Investigation of the Co-Dependence of Morphology and Fluorescence Lifetime in a Metal-Organic Framework
Porous materials, due to their large surface‐to‐volume ratio, are important for a broad range of applications and are the subject of intense research. Most studies investigate the bulk properties of these materials, which are not sensitive to the effect of heterogeneities within the sample. Herein,...
Saved in:
Published in | Small (Weinheim an der Bergstrasse, Germany) Vol. 12; no. 27; pp. 3651 - 3657 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Germany
Blackwell Publishing Ltd
01.07.2016
Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Porous materials, due to their large surface‐to‐volume ratio, are important for a broad range of applications and are the subject of intense research. Most studies investigate the bulk properties of these materials, which are not sensitive to the effect of heterogeneities within the sample. Herein, a new strategy based on correlative fluorescence lifetime imaging and scanning electron microscopy is presented that allows the detection and localization of those heterogeneities, and connects them to morphological and structural features of the material. By applying this method to a dye‐modified metal‐organic framework (MOF), two independent fluorescence quenching mechanisms in the MOF scaffold are identified and quantified. The first mechanism is based on quenching via amino groups, while the second mechanism is influenced by morphology. Furthermore, a similar correlation between the inherent luminescence lifetime and the morphology of the unmodified MOF structure is demonstrated.
A novel approach to elucidate the structural, functional, and morphological properties of (in)organic materials using correlative fluorescence lifetime image microscopy and scanning electron microscopy is presented. Using this method, a correlation between the morphology and the fluorescence lifetime in a metal‐organic framework (MOF) is shown. Additionally, two quenching mechanisms of fluorescein in this MOF are identified and quantified. |
---|---|
AbstractList | Porous materials, due to their large surface‐to‐volume ratio, are important for a broad range of applications and are the subject of intense research. Most studies investigate the bulk properties of these materials, which are not sensitive to the effect of heterogeneities within the sample. Herein, a new strategy based on correlative fluorescence lifetime imaging and scanning electron microscopy is presented that allows the detection and localization of those heterogeneities, and connects them to morphological and structural features of the material. By applying this method to a dye‐modified metal‐organic framework (MOF), two independent fluorescence quenching mechanisms in the MOF scaffold are identified and quantified. The first mechanism is based on quenching via amino groups, while the second mechanism is influenced by morphology. Furthermore, a similar correlation between the inherent luminescence lifetime and the morphology of the unmodified MOF structure is demonstrated. Porous materials, due