Mesopor. Mat.
  doi: 10.1016/j.micromeso.2017.12.023
– volume: 13
  start-page: 12213
  year: 2023
  ident: ref_27
  article-title: Atomic imaging of zeolites and confined single molecules by iDPC-STEM
  publication-title: ACS Catal.
  doi: 10.1021/acscatal.3c02270
– volume: 218
  start-page: 111510
  year: 2023
  ident: ref_9
  article-title: Two novel photochromic compounds based on a thiazolothiazole extended viologen derivative
  publication-title: Dye. Pigment.
  doi: 10.1016/j.dyepig.2023.111510
– volume: 34
  start-page: 8925
  year: 2022
  ident: ref_10
  article-title: Through-space conjugated supramolecular polymer radicals from spatial organization of Cucurbit[8]uril: An efficient approach for electron transfer and smart photochromism materials
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.2c02251
– ident: ref_47
  doi: 10.3390/molecules25153434
– volume: 33
  start-page: 2305796
  year: 2023
  ident: ref_11
  article-title: Light-induced electron transfer toward on/off room temperature phosphorescence in two photochromic coordination polymers
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202305796
– volume: 426
  start-page: 137081
  year: 2025
  ident: ref_30
  article-title: Sensitive monitoring of meat freshness via changes in fluorescence intensity and wavelength based on protonation-regulated intramolecular charge transfer
  publication-title: Sens. Actuators B Chem.
  doi: 10.1016/j.snb.2024.137081
– volume: 10
  start-page: 11056
  year: 2018
  ident: ref_19
  article-title: Differentiable detection of volatile amines with a viologen-derived metal-organic material
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.8b01314
– volume: 6
  start-page: 2922
  year: 2015
  ident: ref_12
  article-title: Methyl viologen-templated zinc gallophosphate zeolitic material with dual photo-/thermochromism and tuneable photovoltaic activity
  publication-title: Chem. Sci.
  doi: 10.1039/C5SC00291E
– volume: 289
  start-page: 70
  year: 2017
  ident: ref_24
  article-title: Generation and characterization of catalytically active sites of heteropolyacids on zeolite Y for liquid-phase esterification
  publication-title: Catal. Today
  doi: 10.1016/j.cattod.2016.08.010
– volume: 21
  start-page: 4015
  year: 2019
  ident: ref_23
  article-title: Insights into the ion-exchange properties of Zn(II)-incorporated MOR zeolites for the capture of multivalent cations
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/C8CP06975A
– ident: ref_7
  doi: 10.3390/ma14071702
– volume: 197
  start-page: 25
  year: 2019
  ident: ref_15
  article-title: Effects of counter ions on electrochromic behaviors of asymmetrically substituted viologens
  publication-title: Sol. Energy Mater. Sol. Cells
  doi: 10.1016/j.solmat.2019.04.004
– volume: 500
  start-page: 215526
  year: 2024
  ident: ref_44
  article-title: Polyoxometalate (POM)-based crystalline hybrid photochromic materials
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2023.215526
– volume: 41
  start-page: 547
  year: 2023
  ident: ref_4
  article-title: Double-layer hydrogels with tunable mechanofluorochromic response for smart display
  publication-title: Chin. J. Polym. Sci.
  doi: 10.1007/s10118-022-2885-z
– volume: 113
  start-page: 5806
  year: 2009
  ident: ref_34
  article-title: Consistent van der Waals radii for the whole main group
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp8111556
– volume: 64
  start-page: e202421744
  year: 2025
  ident: ref_16
  article-title: Photochromic metal-organic frameworks based on host-guest strategy and different viologen derivatives for organic amines sensing and information anticounterfeiting
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.202421744
– volume: 53
  start-page: 17565
  year: 2024
  ident: ref_18
  article-title: A novel viologen-based hybrid crystalline material for photochromic glass films, information storage and anti-counterfeiting
  publication-title: Dalton Trans.
