Outer‐Sphere Reactivity Shift of Secondary Phosphine Oxide‐Based Nickel Complexes: From Ethylene Hydrophosphinylation to Oligomerization

A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migrator...

Full description

Saved in:
Bibliographic Details
Published inChemistry : a European journal Vol. 23; no. 31; pp. 7433 - 7437
Main Authors Lhermet, Rudy, Moser, Emile, Jeanneau, Erwann, Olivier‐Bourbigou, Hélène, Breuil, Pierre‐Alain R.
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 01.06.2017
Wiley-VCH Verlag
Subjects
Online AccessGet full text

Cover

Loading…
Abstract A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer‐sphere interaction with the coordinated SPO ligand. NMR experiments and X‐ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway. On the outer sphere: A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer‐sphere interaction with the coordinated SPO ligand.
AbstractList A new dimension for secondary phosphineoxide (SPOs) ligands is described in this article. Demonstratedon original p-allylic nickel structures, these self-assembledcomplexes trigger catalytic hydrophosphinylationreactions. Addition of a Lewis acid B(C6F5)3 switches the reactivitytowards migratory insertion and thus ethylene oligomerizationthrough an unprecedented outer-sphere interactionwith the coordinated SPO ligand. NMR experimentsand X-ray analyses allowed for the observation ofthe formation of zwitterionic active species as well as theirdegradation pathway.
A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer‐sphere interaction with the coordinated SPO ligand. NMR experiments and X‐ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway. On the outer sphere: A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer‐sphere interaction with the coordinated SPO ligand.
A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π-allylic nickel structures, these self-assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C F ) switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer-sphere interaction with the coordinated SPO ligand. NMR experiments and X-ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway.
A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π-allylic nickel structures, these self-assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6 F5 )3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer-sphere interaction with the coordinated SPO ligand. NMR experiments and X-ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway.
Abstract A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these self‐assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C 6 F 5 ) 3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer‐sphere interaction with the coordinated SPO ligand. NMR experiments and X‐ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway.
A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π-allylic nickel structures, these self-assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C6F5)3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer-sphere interaction with the coordinated SPO ligand. NMR experiments and X-ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway.
Author Moser, Emile
Olivier‐Bourbigou, Hélène
Lhermet, Rudy
Jeanneau, Erwann
Breuil, Pierre‐Alain R.
Author_xml – sequence: 1
  givenname: Rudy
  surname: Lhermet
  fullname: Lhermet, Rudy
  organization: IFP Energies nouvelles
– sequence: 2
  givenname: Emile
  surname: Moser
  fullname: Moser, Emile
  organization: IFP Energies nouvelles
– sequence: 3
  givenname: Erwann
  surname: Jeanneau
  fullname: Jeanneau, Erwann
  organization: Université de Lyon
– sequence: 4
  givenname: Hélène
  surname: Olivier‐Bourbigou
  fullname: Olivier‐Bourbigou, Hélène
  organization: IFP Energies nouvelles
– sequence: 5
  givenname: Pierre‐Alain R.
  orcidid: 0000-0001-6788-8663
  surname: Breuil
  fullname: Breuil, Pierre‐Alain R.