to their large surface‐to‐volume ratio, are important for a broad range of applications and are the subject of intense research. Most studies investigate the bulk properties of these materials, which are not sensitive to the effect of heterogeneities within the sample. Herein, a new strategy based on correlative fluorescence lifetime imaging and scanning electron microscopy is presented that allows the detection and localization of those heterogeneities, and connects them to morphological and structural features of the material. By applying this method to a dye‐modified metal‐organic framework (MOF), two independent fluorescence quenching mechanisms in the MOF scaffold are identified and quantified. The first mechanism is based on quenching via amino groups, while the second mechanism is influenced by morphology. Furthermore, a similar correlation between the inherent luminescence lifetime and the morphology of the unmodified MOF structure is demonstrated. A novel approach to elucidate the structural, functional, and morphological properties of (in)organic materials using correlative fluorescence lifetime image microscopy and scanning electron microscopy is presented. Using this method, a correlation between the morphology and the fluorescence lifetime in a metal‐organic framework (MOF) is shown. Additionally, two quenching mechanisms of fluorescein in this MOF are identified and quantified. Porous materials, due to their large surface-to-volume ratio, are important for a broad range of applications and are the subject of intense research. Most studies investigate the bulk properties of these materials, which are not sensitive to the effect of heterogeneities within the sample. Herein, a new strategy based on correlative fluorescence lifetime imaging and scanning electron microscopy is presented that allows the detection and localization of those heterogeneities, and connects them to morphological and structural features of the material. By applying this method to a dye-modified metal-organic framework (MOF), two independent fluorescence quenching mechanisms in the MOF scaffold are identified and quantified. The first mechanism is based on quenching via amino groups, while the second mechanism is influenced by morphology. Furthermore, a similar correlation between the inherent luminescence lifetime and the morphology of the unmodified MOF structure is demonstrated. A novel approach to elucidate the structural, functional, and morphological properties of (in)organic materials using correlative fluorescence lifetime image microscopy and scanning electron microscopy is presented. Using this method, a correlation between the morphology and the fluorescence lifetime in a metal-organic framework (MOF) is shown. Additionally, two quenching mechanisms of fluorescein in this MOF are identified and quantified. |
Author | Hirschle, Patrick Wuttke, Stefan Lamb, Don C. Schrimpf, Waldemar Ossato, Giulia |