  doi: 10.1039/D4DT02513J
– volume: 93
  start-page: 453
  year: 2024
  ident: ref_17
  article-title: Viologen-based flexible electrochromic devices
  publication-title: J. Energy Chem.
  doi: 10.1016/j.jechem.2024.02.027
– volume: 976
  start-page: 173001
  year: 2024
  ident: ref_42
  article-title: Three Anderson and octamolybdate based compounds modified by an asymmetric viologen: Photo-/thermo-chromic and luminescence properties
  publication-title: J. Alloys Compd.
  doi: 10.1016/j.jallcom.2023.173001
– volume: 221
  start-page: 111818
  year: 2024
  ident: ref_29
  article-title: Multi-emission regulation of trans-4-[4-(N,N-dimethylamino)styryl] pyridine with a mild host-guest strategy based on H-type β-zeolite
  publication-title: Dye. Pigment.
  doi: 10.1016/j.dyepig.2023.111818
– volume: 1329
  start-page: 141431
  year: 2025
  ident: ref_50
  article-title: A one-dimensional viologen-based coordination polymer derived from viologen-carboxylate and sulfate ligands: Crystal structure, photochromism and inkless printing
  publication-title: J. Mol. Struct.
  doi: 10.1016/j.molstruc.2025.141431
– volume: 1
  start-page: 2029
  year: 2019
  ident: ref_26
  article-title: Synthesis of nanostructured catalysts by surfactant-templating of large-pore zeolites
  publication-title: Nanoscale Adv.
  doi: 10.1039/C9NA00004F
– volume: 64
  start-page: 7619
  year: 2025
  ident: ref_52
  article-title: Synergistic photochromism, fluorescence switching, and photomagnetism of three Mn(II) complexes based on a thiazolothiazole extended viologen derivative
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.5c00609
– volume: 333
  start-page: 328
  year: 2011
  ident: ref_22
  article-title: Directing zeolite structures into hierarchically nanoporous architectures
  publication-title: Science
  doi: 10.1126/science.1204452
– volume: 64
  start-page: e202420156
  year: 2025
  ident: ref_32
  article-title: Confinement microenvironment regulation of carbon dots inzeolite for multi-mode time-dependent phosphorescence colorevolution
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.202420156
– volume: 26
  start-page: 1017
  year: 2019
  ident: ref_48
  article-title: Hydrothermal synthesis of beta zeolite from industrial silica sol as silicon source
  publication-title: J. Porous Mater.
  doi: 10.1007/s10934-018-0697-x
– volume: 15
  start-page: 51411
  year: 2023
  ident: ref_41
  article-title: Viologen guest-mediated luminescence emission tuning and photochromic behavior by a series of viologen@Zn-MOF materials
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.3c12012
– ident: ref_2
  doi: 10.1002/adfm.202508216
– volume: 462
  start-page: 142029
  year: 2023
  ident: ref_25
  article-title: Study on the mechanism of acid modified H-Beta zeolite acidic sites on the catalytic pyrolysis of Kraft lignin
  publication-title: Chem. Eng. J.
  doi: 10.1016/j.cej.2023.142029
– volume: 1334
  start-page: 141933
  year: 2025
  ident: ref_40
  article-title: Structure and photochromic properties of two metal-viologen complexes derived from 1-amyl-4,4′-bipyridinium ligand
  publication-title: J. Mol. Struct.
  doi: 10.1016/j.molstruc.2025.141933
– volume: 12
  start-page: 3294
  year: 2025
  ident: ref_49
  article-title: Tuning photochromism and photomagnetism via diverse bimetallic cyanido viologen hybrid materials
  publication-title: Inorg. Chem. Front.
  doi: 10.1039/D4QI03115F
– volume: 9
  start-page: 27215
  year: 2021
  ident: ref_8
  article-title: Viologens: A versatile organic molecule for energy storage applications
  publication-title: J. Mater. Chem. A
  doi: 10.1039/D1TA07201C
– volume: 1312
  start-page: 138478
  year: 2024
  ident: ref_35
  article-title: Recent advances in organic small-molecular dual-state emission probes
  publication-title: J. Mol. Struct.
