Thermal processing influence on mechanical, thermal, and biodegradation behavior in poly(β-hydroxybutyrate)/poly(ε-caprolactone) blends: A descriptive model
ABSTRACT Poly(β‐hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression‐molded blends of PHB and poly(ε‐caprolactone) [PCL] (70/30 mass ratio) were cooled to room te...
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| Published in | Journal of applied polymer science Vol. 133; no. 27; pp. np - n/a |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken
Blackwell Publishing Ltd
15.07.2016
Wiley Subscription Services, Inc |
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| Abstract | ABSTRACT
Poly(β‐hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression‐molded blends of PHB and poly(ε‐caprolactone) [PCL] (70/30 mass ratio) were cooled to room temperature following five different thermal treatments after molding at 180 °C. Blends processed with higher cooling rates were easier to biodegrade, nevertheless elongation at break and tensile strength decreased. Slower cooling kinetics and isothermal treatments increased perfection of crystals, as seen in differential scanning calorimetry and X‐ray diffraction and spherulites size. A descriptive model is proposed herein where thermal, biodegradation, tensile properties, and crystal features were related to cooling kinetics applied. It is proposed that properties of 70/30 (PHB/PCL) blends can be predetermined by an adequate control of thermal conditions during processing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43569. |
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| AbstractList | ABSTRACT
Poly(β‐hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression‐molded blends of PHB and poly(ε‐caprolactone) [PCL] (70/30 mass ratio) were cooled to room temperature following five different thermal treatments after molding at 180 °C. Blends processed with higher cooling rates were easier to biodegrade, nevertheless elongation at break and tensile strength decreased. Slower cooling kinetics and isothermal treatments increased perfection of crystals, as seen in differential scanning calorimetry and X‐ray diffraction and spherulites size. A descriptive model is proposed herein where thermal, biodegradation, tensile properties, and crystal features were related to cooling kinetics applied. It is proposed that properties of 70/30 (PHB/PCL) blends can be predetermined by an adequate control of thermal conditions during processing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43569. Poly( beta -hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression-molded blends of PHB and poly( epsilon -caprolactone) [PCL] (70/30 mass ratio) were cooled to room temperature following five different thermal treatments after molding at 180 degree C. Blends processed with higher cooling rates were easier to biodegrade, nevertheless elongation at break and tensile strength decreased. Slower cooling kinetics and isothermal treatments increased perfection of crystals, as seen in differential scanning calorimetry and X-ray diffraction and spherulites size. A descriptive model is proposed herein where thermal, biodegradation, tensile properties, and crystal features were related to cooling kinetics applied. It is proposed that properties of 70/30 (PHB/PCL) blends can be predetermined by an adequate control of thermal conditions during processing. J. Appl. Polym. Sci. 2016, 133, 43569. Poly([beta]-hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression-molded blends of PHB and poly([epsi]-caprolactone) [PCL] (70/30 mass ratio) were cooled to room temperature following five different thermal treatments after molding at 180°C. Blends processed with higher cooling rates were easier to biodegrade, nevertheless elongation at break and tensile strength decreased. Slower cooling kinetics and isothermal treatments increased perfection of crystals, as seen in differential scanning calorimetry and X-ray diffraction and spherulites size. A descriptive model is proposed herein where thermal, biodegradation, tensile properties, and crystal features were related to cooling kinetics applied. It is proposed that properties of 70/30 (PHB/PCL) blends can be predetermined by an adequate control of thermal conditions during processing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43569. ABSTRACT Poly(β‐hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has been blended with other polymers. Compression‐molded blends of PHB and poly(ε‐caprolactone) [PCL] (70/30 mass ratio) were cooled to room temperature following five different thermal treatments after molding at 180 °C. Blends processed with higher cooling rates were easier to biodegrade, nevertheless elongation at break and tensile strength decreased. Slower cooling kinetics and isothermal treatments increased perfection of crystals, as seen in differential scanning calorimetry and X‐ray diffraction and spherulites size. A descriptive model is proposed herein where thermal, biodegradation, tensile properties, and crystal features were related to cooling kinetics applied. It is proposed that properties of 70/30 (PHB/PCL) blends can be predetermined by an adequate control of thermal conditions during processing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 43569. |
| Author | Gracida-Rodríguez, Jorge Noel Vergara-Porras, Berenice Pérez-Guevara, Fermín |
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Poly(β‐hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB... Poly([beta]-hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has... Poly( beta -hydroxybutyrate) [PHB] is a biodegradable and biocompatible polymer produced by some bacteria genders. To improve mechanical properties, PHB has... |
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| SubjectTerms | Bacteria biodegradable Biodegradation Blends Controllers Cooling Materials science Mathematical models molding phase behavior Polyhydroxybutyrate Polymers Programmable logic devices properties and characterization |
| Title | Thermal processing influence on mechanical, thermal, and biodegradation behavior in poly(β-hydroxybutyrate)/poly(ε-caprolactone) blends: A descriptive model |
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