Author_xml | – sequence: 1 givenname: Waldemar surname: Schrimpf fullname: Schrimpf, Waldemar organization: Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 11, 81377, München, Germany – sequence: 2 givenname: Giulia surname: Ossato fullname: Ossato, Giulia organization: Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 11, 81377, München, Germany – sequence: 3 givenname: Patrick surname: Hirschle fullname: Hirschle, Patrick organization: Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 11, 81377, München, Germany – sequence: 4 givenname: Stefan surname: Wuttke fullname: Wuttke, Stefan email: stefan.wuttke@cup.lmu.de organization: Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 11, 81377, München, Germany – sequence: 5 givenname: Don C. surname: Lamb fullname: Lamb, Don C. email: stefan.wuttke@cup.lmu.de organization: Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 11, 81377, München, Germany |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27171620$$D View this record in MEDLINE/PubMed |
BookMark | eNqNkc1v1DAQxS1URD_gyhFF4sIlW3_EdnKELbtUyrZIi8TRcpzJ1m1iL3ZCu_99E7ZdIS7lNKOZ33ua0TtFR847QOg9wTOCMT2PXdvOKCYCY0GKV-iECMJSkdPi6NATfIxOY7zFmBGayTfomEoiiaD4BG0u3W-Ivd3o3nqX-CbpbyCZ-_QCtuBqcAam4cqH7Y1v_WaXaFcni3bwAaL5sy5tA73tILEu0ckKet2m12GjnTXJIugO7n24e4teN7qN8O6pnqH14uuP-be0vF5ezj-XqeEkK1KuC2N4ZkxFKJaSUUN5RivRYGEEgAbZcIKzitdYZ0ZXhgDNWaY5zWvM2Bn6tHfdBv9rGP9SnR2vbFvtwA9RkZxxLossF_-B4hHLmJjQj_-gt34IbnxjopgkLM-LkZrtKRN8jAEatQ2202GnCFZTVmrKSh2yGgUfnmyHqoP6gD-HMwLFHri3LexesFPrVVn-bZ7utTb28HDQ6nCnhGSSq59XS0XX_OLLd0LVkj0CFeiwag |
CitedBy_id | crossref_primary_10_1038_s41467_018_04833_1 crossref_primary_10_1002_adfm_201909062 crossref_primary_10_1021_acs_inorgchem_3c00019 crossref_primary_10_1021_acs_langmuir_7b04240 crossref_primary_10_1038_s41467_019_10185_1 crossref_primary_10_1021_acsanm_2c04301 crossref_primary_10_1039_C7DT04116K crossref_primary_10_1021_acs_cgd_2c00073 crossref_primary_10_1021_jacs_3c12275 crossref_primary_10_1016_j_ajps_2022_06_001 crossref_primary_10_1039_D3CP00295K crossref_primary_10_1088_1361_648X_ab38da crossref_primary_10_1002_chem_201900406 crossref_primary_10_1039_D1TC02634H crossref_primary_10_1016_j_jssc_2022_122915 crossref_primary_10_1002_chem_202103104 crossref_primary_10_1016_j_optmat_2024_115227 crossref_primary_10_1038_s41598_017_13081_0 crossref_primary_10_1038_s41467_018_04050_w crossref_primary_10_1021_acsmaterialslett_1c00754 crossref_primary_10_1089_ten_tec_2021_0178 crossref_primary_10_1021_jacs_1c04804 |
Cites_doi | 10.1002/anie.200900339 10.1002/anie.201106651 10.1039/B618320B 10.1002/anie.201205627 10.1039/C4CC02650K 10.1021/cr200324t 10.2116/analsci.31.275 10.1016/j.bpj.2013.05.059 10.1039/C4CS90059F 10.1021/cm502920f 10.1529/biophysj.107.120154 10.1002/chem.201203491 10.1126/science.1230444 10.1007/BF00866388 10.1002/chem.201406157 10.1021/cs400959k 10.1039/C39860001709 10.1021/cr300014x 10.1039/c2jm16030g 10.1038/srep05418 10.1021/ja503218j 10.1002/anie.201410252 10.1038/ncomms1714 10.1021/cr200179u 10.1038/srep02562 10.1111/j.1365-2818.2004.01265.x 10.1021/cm103644b 10.1002/anie.201311128 10.1016/j.micromeso.2012.06.044 10.1088/0967-3334/26/4/N01 10.1007/s10895-005-2990-8 |
ContentType | Journal Article |
Copyright | 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copyright © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
