Semiconductive Nanotube Array Constructed from Giant [PbII18I54(I2)9] Wheel Clusters
Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster, as determined by synchrotron X‐ray diffra...
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| Published in | Angewandte Chemie International Edition Vol. 55; no. 2; pp. 514 - 518 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
11.01.2016
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster, as determined by synchrotron X‐ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity.
Lead the way to the tube: The first example of a metal‐halide‐based crystalline nanotube array is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster (see picture, Pb green, I pink). It has typical semiconductive properties and highly anisotropic conductivity. |
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| AbstractList | Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster, as determined by synchrotron X-ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity. Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [Pb(II)18I54(I2)9] wheel cluster, as determined by synchrotron X-ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity. Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster, as determined by synchrotron X‐ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity. Lead the way to the tube: The first example of a metal‐halide‐based crystalline nanotube array is constructed from an unprecedented giant [PbII18I54(I2)9] wheel cluster (see picture, Pb green, I pink). It has typical semiconductive properties and highly anisotropic conductivity. Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [Pb II 18 I 54 (I 2 ) 9 ] wheel cluster, as determined by synchrotron X‐ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity. |
| Author | Yao, Ming-Shui Wang, Ming-Sheng Guo, Guo-Cong Liu, Bin-Wen Wang, Guan-E Xu, Gang |
| Author_xml | – sequence: 1 givenname: Guan-E surname: Wang fullname: Wang, Guan-E organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China) – sequence: 2 givenname: Gang surname: Xu fullname: Xu, Gang email: gxu@fjirsm.ac.cn organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China) – sequence: 3 givenname: Bin-Wen surname: Liu fullname: Liu, Bin-Wen organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China) – sequence: 4 givenname: Ming-Sheng surname: Wang fullname: Wang, Ming-Sheng organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China) – sequence: 5 givenname: Ming-Shui surname: Yao fullname: Yao, Ming-Shui – sequence: 6 givenname: Guo-Cong surname: Guo fullname: Guo, Guo-Cong email: gcguo@fjirsm.ac.cn organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26549327$$D View this record in MEDLINE/PubMed |
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| Keywords | nanotube arrays wheel clusters inorganic-organic hybrid composites semiconductors lead |
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| Snippet | Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based... |
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| SubjectTerms | Anisotropy Clusters Crystal structure Diffraction Electrical properties Electrical resistivity inorganic-organic hybrid composites lead Nanostructure nanotube arrays Semiconductivity semiconductors wheel clusters X-ray diffraction X-rays |
| Title | Semiconductive Nanotube Array Constructed from Giant [PbII18I54(I2)9] Wheel Clusters |
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