  email: pierre-alain.breuil@ifpen.fr
  organization: IFP Energies nouvelles
BackLink https://www.ncbi.nlm.nih.gov/pubmed/28393410$$D View this record in MEDLINE/PubMed
https://ifp.hal.science/hal-01581820$$DView record in HAL
BookMark eNqFkc2O0zAURi00iOkMbFkiS2xg0eKfOI7ZDVWHIhWKKKytNL4hHpI42MnMZFY8AAuekSfBpaVIbFhd6ep8n-7VOUMnrWsBoceUzCgh7EVRQTNjhEpCE5rcQxMqGJ1ymYoTNCEqkdNUcHWKzkK4IoSolPMH6JRlXPGEkgn6vh568D-__dh0FXjAHyAventt-xFvKlv22JV4A4VrTe5H_L5yoatsC3h9aw3E2Ks8gMHvbPEFajx3TVfDLYSX-NK7Bi_6aqwh0svReNcdwmOd99a1uHd4XdvPrgFv736vHqL7ZV4HeHSY5-jT5eLjfDldrV-_mV-spoWgJJkmRSbplm1pmTNJhaElF8RAYsg2UyyTSpiyUEpAKuPghm2lTLlUjBRclmD4OXq-763yWnfeNvE37XKrlxcrvdsRKjKaMXJNI_tsz3befR0g9LqxoYC6zltwQ9A0y1IuUq5kRJ_-g165wbfxE00ViXqEZDxSsz1VeBeCh_J4ASV651TvnOqj0xh4cqgdtg2YI_5HYgTUHrixNYz_qdPz5eLt3_JfdRayFg
CitedBy_id crossref_primary_10_1002_ejic_202001028
crossref_primary_10_3390_catal10050498
crossref_primary_10_1016_j_tet_2020_131020
crossref_primary_10_1021_acs_joc_8b02882
crossref_primary_10_1002_chem_202302362
crossref_primary_10_1002_cctc_202200736
crossref_primary_10_1016_j_ccr_2021_214227
crossref_primary_10_1021_acs_chemrev_0c00076
crossref_primary_10_1021_acs_joc_0c02246
crossref_primary_10_1021_acs_organomet_1c00575
crossref_primary_10_3390_ma16093308
crossref_primary_10_1039_D3CS00188A
crossref_primary_10_1021_acs_organomet_2c00399
crossref_primary_10_1002_cctc_202000493
crossref_primary_10_1002_adsc_201700663
crossref_primary_10_1021_acs_chemrev_1c00862
crossref_primary_10_1039_C9DT00498J
crossref_primary_10_1039_C9CY01501A
crossref_primary_10_1016_j_poly_2021_115357
Cites_doi 10.1039/C3RA45212C
10.1021/ie50732a005
10.1002/ange.200500879
10.1021/ja994222c
10.1021/jo010764c
10.1002/zaac.19885660116
10.1021/ja004191h
10.1021/om100171p
10.1021/ja002042t
10.1002/chem.201103723
10.1002/ange.201002225
10.1016/S0022-328X(02)01259-7
10.1021/ic049744u
10.1021/ja0283551
10.1246/cl.130374
10.1016/j.jorganchem.2010.08.043
10.1021/ol049851s
10.1021/jo701893m
10.1021/jo501842p
10.1021/ic50167a046
10.1002/ange.201003125
10.1039/c2ob25225b
10.1021/ba-1968-0070.ch013
10.1021/ja0494297
10.1002/1521-3773(20010417)40:8<1513::AID-ANIE1513>3.0.CO;2-C
10.1002/anie.201002225
10.1021/jo010983y
10.1016/j.jorganchem.2013.08.021
10.1002/anie.200461630
10.1002/anie.197309431
10.1002/anie.201003125
10.1007/s10562-014-1451-x
10.1021/cr9804644
10.1039/c39860000031
10.1016/S0022-328X(00)99835-8
10.1021/jacs.5b02802
10.1021/ic50149a065
10.1002/chem.201101663
10.1016/S0010-8545(99)00229-5
10.1021/om010576c
10.1021/ol0508431
10.1002/ange.200461630
10.1021/acs.organomet.5b00055
10.1021/om200234c
10.1016/j.tetasy.2003.07.008
10.1002/anie.200500879
10.1021/ar050040d
10.1002/adsc.201200853
10.1002/1521-3757(20010417)113:8<1561::AID-ANGE1561>3.0.CO;2-0
10.1021/cr980461r
10.1002/ange.19730852302
ContentType Journal Article
Copyright 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Distributed under a Creative Commons Attribution 4.0 International License
Copyright_xml – notice: 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
– notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
– notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
– notice: Distributed under a Creative Commons Attribution 4.0 International License
DBID NPM
AAYXX
CITATION
7SR
8BQ
8FD
JG9
K9.