Copyright_xml | – notice: 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. – notice: Copyright © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DBID | BSCLL NPM AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M 7X8 F28 FR3 |
DOI | 10.1002/smll.201600619 |
DatabaseName | Istex PubMed CrossRef Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace MEDLINE - Academic ANTE: Abstracts in New Technology & Engineering Engineering Research Database |
DatabaseTitle | PubMed CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX MEDLINE - Academic Engineering Research Database ANTE: Abstracts in New Technology & Engineering |
DatabaseTitleList | CrossRef MEDLINE - Academic Materials Research Database Materials Research Database PubMed |
Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering |
EISSN | 1613-6829 |
EndPage | 3657 |
ExternalDocumentID | 4116695421 10_1002_smll_201600619 27171620 SMLL201600619 ark_67375_WNG_2S5DBP12_G |
Genre | article Journal Article |
GrantInformation_xml | – fundername: Excellence Cluster Nanosystems Initiative Munich – fundername: Center for NanoScience Munich – fundername: Deutsche Forschungsgemeinschaft funderid: SFB1032 |
GroupedDBID | --- 05W 0R~ 123 1L6 1OC 31~ 33P 3SF 3WU 4.4 50Y 52U 53G 5VS 66C 8-0 8-1 8UM A00 AAESR AAEVG AAHHS AAIHA AANLZ AAONW AASGY AAXRX AAYOK AAZKR ABCUV ABHUG ABIJN ABJNI ABLJU ABRTZ ABWRO ACAHQ ACBWZ ACCFJ ACCZN ACFBH ACGFS ACIWK ACPOU ACXBN ACXME ACXQS ADAWD ADBBV ADDAD ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEIGN AEIMD AENEX AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFVGU AFZJQ AGJLS AHBTC AIURR AIWBW AJBDE AJXKR ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ASPBG ATUGU AUFTA AVWKF AZFZN AZVAB BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BOGZA BRXPI BSCLL CS3 DCZOG DPXWK DR2 DRFUL DRSTM DU5 EBD EBS EJD EMOBN F5P FEDTE G-S GNP GODZA HBH HHY HHZ HVGLF HZ~ IX1 KQQ LATKE LAW LEEKS LITHE LOXES LUTES LYRES MEWTI MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM MY~ O66 O9- P2P P2W P4E QRW R.K RIWAO RNS ROL RWI RX1 RYL SUPJJ SV3 V2E W99 WBKPD WFSAM WIH WIK WJL WOHZO WXSBR WYISQ WYJ XV2 Y6R ZZTAW ~S- AITYG HGLYW OIG NPM AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M 7X8 F28 FR3 |
ID | FETCH-LOGICAL-c5149-5a9cc54ccb1207732c2542b6f06c6eeae7f5104b5d0a4cabc1e2834a528d033 |
IEDL.DBID | DR2 |
ISSN | 1613-6810 |
IngestDate | Fri Aug 16 05:24:53 EDT 2024 Sat Aug 17 01:33:40 EDT 2024 Thu Oct 10 17:39:30 EDT 2024 Fri Aug 23 01:08:44 EDT 2024 Sat Sep 28 08:06:25 EDT 2024 Sat Aug 24 00:53:32 EDT 2024 Wed Jan 17 05:02:27 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 27 |
Keywords | phasors correlative microscopy electron microscopy fluorescence lifetime imaging metal-organic frameworks |
Language | English |
License | 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c5149-5a9cc54ccb1207732c2542b6f06c6eeae7f5104b5d0a4cabc1e2834a528d033 |
Notes | istex:492AEB630A14E68DF49139D603BA5A865DEEA24E Deutsche Forschungsgemeinschaft - No. SFB1032 Excellence Cluster Nanosystems Initiative Munich ArticleID:SMLL201600619 Center for NanoScience Munich ark:/67375/WNG-2S5DBP12-G ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
