An Effective Resistive-Type Alcohol Vapor Sensor Using One-Step Facile Nanoporous Anodic Alumina

• Published in: Micromachines (Basel) Vol. 14; no. 7; p. 1330
• Main Authors: Chung, Chen-Kuei, Ku, Chin-An
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 29.06.2023; MDPI
• Subjects: AAO; Acids; Alcohol; alcohol vapor; Alcohols; Aluminum alloys; Aluminum oxide; anodization; Boron nitride; Breath tests; Contact angle; Drinking; Drinking of alcoholic beverages; Driving; Drunk driving; Electric properties; Electrodes; Environmental law; Ethanol; Graphene; Humidity; Low temperature; Manufacturing; Measurement methods; Metal oxides; Methods; Morphology; nanoporous alumina; Purity; resistive sensor; Room temperature; Semiconductor materials; Semiconductors; Sensors; Vapor resistance; Working conditions; anodization; resistive sensor; alcohol vapor; nanoporous alumina; AAO
• DOI: 10.3390/mi14071330
• ISSN: 2072-666X

With the increases in work environment regulations restricting alcohol to 1000 ppm, and in drink-driving laws, testing for alcohol with a simple method is a crucial issue. Conventional alcohol sensors based on sulfide, metal oxide, boron nitride or graphene oxide have a detection limit in the range of 50–1000 ppm but have disadvantages of complicated manufacture and longer processing times. A recent portable alcohol meter based on semiconductor material using conductivity or chemistry measurements still has the problem of a complex and lengthy manufacturing process. In this paper, a simple and effective resistive-type alcohol vapor sensor using one-step anodic aluminum oxide (AAO) is proposed. The nanoporous AAO was produced in one-step by anodizing low-purity AA1050 at room temperature of 25 °C, which overcame the traditional high-cost and lengthy process at low temperature of anodization and etching from high-purity aluminum. The highly specific surface area of AAO has benefits for good sensing performance, especially as a humidity or alcohol vapor sensor. With the resistance measurement method, alcohol vapor concentration of 0, 100, 300, 500, 700 and 1000 ppm correspond to mean resistances of 8524 Ω, 8672 Ω, 9121 Ω, 9568 Ω, 10,243 Ω, and 11,045 Ω, respectively, in a linear relationship. Compared with other materials for detecting alcohol vapor, the AAO resistive sensor has advantages of fast and simple manufacturing with good detection limits for practical applications. The resistive-type alcohol vapor-sensing mechanism is described with respect to the resistivity of the test substance and the pore morphology of AAO. In a human breath test, the AAO sensor can quickly distinguish whether the subject is drinking, with normal breath response of −30% to −40% and −20% to −30% response after drinking 50 mL of wine of 25% alcohol.