  doi: 10.1016/j.molstruc.2024.138478
– volume: 636
  start-page: 368
  year: 2024
  ident: ref_21
  article-title: A stable zeolite with atomically ordered and interconnected mesopore channel
  publication-title: Nature
  doi: 10.1038/s41586-024-08206-1
– volume: 161
  start-page: 237
  year: 2019
  ident: ref_43
  article-title: Photochromism of three supramolecular assemblies derived from benzenecarboxylate donors and viologen acceptors
  publication-title: Polyhedron
  doi: 10.1016/j.poly.2019.01.014
– volume: 61
  start-page: 8153
  year: 2022
  ident: ref_46
  article-title: A three-component donor−acceptor hybrid framework with low power X-ray-induced photochromism
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.2c00381
– volume: 507
  start-page: 160650
  year: 2025
  ident: ref_51
  article-title: Photochromic and thermochromic inks based on supramolecular complexes of viologens and cyclodextrin for printable anticounterfeiting applications
  publication-title: Chem. Eng. J.
  doi: 10.1016/j.cej.2025.160650
– volume: 328
  start-page: 111452
  year: 2021
  ident: ref_38
  article-title: Encapsulation of aggregation-caused quenching dye in metal-organic framework as emissive layer of organic light-emitting diodes
  publication-title: Micropor. Mesopor. Mat.
  doi: 10.1016/j.micromeso.2021.111452
– volume: 12
  start-page: 6326
  year: 2024
  ident: ref_39
  article-title: Metal-cyanide hybrid materials exhibiting photochromic and photomagnetic responses based on viologen receptors
  publication-title: J. Mater. Chem. C
  doi: 10.1039/D4TC00977K
– volume: 16
  start-page: 51384
  year: 2024
  ident: ref_6
  article-title: Stretchable distributed bragg reflectors as strain-responsive mechanochromic sensors
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.4c13447
– volume: 34
  start-page: 2410233
  year: 2024
  ident: ref_31
  article-title: Effects of amino compounds and zeolite matrix on the afterglow performance of carbon dots@zeolite composites
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202410233
– ident: ref_5
  doi: 10.3390/ma17163980
– volume: 62
  start-page: 14385
  year: 2023
  ident: ref_20
  article-title: Multi-stimuli-responsive chromic behaviors of an all-in-one viologen-based Cd(II) complex
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.3c02070
– volume: 518
  start-page: 216064
  year: 2024
  ident: ref_1
  article-title: Advances in viologen-based stimulus-responsive crystalline hybrid materials
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2024.216064
– volume: 21
  start-page: 2375
  year: 2021
  ident: ref_13
  article-title: Redox of viologen for powering and coloring
  publication-title: Chem. Rec.
  doi: 10.1002/tcr.202100082
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Snippet In this work, methyl viologen (MV) was adsorbed into the nanopores of Si/Al H-β-zeolite via cation exchange. The resulting MV@β-zeolite possessed...
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SubjectTerms absorption/fluorescence dual-mode
Adsorption
Aluminum
Counterfeiting
Electricity
Electron transport
Electrons
Ethanol
Fluorescence
Information storage
methyl viologen
Optical properties
photo/chemical synergistic
Porous materials
Solvents
stimuli-responsive chromism
Zeolites
β-zeolite
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Title Methyl Viologen@β-Zeolite with Absorption/Fluorescence Dual-Mode and Photo/Chemical Synergistic Stimuli-Responsive Chromism
URI https://www.ncbi.nlm.nih.gov/pubmed/40649386
https://www.proquest.com/docview/3229152549
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https://pubmed.ncbi.nlm.nih.gov/PMC12251173
https://doaj.org/article/883c551653d34c8e957c1f6901549411
Volume 30
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