PMID | 27171620 |
PQID | 1803713889 |
PQPubID | 1046358 |
PageCount | 7 |
ParticipantIDs | proquest_miscellaneous_1835579486 proquest_miscellaneous_1804864366 proquest_journals_1803713889 crossref_primary_10_1002_smll_201600619 pubmed_primary_27171620 wiley_primary_10_1002_smll_201600619_SMLL201600619 istex_primary_ark_67375_WNG_2S5DBP12_G |
PublicationCentury | 2000 |
PublicationDate | 2016-Jul |
PublicationDateYYYYMMDD | 2016-07-01 |
PublicationDate_xml | – month: 07 year: 2016 text: 2016-Jul |
PublicationDecade | 2010 |
PublicationPlace | Germany |
PublicationPlace_xml | – name: Germany – name: Weinheim |
PublicationTitle | Small (Weinheim an der Bergstrasse, Germany) |
PublicationTitleAlternate | Small |
PublicationYear | 2016 |
Publisher | Blackwell Publishing Ltd Wiley Subscription Services, Inc |
Publisher_xml | – name: Blackwell Publishing Ltd – name: Wiley Subscription Services, Inc |
References | G. I. Redford, R. M. Clegg, J. Fluoresc. 2005, 15, 805. L. E. Kreno, K. Leong, O. K. Farha, M. Allendorf, R. P. Van Duyne, J. T. Hupp, Chem. Rev. 2012, 112, 1105. H. Hintz, S. Wuttke, Chem. Mater. 2014, 26, 6722. B. M. Weckhuysen, Angew. Chem. Int. Ed. 2009, 48, 4910. J. R. Lakowicz, H. Szmacinski, M. L. Johnson, J. Fluoresc. 1992, 2, 47. H. Hintz, S. Wuttke, Chem. Commun. 2014, 50, 11472. P. Serra-Crespo, E. V. Ramos-Fernandez, J. Gascon, F. Kapteijn, Chem. Mater. 2011, 23, 2565. J. Hendrix, W. Schrimpf, M. Höller, D. C. Lamb, Biophys. J. 2013, 105, 848. M. A. Karreman, I. L. Buurmans, J. W. Geus, A. V. Agronskaia, J. Ruiz-Martinez, H. C. Gerritsen, B. M. Weckhuysen, Angew. Chem. Int. Ed. 2012, 51, 1428. T. Nakabayashi, N. Ohta, Anal. Sci. 2015, 31, 275. S. M. Cohen, Chem. Rev. 2012, 112, 970. F. M. Hinterholzinger, B. Rühle, S. Wuttke, K. Karaghiosoff, T. Bein, Sci. Rep. 2013, 3, 2562. Z. Fang, J. P. Dürholt, M. Kauer, W. Zhang, C. Lochenie, B. Jee, B. Albada, N. Metzler-Nolte, A. Pöppl, B. Weber, M. Muhler, Y. Wang, R. Schmid, R. A. Fischer, J. Am. Chem. Soc. 2014, 136, 9627. T. Liu, X. Liu, D. R. Spring, X. Qian, J. Cui, Z. Xu, Sci. Rep. 2014, 4, DOI 10.1038/srep05418. R. Ameloot, F. Vermoortele, J. Hofkens, F. C. De Schryver, D. E. De Vos, M. B. J. Roeffaers, Angew. Chem. Int. Ed. 2013, 52, 401. J. Gascon, A. Corma, F. Kapteijn, F. X. Llabrés i. Xamena, ACS Catal. 2014, 4, 361. C. Dietl, H. Hintz, B. Rühle, J. Schmedt auf der Günne, H. Langhals, S. Wuttke, Chem. Eur. J. 2015, 21, 10714. H. Furukawa, K. E. Cordova, M. O'Keeffe, O. M. Yaghi, Science 2013, 341, 1230444. M. Hammer, D. Schweitzer, S. Richter, E. Königsdörffer, Physiol. Meas. 2005, 26, N9. A. H. A. Clayton, Q. S. Hanley, P. J. Verveer, J. Microsc. 2004, 213, 1. F. Vermoortele, R. Ameloot, L. Alaerts, R. Matthessen, B. Carlier, E. V. R. Fernandez, J. Gascon, F. Kapteijn, D. E. De Vos, J. Mater. Chem. 2012, 22, 10313. A. P. de Silva, S. A. de Silva, J. Chem. Soc., Chem. Commun. 1986, 23, 1709. K. Okabe, N. Inada, C. Gota, Y. Harada, T. Funatsu, S. Uchiyama, Nat. Commun. 2012, 3, 705. H.