Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach
Power conversion efficiencies in excess of 7 % have been achieved with bulk heterojunction (BHJ)‐type organic solar cells using two components: p‐ and n‐doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful desig...
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| Published in | ChemSusChem Vol. 6; no. 1; pp. 20 - 35 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
01.01.2013
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
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| Abstract | Power conversion efficiencies in excess of 7 % have been achieved with bulk heterojunction (BHJ)‐type organic solar cells using two components: p‐ and n‐doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy‐level offset, balanced electron and hole mobility, and good light‐harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullerene I/functional fullerene II, and polymer/quantum dot or metal/functional fullerene systems.
All good things come in threes: Addition of a third component in bulk heterojunction solar cells (sensitizer or fullerene derivative) may increase the short‐circuit current through enhanced light harvesting and/or can increase the open‐circuit voltage through enhanced carrier mobility and modification of HOMO/LUMO energy levels. Such ternary organic solar cell systems will be reviewed in this article. |
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| AbstractList | Power conversion efficiencies in excess of 7% have been achieved with bulk heterojunction (BHJ)-type organic solar cells using two components: p- and n-doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy-level offset, balanced electron and hole mobility, and good light-harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullerene I/functional fullerene II, and polymer/quantum dot or metal/functional fullerene systems.Power conversion efficiencies in excess of 7% have been achieved with bulk heterojunction (BHJ)-type organic solar cells using two components: p- and n-doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy-level offset, balanced electron and hole mobility, and good light-harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullerene I/functional fullerene II, and polymer/quantum dot or metal/functional fullerene systems. Power conversion efficiencies in excess of 7 % have been achieved with bulk heterojunction (BHJ)‐type organic solar cells using two components: p‐ and n‐doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy‐level offset, balanced electron and hole mobility, and good light‐harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullerene I/functional fullerene II, and polymer/quantum dot or metal/functional fullerene systems. All good things come in threes: Addition of a third component in bulk heterojunction solar cells (sensitizer or fullerene derivative) may increase the short‐circuit current through enhanced light harvesting and/or can increase the open‐circuit voltage through enhanced carrier mobility and modification of HOMO/LUMO energy levels. Such ternary organic solar cell systems will be reviewed in this article. Power conversion efficiencies in excess of 7 % have been achieved with bulk heterojunction (BHJ)‐type organic solar cells using two components: p‐ and n‐doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy‐level offset, balanced electron and hole mobility, and good light‐harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullerene I/functional fullerene II, and polymer/quantum dot or metal/functional fullerene systems. Power conversion efficiencies in excess of 7% have been achieved with bulk heterojunction (BHJ)-type organic solar cells using two components: p- and n-doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional component is required to achieve optimal panchromatic absorption, suitable energy-level offset, balanced electron and hole mobility, and good light-harvesting efficiency. This article reviews the recent progress on ternary organic photovoltaic systems, including polymer/small molecule/functional fullerene, polymer/polymer/functional fullerene, small molecule/small molecule/functional fullerene, polymer/functional fullereneI/functional fullereneII, and polymer/quantum dot or metal/functional fullerene systems. [PUBLICATION ABSTRACT] |
| Author | Lin, Ryan Yeh-Yung Ho, Kuo-Chuan Chen, Yung-Chung Hsu, Chih-Yu Lin, Jiann T. |
| Author_xml | – sequence: 1 givenname: Yung-Chung surname: Chen fullname: Chen, Yung-Chung organization: Institute of Chemistry, Academia Sinica, 128 Academia Road Sec. 2, Nankang Taipei, 115 Taiwan (ROC), Fax: (+886) 2-27831237 – sequence: 2 givenname: Chih-Yu surname: Hsu fullname: Hsu, Chih-Yu organization: Institute of Chemistry, Academia Sinica, 128 Academia Road Sec. 2, Nankang Taipei, 115 Taiwan (ROC), Fax: (+886) 2-27831237 – sequence: 3 givenname: Ryan Yeh-Yung surname: Lin fullname: Lin, Ryan Yeh-Yung organization: Institute of Chemistry, Academia Sinica, 128 Academia Road Sec. 2, Nankang Taipei, 115 Taiwan (ROC), Fax: (+886) 2-27831237 – sequence: 4 givenname: Kuo-Chuan surname: Ho fullname: Ho, Kuo-Chuan organization: Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, 106 Taiwan (ROC) – sequence: 5 givenname: Jiann T. surname: Lin fullname: Lin, Jiann T. email: jtlin@gate.sinica.edu.tw organization: Institute of Chemistry, Academia Sinica, 128 Academia Road Sec. 2, Nankang Taipei, 115 Taiwan (ROC), Fax: (+886) 2-27831237 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23288712$$D View this record in MEDLINE/PubMed |
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| Snippet | Power conversion efficiencies in excess of 7 % have been achieved with bulk heterojunction (BHJ)‐type organic solar cells using two components: p‐ and n‐doped... Power conversion efficiencies in excess of 7% have been achieved with bulk heterojunction (BHJ)-type organic solar cells using two components: p- and n-doped... |
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| SubjectTerms | absorption carrier mobility charge transfer Electric Power Supplies energy level Equipment Design Fullerenes - chemistry Metals - chemistry Photovoltaic cells Polymers - chemistry Quantum Dots solar cells Solar Energy |
| Title | Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach |
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