7X8
1XC
DOI 10.1002/chem.201701414
DatabaseName PubMed
CrossRef
Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
MEDLINE - Academic
Hyper Article en Ligne (HAL)
DatabaseTitle PubMed
CrossRef
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
Engineered Materials Abstracts
Technology Research Database
METADEX
MEDLINE - Academic
DatabaseTitleList

PubMed
MEDLINE - Academic
CrossRef
Materials Research Database
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1521-3765
EndPage 7437
ExternalDocumentID oai_HAL_hal_01581820v1
10_1002_chem_201701414
28393410
CHEM201701414
Genre shortCommunication
Journal Article
GroupedDBID ---
-DZ
-~X
.3N
.GA
05W
0R~
10A
1L6
1OB
1OC
1ZS
29B
33P
3SF
3WU
4.4
4ZD
50Y
50Z
51W
51X
52M
52N
52O
52P
52S
52T
52U
52W
52X
53G
5GY
5VS
66C
6J9
702
77Q
7PT
8-0
8-1
8-3
8-4
8-5
8UM
930
A03
AAESR
AAEVG
AAHHS
AANLZ
AAONW
AASGY
AAXRX
AAZKR
ABCQN
ABCUV
ABDBF
ABIJN
ABJNI
ABLJU
ABPVW
ACAHQ
ACCFJ
ACCZN
ACGFS
ACIWK
ACNCT
ACPOU
ACXBN
ACXQS
ADBBV
ADEOM
ADIZJ
ADKYN
ADMGS
ADOZA
ADXAS
ADZMN
ADZOD
AEEZP
AEGXH
AEIGN
AEIMD
AEQDE
AEUQT
AEUYR
AFBPY
AFFPM
AFGKR
AFPWT
AFRAH
AFZJQ
AHBTC
AHMBA
AITYG
AIURR
AIWBW
AJBDE
AJXKR
ALAGY
ALMA_UNASSIGNED_HOLDINGS
AMBMR
AMYDB
ATUGU
AUFTA
AZBYB
AZVAB
BAFTC
BDRZF
BFHJK
BHBCM
BMNLL
BMXJE
BNHUX
BROTX
BRXPI
BY8
CS3
D-E
D-F
DCZOG
DPXWK
DR2
DRFUL
DRSTM
EBD
EBS
EJD
F00
F01
F04
F5P
G-S
G.N
GNP
GODZA
H.T
H.X
HBH
HGLYW
HHY
HHZ
HZ~
IX1
J0M
JPC
KQQ
LATKE
LAW
LC2
LC3
LEEKS
LH4
LITHE
LOXES
LP6
LP7
LUTES
LW6
LYRES
MEWTI
MK4
MRFUL
MRSTM
MSFUL
MSSTM
MXFUL
MXSTM
N04
N05
N9A
NF~
NNB
O66
O9-
OIG
P2W
P2X
P4D
PQQKQ
Q.N
Q11
QB0
QRW
R.K
RGC
RNS
ROL
RWI
RX1
RYL
SUPJJ
TN5
TWZ
UB1
UPT
V2E
V8K
W8V
W99
WBFHL
WBKPD
WH7
WIB
WIH
WIK
WJL
WOHZO
WQJ
WRC
WXSBR
WYISQ
XG1
XPP
XV2
YZZ
ZZTAW
~IA
~WT
NPM
.GJ
.Y3
186
31~
6TJ
9M8
AAYXX
ABEML
ACBWZ
ACSCC
AGCDD
AI.
ASPBG
AVWKF
AZFZN
BZBRT
CITATION
FEDTE
HF~
HVGLF
H~9
MVM
PALCI
RIWAO
RJQFR
SAMSI
UQL
VH1
WSR
Y6R
ZGI
7SR
8BQ
8FD
JG9
K9.