-C. Zhou, S. Kitagawa, Chem. Soc. Rev. 2014, 43, 5403. H. Furukawa, U. Müller, O. M. Yaghi, Angew. Chem. Int. Ed. 2015, 54, 3417. M. A. Karreman, I. L. Buurmans, A. V. Agronskaia, J. W. Geus, H. C. Gerritsen, B. M. Weckhuysen, Chem. Eur. J. 2013, 19, 3846. O. Kozachuk, I. Luz, F. X. Llabrés i Xamena, H. Noei, M. Kauer, H. B. Albada, E. D. Bloch, B. Marler, Y. Wang, M. Muhler, R. A. Fischer, Angew. Chem. Int. Ed. 2014, 53, 7058. G. Férey, Chem. Soc. Rev. 2008, 37, 191. H.-C. Zhou, J. R. Long, O. M. Yaghi, Chem. Rev. 2012, 112, 673. M. Hartmann, M. Fischer, Microporous Mesoporous Mater. 2012, 164, 38. M. A. Digman, V. R. Caiolfa, M. Zamai, E. Gratton, Biophys. J. 2008, 94, L14. 2012; 164 2013; 3 2015; 31 2013; 105 2015; 54 2008; 37 2014; 26 2013; 341 2008; 94 2005; 26 2014; 136 2009; 48 2014; 43 2012; 51 2013; 19 2014; 4 2012; 3 2012; 112 2004; 213 1986; 23 2013; 52 2015; 21 2011; 23 2005; 15 2014; 50 2012; 22 1992; 2 2014; 53 e_1_2_6_10_1 e_1_2_6_31_1 e_1_2_6_30_1 e_1_2_6_19_1 e_1_2_6_13_1 e_1_2_6_14_1 e_1_2_6_11_1 e_1_2_6_12_1 e_1_2_6_17_1 e_1_2_6_18_1 e_1_2_6_15_1 e_1_2_6_16_1 e_1_2_6_21_1 e_1_2_6_20_1 e_1_2_6_9_1 e_1_2_6_8_1 e_1_2_6_5_1 e_1_2_6_4_1 e_1_2_6_7_1 e_1_2_6_6_1 e_1_2_6_1_1 e_1_2_6_25_1 e_1_2_6_24_1 e_1_2_6_3_1 e_1_2_6_23_1 e_1_2_6_2_1 e_1_2_6_22_1 e_1_2_6_29_1 e_1_2_6_28_1 e_1_2_6_27_1 e_1_2_6_26_1 |
References_xml | – volume: 23 start-page: 2565 year: 2011 publication-title: Chem. Mater. – volume: 53 start-page: 7058 year: 2014 publication-title: Angew. Chem. Int. Ed. – volume: 2 start-page: 47 year: 1992 publication-title: J. Fluoresc. – volume: 21 start-page: 10714 year: 2015 publication-title: Chem. Eur. J. – volume: 105 start-page: 848 year: 2013 publication-title: Biophys. J. – volume: 37 start-page: 191 year: 2008 publication-title: Chem. Soc. Rev. – volume: 15 start-page: 805 year: 2005 publication-title: J. Fluoresc. – volume: 52 start-page: 401 year: 2013 publication-title: Angew. Chem. Int. Ed. – volume: 50 start-page: 11472 year: 2014 publication-title: Chem. Commun. – volume: 31 start-page: 275 year: 2015 publication-title: Anal. Sci. – volume: 3 start-page: 2562 year: 2013 publication-title: Sci. Rep. – volume: 341 start-page: 1230444 year: 2013 publication-title: Science – volume: 112 start-page: 673 year: 2012 publication-title: Chem. Rev. – volume: 26 start-page: N9 year: 2005 publication-title: Physiol. Meas. – volume: 213 start-page: 1 year: 2004 publication-title: J. Microsc. – volume: 94 start-page: L14 year: 2008 publication-title: Biophys. J. – volume: 4 start-page: 361 year: 2014 publication-title: ACS Catal. – volume: 23 start-page: 1709 year: 1986 publication-title: J. Chem. Soc., Chem. Commun. – volume: 43 start-page: 5403 year: 2014 publication-title: Chem. Soc. Rev. – volume: 3 start-page: 705 year: 2012 publication-title: Nat. Commun. – volume: 19 start-page: 3846 year: 2013 publication-title: Chem. Eur. J. – volume: 4 year: 2014 publication-title: Sci. Rep. – volume: 136 start-page: 9627 year: 2014 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 4910 year: 2009 publication-title: Angew. Chem. Int. Ed. – volume: 164 start-page: 38 year: 2012 publication-title: Microporous Mesoporous