Advances in actinide solid-state and coordination chemistry

Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departure...

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Published inMRS bulletin Vol. 35; no. 11; pp. 868 - 876
Main Authors Burns, Peter C., Ikeda, Yasuhisa, Czerwinski, Ken
Format Journal Article
LanguageEnglish
Published New York, USA Cambridge University Press 01.11.2010
Springer International Publishing
Springer Nature B.V
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Abstract Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation's repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.
AbstractList Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5 f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation's repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.
Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation’s repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.
Author Burns, Peter C.
Ikeda, Yasuhisa
Czerwinski, Ken
Author_xml – sequence: 1
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  surname: Burns
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  givenname: Yasuhisa
  surname: Ikeda
  fullname: Ikeda, Yasuhisa
  email: yikeda@nr.titech.ac.jp
  organization: Laboratory for Nuclear Reactors at Tokyo Institute of Technology, Japan; yikeda@nr.titech.ac.jp
– sequence: 3
  givenname: Ken
  surname: Czerwinski
  fullname: Czerwinski, Ken
  email: ken.czerwinski@unlv.edu
  organization: University of Nevada, Las Vegas, NV 89154, USA; ken.czerwinski@unlv.edu
BackLink https://www.osti.gov/biblio/1065050$$D View this record in Osti.gov
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Snippet Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements....
Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5 f elements....
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SubjectTerms Applied and Technical Physics
Cations
Characterization and Evaluation of Materials
Complexity
Coordination
Energy Materials
Functional groups
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ligands
Materials Engineering
Materials Science
NANOSCIENCE AND NANOTECHNOLOGY
Nanotechnology
nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
Solid state
Technical Feature
Topology
Title Advances in actinide solid-state and coordination chemistry
URI https://www.cambridge.org/core/product/identifier/S0883769400008873/type/journal_article
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https://www.osti.gov/biblio/1065050
Volume 35
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