7X8
1XC
ID FETCH-LOGICAL-c5104-4c871b2b1fa2715d1f350de4d0b8928795dfc995e67c993d2b77637920c37fed3
IEDL.DBID DR2
ISSN 0947-6539
IngestDate Tue Oct 15 15:34:07 EDT 2024
Sat Aug 17 00:42:22 EDT 2024
Thu Oct 10 19:11:12 EDT 2024
Thu Sep 26 19:16:44 EDT 2024
Sat Sep 28 08:46:31 EDT 2024
Sat Aug 24 01:10:57 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 31
Keywords nickel
homogeneous catalysis
secondary phosphine oxide ligand
Lewis acid interaction
outer-sphere coordination
Cayalysts
Stable palladium catalysis
Olefins
Homogeneous catalysis
Platinium
Nickel
Secondary phosphine oxide ligand
Dimerization
Outer-pherecoordination
Hydrogeznation
Language English
License 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c5104-4c871b2b1fa2715d1f350de4d0b8928795dfc995e67c993d2b77637920c37fed3
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ORCID 0000-0001-6788-8663
0000-0002-0337-4652
0000-0002-8861-4140
PMID 28393410
PQID 1904145723
PQPubID 986340
PageCount 5
ParticipantIDs hal_primary_oai_HAL_hal_01581820v1
proquest_miscellaneous_1886356397
proquest_journals_1904145723
crossref_primary_10_1002_chem_201701414
pubmed_primary_28393410
wiley_primary_10_1002_chem_201701414_CHEM201701414
PublicationCentury 2000
PublicationDate June 1, 2017
PublicationDateYYYYMMDD 2017-06-01
PublicationDate_xml – month: 06
  year: 2017
  text: June 1, 2017
  day: 01
PublicationDecade 2010
PublicationPlace Germany
PublicationPlace_xml – name: Germany
– name: Weinheim
PublicationSubtitle A European Journal
PublicationTitle Chemistry : a European journal
PublicationTitleAlternate Chemistry
PublicationYear 2017
Publisher Wiley Subscription Services, Inc
Wiley-VCH Verlag
Publisher_xml – name: Wiley Subscription Services, Inc
– name: Wiley-VCH Verlag
References 2004; 43
2015; 34
2011; 696
2001; 123
2004; 126
1983; 252
2010
1983 1983; 99
1974; 70
2002; 653
2015; 145
2013; 42
2011; 30
2003; 14
2004; 6
1975; 14
2010 2010; 49 122
2012; 18
2015; 80
2011; 17
2001; 66
2008; 73
2012; 10
2001; 20
1988; 566
2014; 751
2014; 4
2015; 137
2000; 203
2010; 29
1977; 16
2002; 67
2002; 124
1986
2005; 7
2005 2005; 44 117
2013; 355
1970; 62
2000; 100
2000; 122
1973 1973; 12 85
2005; 38
2003; 103
2001 2001; 40 113
e_1_2_2_47_2
e_1_2_2_4_2
e_1_2_2_24_1
e_1_2_2_6_1
e_1_2_2_22_2
e_1_2_2_49_2
e_1_2_2_20_2
e_1_2_2_2_1
e_1_2_2_41_2
e_1_2_2_43_2
e_1_2_2_8_1
e_1_2_2_28_1
e_1_2_2_26_2
e_1_2_2_45_2
e_1_2_2_45_3
(e_1_2_2_4_3) 1983; 99
e_1_2_2_13_2
e_1_2_2_11_3
e_1_2_2_11_2
e_1_2_2_38_2
e_1_2_2_51_2
e_1_2_2_19_2
e_1_2_2_30_2
e_1_2_2_53_2
e_1_2_2_17_3
Hartwig J. F. (e_1_2_2_1_1) 2010
e_1_2_2_17_2
e_1_2_2_32_2
e_1_2_2_55_2
e_1_2_2_15_2
e_1_2_2_34_2
e_1_2_2_36_1
e_1_2_2_3_2
e_1_2_2_46_3
e_1_2_2_5_1
e_1_2_2_23_2
e_1_2_2_48_2
e_1_2_2_7_1
e_1_2_2_21_1
e_1_2_2_40_2
e_1_2_2_29_2
e_1_2_2_42_2
e_1_2_2_7_2
e_1_2_2_44_1
e_1_2_2_27_2
e_1_2_2_25_3
e_1_2_2_9_2
e_1_2_2_25_2
e_1_2_2_46_2
e_1_2_2_12_2
e_1_2_2_37_2
e_1_2_2_10_2
e_1_2_2_39_2
e_1_2_2_52_1
e_1_2_2_50_2
e_1_2_2_31_2
e_1_2_2_18_1
e_1_2_2_16_2
e_1_2_2_33_2
e_1_2_2_54_2
e_1_2_2_35_1
e_1_2_2_14_2
e_1_2_2_56_2
References_xml – volume: 653
  start-page: 63
  year: 2002
  end-page: 68
  publication-title: J. Organomet. Chem.
– volume: 566
  start-page: 121
  year: 1988
  end-page: 130
  publication-title: Z. Anorg. Allg. Chem.