Mater. – volume: 22 start-page: 10313 year: 2012 publication-title: J. Mater. Chem. – volume: 112 start-page: 970 year: 2012 publication-title: Chem. Rev. – volume: 26 start-page: 6722 year: 2014 publication-title: Chem. Mater. – volume: 54 start-page: 3417 year: 2015 publication-title: Angew. Chem. Int. Ed. – volume: 112 start-page: 1105 year: 2012 publication-title: Chem. Rev. – volume: 51 start-page: 1428 year: 2012 publication-title: Angew. Chem. Int. Ed. – ident: e_1_2_6_5_1 doi: 10.1002/anie.200900339 – ident: e_1_2_6_12_1 doi: 10.1002/anie.201106651 – ident: e_1_2_6_3_1 doi: 10.1039/B618320B – ident: e_1_2_6_8_1 doi: 10.1002/anie.201205627 – ident: e_1_2_6_25_1 doi: 10.1039/C4CC02650K – ident: e_1_2_6_27_1 doi: 10.1021/cr200324t – ident: e_1_2_6_14_1 doi: 10.2116/analsci.31.275 – ident: e_1_2_6_31_1 doi: 10.1016/j.bpj.2013.05.059 – ident: e_1_2_6_2_1 doi: 10.1039/C4CS90059F – ident: e_1_2_6_26_1 doi: 10.1021/cm502920f – ident: e_1_2_6_21_1 doi: 10.1529/biophysj.107.120154 – ident: e_1_2_6_13_1 doi: 10.1002/chem.201203491 – ident: e_1_2_6_4_1 doi: 10.1126/science.1230444 – ident: e_1_2_6_15_1 doi: 10.1007/BF00866388 – ident: e_1_2_6_29_1 doi: 10.1002/chem.201406157 – ident: e_1_2_6_10_1 doi: 10.1021/cs400959k – ident: e_1_2_6_16_1 doi: 10.1039/C39860001709 – ident: e_1_2_6_1_1 doi: 10.1021/cr300014x – ident: e_1_2_6_9_1 doi: 10.1039/c2jm16030g – ident: e_1_2_6_18_1 doi: 10.1038/srep05418 – ident: e_1_2_6_7_1 doi: 10.1021/ja503218j – ident: e_1_2_6_11_1 doi: 10.1002/anie.201410252 – ident: e_1_2_6_17_1 doi: 10.1038/ncomms1714 – ident: e_1_2_6_24_1 doi: 10.1021/cr200179u – ident: e_1_2_6_28_1 doi: 10.1038/srep02562 – ident: e_1_2_6_19_1 doi: 10.1111/j.1365-2818.2004.01265.x – ident: e_1_2_6_23_1 doi: 10.1021/cm103644b – ident: e_1_2_6_6_1 doi: 10.1002/anie.201311128 – ident: e_1_2_6_22_1 doi: 10.1016/j.micromeso.2012.06.044 – ident: e_1_2_6_30_1 doi: 10.1088/0967-3334/26/4/N01 – ident: e_1_2_6_20_1 doi: 10.1007/s10895-005-2990-8 |
SSID | ssj0031247 |
Score | 2.365227 |
Snippet | Porous materials, due to their large surface‐to‐volume ratio, are important for a broad range of applications and are the subject of intense research. Most... Porous materials, due to their large surface-to-volume ratio, are important for a broad range of applications and are the subject of intense research. Most... |
SourceID | proquest crossref pubmed wiley istex |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 3651 |
SubjectTerms | Correlation correlative microscopy Dependence electron microscopy Fluorescence fluorescence lifetime imaging Heterogeneity Metal-organic frameworks Morphology Nanotechnology phasors Porous materials Quenching Scanning electron microscopy Service life assessment |
Title | Investigation of the Co-Dependence of Morphology and Fluorescence Lifetime in a Metal-Organic Framework |
URI | https://api.istex.fr/ark:/67375/WNG-2S5DBP12-G/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fsmll.201600619 https://www.ncbi.nlm.nih.gov/pubmed/27171620 https://www.proquest.com/docview/1803713889 https://search.proquest.com/docview/1804864366 https://search.proquest.com/docview/1835579486 |
