Nanophase oxalate precursors of thermoelectric CoSb3 by controlled coprecipitation predicted by thermodynamic modeling
[Display omitted] •CoSb3 nanoparticles were synthesized by thermodynamic modeling.•Highly monodispersed precursors of CoSb3 nanoparticles were coprecipitated.•Method to synthesized nanoparticle with complex composition was established.•The ZT of coprecipitated CoSb3 shows twice higher than the ball...
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| Published in | Advanced powder technology : the international journal of the Society of Powder Technology, Japan Vol. 27; no. 2; pp. 773 - 778 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.03.2016
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| Subjects | |
| Online Access | Get full text |
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| Abstract | [Display omitted]
•CoSb3 nanoparticles were synthesized by thermodynamic modeling.•Highly monodispersed precursors of CoSb3 nanoparticles were coprecipitated.•Method to synthesized nanoparticle with complex composition was established.•The ZT of coprecipitated CoSb3 shows twice higher than the ball milled one.
The precursors for the formation of thermoelectric skutterudite CoSb3 nanoparticles are predicted by thermodynamic modeling of the complex chemical species. Based on the results, equimolar mixture of CoC2O4·2H2O and Sb(C2O4)OH are successively co-precipitated under controlled conditions of pH=2.7 and concentration of reactants. The as synthesized powder was decomposed at 350°C to remove the organic molecules and further reduced to CoSb3 phase by heating at 530°C under hydrogen flow. The obtained powder was consolidated by spark plasma sintering (SPS). CoSb3 prepared by controlled chemical co-precipitation has p-type behavior with a positive sign of the Seebeck coefficient. TE transport properties were measured, which revealed that the Seebeck coefficient increased 2.5 times with increasing the temperature and it is lower than the ball milled CoSb3. Thermal conductivity of sintered CoSb3 at 773K starts from 0.06W/cmK at room temperature and decreases to 0.04W/cmK at 700K, which is lower than the bulk counterpart. The ZT of coprecipitated CoSb3 and SPS consolidated at 773K shows 2 times higher than the ball milled one. |
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| AbstractList | The precursors for the formation of thermoelectric skutterudite CoSb3 nanoparticles are predicted by thermodynamic modeling of the complex chemical species. Based on the results, equimolar mixture of CoC2O4 center dot 2H(2)O and Sb(C2O4) OH are successively co-precipitated under controlled conditions of pH = 2.7 and concentration of reactants. The as synthesized powder was decomposed at 350 degrees C to remove the organic molecules and further reduced to CoSb3 phase by heating at 530 degrees C under hydrogen flow. The obtained powder was consolidated by spark plasma sintering (SPS). CoSb3 prepared by controlled chemical co-precipitation has p-type behavior with a positive sign of the Seebeck coefficient. TE transport properties were measured, which revealed that the Seebeck coefficient increased 2.5 times with increasing the temperature and it is lower than the ball milled CoSb3. Thermal conductivity of sintered CoSb3 at 773 K starts from 0.06 W/cm K at room temperature and decreases to 0.04 W/cm K at 700 K, which is lower than the bulk counterpart. The ZT of coprecipitated CoSb3 and SPS consolidated at 773 K shows 2 times higher than the ball milled one. (C) 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved. [Display omitted] •CoSb3 nanoparticles were synthesized by thermodynamic modeling.•Highly monodispersed precursors of CoSb3 nanoparticles were coprecipitated.•Method to synthesized nanoparticle with complex composition was established.•The ZT of coprecipitated CoSb3 shows twice higher than the ball milled one. The precursors for the formation of thermoelectric skutterudite CoSb3 nanoparticles are predicted by thermodynamic modeling of the complex chemical species. Based on the results, equimolar mixture of CoC2O4·2H2O and Sb(C2O4)OH are successively co-precipitated under controlled conditions of pH=2.7 and concentration of reactants. The as synthesized powder was decomposed at 350°C to remove the organic molecules and further reduced to CoSb3 phase by heating at 530°C under hydrogen flow. The obtained powder was consolidated by spark plasma sintering (SPS). CoSb3 prepared by controlled chemical co-precipitation has p-type behavior with a positive sign of the Seebeck coefficient. TE transport properties were measured, which revealed that the Seebeck coefficient increased 2.5 times with increasing the temperature and it is lower than the ball milled CoSb3. Thermal conductivity of sintered CoSb3 at 773K starts from 0.06W/cmK at room temperature and decreases to 0.04W/cmK at 700K, which is lower than the bulk counterpart. The ZT of coprecipitated CoSb3 and SPS consolidated at 773K shows 2 times higher than the ball milled one. |
| Author | Ahn, Jong Pil Koo, Sang Mo Toprak, Muhammet S. Park, Joo-Seok Lee, Byung-Ha Tafti, Mohsen Y. Kim, Do Kyung Kim, Min-Suk Moon, Kyoung-Sook Kim, Min Cheol Kim, Se-Hoon |
| Author_xml | – sequence: 1 givenname: Se-Hoon surname: Kim fullname: Kim, Se-Hoon organization: Business Cooperation Center, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, South Korea – sequence: 2 givenname: Min Cheol surname: Kim fullname: Kim, Min Cheol organization: Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA – sequence: 3 givenname: Min-Suk surname: Kim fullname: Kim, Min-Suk organization: Business Cooperation Center, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, South Korea – sequence: 4 givenname: Jong Pil surname: Ahn fullname: Ahn, Jong Pil organization: Business Cooperation Center, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, South Korea – sequence: 5 givenname: Kyoung-Sook surname: Moon fullname: Moon, Kyoung-Sook organization: Department of Mathematics and Information, Gachon University, Seongnam 461-701, South Korea – sequence: 6 givenname: Sang Mo surname: Koo fullname: Koo, Sang Mo organization: Department of Electronic Materials Engineering, Kwangwoon University, Seoul 139-701, South Korea – sequence: 7 givenname: Mohsen Y. surname: Tafti fullname: Tafti, Mohsen Y. organization: Department of Materials and Nano Physics, KTH Royal Institute of Technology, Stockholm 16440, Sweden – sequence: 8 givenname: Joo-Seok surname: Park fullname: Park, Joo-Seok organization: Business Cooperation Center, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, South Korea – sequence: 9 givenname: Muhammet S. surname: Toprak fullname: Toprak, Muhammet S. organization: Department of Materials and Nano Physics, KTH Royal Institute of Technology, Stockholm 16440, Sweden – sequence: 10 givenname: Byung-Ha surname: Lee fullname: Lee, Byung-Ha organization: Department of Material Science & Engineering, Myongji University, YongIn 449-728, South Korea – sequence: 11 givenname: Do Kyung surname: Kim fullname: Kim, Do Kyung email: dokyung@konyang.ac.kr organization: Department of Pharmacology, College of Medicine, Konyang University, Daejeon 302-718, South Korea |
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•CoSb3 nanoparticles were synthesized by thermodynamic modeling.•Highly monodispersed precursors of CoSb3 nanoparticles were... The precursors for the formation of thermoelectric skutterudite CoSb3 nanoparticles are predicted by thermodynamic modeling of the complex chemical species.... |
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| SubjectTerms | Co-precipitation CoSb3 Thermodynamic modeling Thermoelectric |
| Title | Nanophase oxalate precursors of thermoelectric CoSb3 by controlled coprecipitation predicted by thermodynamic modeling |
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