– volume: 20
  start-page: 5425
  year: 2001
  end-page: 5431
  publication-title: Organometallics
– volume: 67
  start-page: 3643
  year: 2002
  end-page: 3650
  publication-title: J. Org. Chem.
– volume: 34
  start-page: 1139
  year: 2015
  end-page: 1142
  publication-title: Organometallics
– volume: 99
  start-page: 121813
  year: 1983 1983
  publication-title: Chem. Abstr.
– volume: 103
  start-page: 283
  year: 2003
  end-page: 315
  publication-title: Chem. Rev.
– volume: 14
  start-page: 2821
  year: 2003
  end-page: 2826
  publication-title: Tetrahedron: Asymmetry
– volume: 7
  start-page: 2909
  year: 2005
  end-page: 2911
  publication-title: Org. Lett.
– volume: 126
  start-page: 5080
  year: 2004
  end-page: 5081
  publication-title: J. Am. Chem. Soc.
– volume: 696
  start-page: 130
  year: 2011
  end-page: 140
  publication-title: J. Organomet. Chem.
– volume: 38
  start-page: 784
  year: 2005
  end-page: 793
  publication-title: Acc. Chem. Res.
– volume: 355
  start-page: 659
  year: 2013
  end-page: 666
  publication-title: Adv. Synth. Catal.
– volume: 44 117
  start-page: 4753 4831
  year: 2005 2005
  end-page: 4757 4835
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 4
  start-page: 2322
  year: 2014
  end-page: 2326
  publication-title: RSC Adv.
– volume: 100
  start-page: 1169
  year: 2000
  end-page: 1203
  publication-title: Chem. Rev.
– volume: 14
  start-page: 1732
  year: 1975
  end-page: 1734
  publication-title: Inorg. Chem.
– volume: 73
  start-page: 162
  year: 2008
  end-page: 167
  publication-title: J. Org. Chem.
– volume: 49 122
  start-page: 7890 8062
  year: 2010 2010
  end-page: 7894 8066
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 43
  start-page: 4921
  year: 2004
  end-page: 4926
  publication-title: Inorg. Chem.
– volume: 49 122
  start-page: 6873 7025
  year: 2010 2010
  end-page: 6876 7028
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 751
  start-page: 717
  year: 2014
  end-page: 741
  publication-title: J. Organomet. Chem.
– volume: 137
  start-page: 7718
  year: 2015
  end-page: 7727
  publication-title: J. Am. Chem. Soc.
– year: 2010
– volume: 17
  start-page: 12729
  year: 2011
  end-page: 12740
  publication-title: Chem. Eur. J.
– volume: 42
  start-page: 1065
  year: 2013
  end-page: 1067
  publication-title: Chem. Lett.
– start-page: 31
  year: 1986
  end-page: 33
  publication-title: J. Chem. Soc. Chem. Commun.
– volume: 122
  start-page: 1830
  year: 2000
  end-page: 1831
  publication-title: J. Am. Chem. Soc.
– volume: 12 85
  start-page: 943 1001
  year: 1973 1973
  end-page: 953 1012
  publication-title: Angew. Chem. Int. Ed. Engl. Angew. Chem.
– volume: 30
  start-page: 4814
  year: 2011
  end-page: 4821
  publication-title: Organometallics
– volume: 70
  start-page: 250
  year: 1974
  end-page: 265
  publication-title: Adv. Chem. Ser.
– volume: 66
  start-page: 8677
  year: 2001
  end-page: 6881
  publication-title: J. Org. Chem.
– volume: 44 117
  start-page: 1108 1132
  year: 2005 2005
  end-page: 1112 1136
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 203
  start-page: 325
  year: 2000
  end-page: 351
  publication-title: Coord. Chem. Rev.
– volume: 80
  start-page: 1192
  year: 2015
  end-page: 1199
  publication-title: J. Org. Chem.
– volume: 18
  start-page: 9622
  year: 2012
  end-page: 9627
  publication-title: Chem. Eur. J.
– volume: 252
  start-page: 347
  year: 1983
  end-page: 357
  publication-title: J. Organomet. Chem.
– volume: 40 113
  start-page: 1513 1561
  year: 2001 2001
  end-page: 1516 1564
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 122
  start-page: 12379
  year: 2000
  end-page: 12380
  publication-title: J. Am. Chem. Soc.