Volume | 12 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT9wwELYQvdBDH_S1lCJXqugpkDi2kxxbYEHVLqrYVuVm-RUJLU2qfUioJ34Cv5FfwoyzSXerqkjtLYnHke3xeD4_5jMh71JnC6RJjwrp04iX3ka5T1wkYRqWpM4zyzFQeHgqT77yT-fifCmKv-GH6Bbc0DLCeI0Grs10_xdp6PT7JW4dJBK9MEbwIZseoqKzjj8qBecVblcBnxUh8VbL2hiz_dXsK17pATbw1Z8g5yqCDS6o_5jotvDNyZPx3nxm9uzP33gd_6d2T8ijBT6lH5oO9ZSs-WqTPFxiLXxGxkvcHHVF65ICiKQH9e31zeHiSl3r8fOwBiWGZXuqK0f7l_N6EtijIHlwUXq8155eVFTToYc5AORvIkMt7bdHxp6TUf_oy8FJtLizIbIAvYpI6MJawa01CYuzLGUWZqDMyDKWVnqvfVbCKMCNcLHmVhubeAA4XAuWuzhNX5D1qq78K0KFdpK7zLm8MNxDDgn_NQXnOo5dUYgeed9qTP1oiDlUQ8HMFDae6hqvR3aDQjsxPRnjcbZMqG-nx4qNxOHHzwlTxz2y3WpcLSx5qpIcSQ3TPIf_vO2SwQZxY0VXvp4HGZ4DtJPybzKA7GDwy0HmZdObugKxDEmLWNwjLPSJeyqkRsPBoHvb-pdMr8kGPjfnjrfJ-mwy928AXc3MTrCgO0UoHZM |
link.rule.ids | 315,786,790,1382,27955,27956,46327,46751 |
linkProvider | Wiley-Blackwell |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwELagPQAH3tAtBYyE4JQ2cWwnOUKX7QLJCrFFcLP8ilRtm6DtrlRx4if0N_aXMJNsQhchkOAYx2P5NZ7P9vgbQp7HzmZIkx5k0scBL70NUh-5QMI2LIqdZ5bjQ-FiIsef-LsvovMmxLcwLT9Ef-CGmtGs16jgeCC995M19PTkGO8OIolmOLtKNkHnBerm8GPPIBWD-Wriq4DVCpB6q-NtDNneuvyaXdrELj77Hehcx7CNERrdIqarfut7MttdLsyu_fYLs-N_te82ubmCqPRVO6fukCu-uktuXCIuvEdml-g56orWJQUcSffri-_nw1VUXesxuahhHJuTe6orR0fHy3reEEjB7_yo9Bjanh5VVNPCwzYA5NvHoZaOOq-x-2Q6enO4Pw5WYRsCC-grC4TOrBXcWhOxMEliZmETyowsQ2ml99onJSwE3AgXam61sZEHjMO1YKkL4_gB2ajqym8RKrST3CXOpZnhHiQklGsyznUYuiwTA_KyGzL1teXmUC0LM1PYearvvAF50Yxon03PZ-jRlgj1eXKg2FQMX3-ImDoYkJ1uyNVKmU9VlCKvYZymUM6z_jeoId6t6MrXyyYPTwHdSfmnPADuYP1LIc_Ddjr1FWIJ8haxcEBYMyn-0iA1LfK8_9r-F6Gn5Nr4sMhV_nby_hG5jumtG_IO2VjMl_4xgK2FedKo0w8cxyGz |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwEB5BKyE48H4sFDASglPaxK8kR-iSFthdVSyI3izHdqRqS1JtdyXEiZ_Ab-SXMHY2YRchkOAYZ2zZHo_n8-sbgKfMmtzTpEe5dCzilTNR5hIbSVyGJcw6arh_KDyeyMMP_M2xOF57xd_yQ_Qbbt4ywnztDfzMVns_SUPPP536o4NEei-cX4RtLhn1y6_hu55AiqH3CuFV0GlFnnmro22M6d5m_g23tO17-PPvMOcmhA0-qLgGuqt9e_VktrtclLvmyy_Ejv_TvOtwdQVQyYt2RN2AC66-CVfWaAtvwWyNnKOpSVMRRJFkv_n-9dtwFVPXOJ88blCLYd-e6NqS4nTZzAN9FP4enVTOB7YnJzXRZOxwEYD526ehhhTdnbHbMC1evd8_jFZBGyKD2CuPhM6NEdyYMqFxmjJqcAlKS1nF0kjntEsrnAZ4KWysudGlSRwiHK4FzWzM2B3Yqpva3QMitJXcptZmeckd5pBYbplzruPY5rkYwPNOY-qsZeZQLQczVb7zVN95A3gWFNqL6fnM32dLhfo4OVB0KoYvjxKqDgaw02lcrUz5XCWZZzVkWYblPOl_oxH6kxVdu2YZZHiG2E7KP8kgtMPZL0OZu-1o6itEU89aROMB0DAm_tIgNR2PRv3X_X_J9BguHQ0LNXo9efsALvvk9g7yDmwt5kv3EJHWonwUjOkHnE8gYg |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Investigation+of+the+Co%E2%80%90Dependence+of+Morphology+and+Fluorescence+Lifetime+in+a+Metal%E2%80%90Organic+Framework&rft.jtitle=Small+%28Weinheim+an+der+Bergstrasse%2C+Germany%29&rft.au=Schrimpf%2C+Waldemar&rft.au=Ossato%2C+Giulia&rft.au=Hirschle%2C+Patrick&rft.au=Wuttke%2C+Stefan&rft.date=2016-07-01&rft.issn=1613-6810&rft.eissn=1613-6829&rft.volume=12&rft.issue=27&rft.spage=3651&rft.epage=3657&rft_id=info:doi/10.1002%2Fsmll.201600619&rft.externalDBID=10.1002%252Fsmll.201600619&rft.externalDocID=SMLL201600619 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1613-6810&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1613-6810&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1613-6810&client=summon |