4-(N,N-Dimethylamino)pyridine-Embedded Nanoporous Conjugated Polymer as a Highly Active Heterogeneous Organocatalyst

• Published in: Chemistry : a European journal Vol. 18; no. 20; pp. 6328 - 6334
• Main Authors: Zhang, Yuan, Zhang, Yong, Sun, Ya Lei, Du, Xin, Shi, Jiao Yi, Wang, Wei David, Wang, Wei
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 14.05.2012; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: 4-Aminopyridine - analogs & derivatives; 4-Aminopyridine - chemical synthesis; 4-Aminopyridine - chemistry; acylation; Catalysis; Chemistry; heterogeneous catalysis; Molecular Structure; nanoporous structures; Nanostructures - chemistry; organocatalysis; Polymers; Polymers - chemistry; Porosity; Proteins; Rigidity

We report herein for the first time the incorporation of a versatile organocatalyst, 4‐(N,N‐dimethylamino)pyridine (DMAP), into the network of a nanoporous conjugated polymer (NCP) by the “bottom‐up” approach. The resulting DMAP‐NCP material possesses highly concentrated and homogeneously distribute...