– volume: 6
  start-page: 1147
  year: 2004
  end-page: 1150
  publication-title: Org. Lett.
– volume: 145
  start-page: 173
  year: 2015
  end-page: 192
  publication-title: Catal. Lett.
– volume: 62
  start-page: 34
  year: 1970
  end-page: 44
  publication-title: Ind. Eng. Chem.
– volume: 10
  start-page: 3500
  year: 2012
  end-page: 3505
  publication-title: Org. Biomol. Chem.
– volume: 124
  start-page: 15280
  year: 2002
  end-page: 15285
  publication-title: J. Am. Chem. Soc.
– volume: 29
  start-page: 3139
  year: 2010
  end-page: 3145
  publication-title: Organometallics
– volume: 123
  start-page: 5352
  year: 2001
  end-page: 5353
  publication-title: J. Am. Chem. Soc.
– volume: 16
  start-page: 209
  year: 1977
  end-page: 211
  publication-title: Inorg. Chem.
– ident: e_1_2_2_38_2
  doi: 10.1039/C3RA45212C
– ident: e_1_2_2_26_2
  doi: 10.1021/ie50732a005
– ident: e_1_2_2_11_3
  doi: 10.1002/ange.200500879
– ident: e_1_2_2_51_2
  doi: 10.1021/ja994222c
– volume: 99
  start-page: 121813
  year: 1983
  ident: e_1_2_2_4_3
  publication-title: Chem. Abstr.
– ident: e_1_2_2_16_2
  doi: 10.1021/jo010764c
– ident: e_1_2_2_19_2
  doi: 10.1002/zaac.19885660116
– ident: e_1_2_2_49_2
  doi: 10.1021/ja004191h
– ident: e_1_2_2_53_2
  doi: 10.1021/om100171p
– ident: e_1_2_2_50_2
  doi: 10.1021/ja002042t
– ident: e_1_2_2_41_2
  doi: 10.1002/chem.201103723
– ident: e_1_2_2_28_1
– ident: e_1_2_2_7_2
  doi: 10.1002/ange.201002225
– volume-title: Organotransition Metal Chemistry: From Bonding to Catalysis
  year: 2010
  ident: e_1_2_2_1_1
  contributor:
    fullname: Hartwig J. F.
– ident: e_1_2_2_36_1
– ident: e_1_2_2_15_2
  doi: 10.1016/S0022-328X(02)01259-7
– ident: e_1_2_2_54_2
  doi: 10.1021/ic049744u
– ident: e_1_2_2_47_2
  doi: 10.1021/ja0283551
– ident: e_1_2_2_40_2
  doi: 10.1246/cl.130374
– ident: e_1_2_2_43_2
  doi: 10.1016/j.jorganchem.2010.08.043
– ident: e_1_2_2_12_2
  doi: 10.1021/ol049851s
– ident: e_1_2_2_44_1
– ident: e_1_2_2_52_1
– ident: e_1_2_2_10_2
  doi: 10.1021/jo701893m
– ident: e_1_2_2_37_2
  doi: 10.1021/jo501842p
– ident: e_1_2_2_55_2
  doi: 10.1021/ic50167a046
– ident: e_1_2_2_45_3
  doi: 10.1002/ange.201003125
– ident: e_1_2_2_42_2
  doi: 10.1039/c2ob25225b
– ident: e_1_2_2_27_2
  doi: 10.1021/ba-1968-0070.ch013
– ident: e_1_2_2_23_2
  doi: 10.1021/ja0494297
– ident: e_1_2_2_17_2
  doi: 10.1002/1521-3773(20010417)40:8<1513::AID-ANIE1513>3.0.CO;2-C
– ident: e_1_2_2_7_1
  doi: 10.1002/anie.201002225
– ident: e_1_2_2_14_2
  doi: 10.1021/jo010983y
– ident: e_1_2_2_30_2
  doi: 10.1016/j.jorganchem.2013.08.021
– ident: e_1_2_2_46_2
  doi: 10.1002/anie.200461630
– ident: e_1_2_2_25_2
  doi: 10.1002/anie.197309431
– ident: e_1_2_2_45_2
  doi: 10.1002/anie.201003125
– ident: e_1_2_2_29_2
  doi: 10.1007/s10562-014-1451-x
– ident: e_1_2_2_34_2
  doi: 10.1021/cr9804644
– ident: e_1_2_2_3_2
  doi: 10.1039/c39860000031
– ident: e_1_2_2_20_2
  doi: 10.1016/S0022-328X(00)99835-8
– ident: e_1_2_2_18_1
– ident: e_1_2_2_6_1
  doi: 10.1021/jacs.5b02802
– ident: e_1_2_2_56_2
  doi: 10.1021/ic50149a065
– ident: e_1_2_2_5_1
  doi: 10.1002/chem.201101663
– ident: e_1_2_2_33_2
  doi: 10.1016/S0010-8545(99)00229-5
– ident: e_1_2_2_48_2
  doi: 10.1021/om010576c
– ident: e_1_2_2_22_2
  doi: 10.1021/ol0508431
– ident: e_1_2_2_46_3
  doi: 10.1002/ange.200461630
– ident: e_1_2_2_35_1
  doi: 10.1021/acs.organomet.5b00055
– ident: e_1_2_2_8_1
– ident: e_1_2_2_9_2
  doi: 10.1021/om200234c
– ident: e_1_2_2_13_2
  doi: 10.1016/j.tetasy.2003.07.008
– ident: e_1_2_2_11_2
  doi: 10.1002/anie.200500879
– ident: e_1_2_2_31_2
  doi: 10.1021/ar050040d
– ident: e_1_2_2_2_1
– ident: e_1_2_2_39_2
  doi: 10.1002/adsc.201200853
– ident: e_1_2_2_17_3
  doi: 10.1002/1521-3757(20010417)113:8<1561::AID-ANGE1561>3.0.CO;2-0
– ident: e_1_2_2_24_1
– ident: e_1_2_2_21_1
– ident: e_1_2_2_32_2
  doi: 10.1021/cr980461r
– ident: e_1_2_2_4_2
– ident: e_1_2_2_25_3
  doi: 10.1002/ange.19730852302
SSID ssj0009633
Score 2.3949509
Snippet A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these...
A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π-allylic nickel structures, these...
Abstract A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π‐allylic nickel structures, these...
A new dimension for secondary phosphineoxide (SPOs) ligands is described in this article. Demonstratedon original p-allylic nickel structures, these...
SourceID hal
proquest
crossref
pubmed
wiley
SourceType Open Access Repository
Aggregation Database
Index Database
Publisher
StartPage 7433
SubjectTerms Catalysis
Chemical Sciences
Chemistry
Ethylene
homogeneous catalysis
Lewis acid
Lewis acid interaction
Ligands
Nickel
NMR
Nuclear magnetic resonance
Oligomerization
outer-sphere coordination
Phosphine oxide
secondary phosphine oxide ligand
Self-assembly
Switches
Title Outer‐Sphere Reactivity Shift of Secondary Phosphine Oxide‐Based Nickel Complexes: From Ethylene Hydrophosphinylation to Oligomerization
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201701414
https://www.ncbi.nlm.nih.gov/pubmed/28393410
https://www.proquest.com/docview/1904145723
https://search.proquest.com/docview/1886356397
https://ifp.hal.science/hal-01581820
Volume 23
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9NAEB6VXuAClPIwlGqpkDi5Xa_trt1bqRpFFRDUUKk3y_tqooY4ShzUcuoP4MBv5Jcwk41dAgckOPm1I-9jZudbe-cbgNfO4aIh0ybMtJIhzpJxmCkXhQa9s9BRZkxM0cjvP-x3z5KT8_T8lyh-zw_RfnAjy1jM12TgpZrt3ZKGYpsokpz4xH0ma2LTI1R0essfhdrlc8knMiQO1oa1kYu9VfEVr3RnQHsi_wScq_h14YA6D6Bsqu73nVzuzmu1q7_-xur4P217CPeX6JQdenXagDU7fgR3j5qkcJvwrUcpIH7cfO8THYFlp5YCIyj_BOsPhq5mlWN9WmMbfDn7OKhmkwHWhvWuhsai2Ft0moah-l3aEaO5aGSv7OyAdabVZ3aMSoNO0LLutZlWk6Xwtd-tx-qK9UbDi4p-MfnY0cdw1jn-dNQNlwkdQo2mn4SJxuWZEipypZBRaiIXp9zYxHCV5YLSnhun8zy1-xIPsRFK4vQnc8F1LJ018RNYH1dj-wwYrku5SzTXpTYJLzmWLqXmaBc6drk0AbxpBrSYeN6OwjM0i4J6t2h7N4AdHO-2ENFtdw_fFXQPoVJGBPdfogC2GnUolkY-KxBLoXwqRRzAq_YxDgj9cynHtppjmSwjBkBEfQE89WrUvgqRXY4gggcgFsrwl4oWRJLRXj3_F6EXcI_O_Va3LVivp3P7EkFVrbYXhvMT2uAb1w
link.rule.ids 230,315,786,790,891,1382,27955,27956,46327,46751
linkProvider Wiley-Blackwell
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwEB5BOZRLeZdAAYOQOKV1nKROuJXSVYBtF3VbiVuU-MGuut2s9oFaTvwADvxGfgkz8SbVwgEJTlESj-LEM57Pzsw3AC-txUVDorSfqFL6OEuGflLawNfonYUKEq1DykY-PNrNTqP3n-ImmpByYRw_RLvhRpZRz9dk4LQhvXPFGoovRankRChel7K-gTYfk22-Pb5ikEL9ctXkI-kTC2vD28jFzqr8il-6PqCoyD8h5yqCrV1Q5xaUTedd5MnZ9mJebquvv_E6_tfb3YaNJUBle06j7sA1M74L6_tNXbh78L1HVSB-fvvRJ0YCw44N5UZQCQrWHwztnFWW9WmZrfHp7OOgmk0G2B3Wuxhqg2Jv0G9qhhp4ZkaMpqORuTCz16wzrc7ZAeoN-kHDsks9rSZL4UsXsMfmFeuNhp8r-svk0kfvw2nn4GQ_85c1HXyF1h_5kcIVWinKwBZCBrEObBhzbSLNyyQVVPlcW5WmsdmVeAi1KCXOgDIVXIXSGh0-gLVxNTYPgeHSlNtIcVUoHfGCY-tCKo6moUKbSu3Bq2ZE84mj7sgdSbPI6evm7df14AUOeNuIGLezvW5O1xAtJcRx_yXwYKvRh3xp57Mc4RTKx1KEHjxvb-OA0G-XYmyqBbZJEiIBRODnwabTo_ZRCO5SxBHcA1Frw186mhNPRnv26F-EnsF6dnLYzbvvjj48hpt03UW-bcHafLowTxBjzcuntRX9ApLRH_c
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3NbtNAEB5BkYAL_wVDgQUhcXK7XttZm1tpGwUoTdVQqTfL3h8SNcRR4qCWEw_AgWfkSZjxxi6BAxKcLNs78q53Zucbe-cbgBfWYtCQKO0nqpA-rpKhnxQ28DV6Z6GCROuQspHfH3R6x9Hbk_jklyx-xw_RfnAjy6jXazLwqbZbF6ShOCbKJCc-8bqS9ZWoEwoKv3aPLgikUL1cMflI-kTC2tA2crG1Kr_ili4PaVPkn4hzFcDWHqh7E_Km727jyenmoio21ZffaB3_Z3C34MYSnrJtp0-34ZKZ3IFrO01VuLvwrU81IH58_T4gPgLDjgxlRlABCjYYjmzFSssGFGRrfDg7HJbz6RB7w_pnI21Q7DV6Tc1Q_07NmNFiNDZnZv6KdWflJ7aHWoNe0LDeuZ6V06Xwuduux6qS9cejjyX9Y3LJo_fguLv3YafnLys6-AptP_IjhfFZIYrA5kIGsQ5sGHNtIs2LJBVU91xblaax6Ug8hFoUEtc_mQquQmmNDtdhbVJOzANgGJhyGymucqUjnnNsnUvF0TBUaFOpPXjZTGg2dcQdmaNoFhm93ax9ux48x_luGxHfdm97P6NriJUSYrj_HHiw0ahDtrTyeYZgCuVjKUIPnrW3cULop0s-MeUC2yQJUQAi7PPgvlOj9lEI7VJEEdwDUSvDXzqaEUtGe_bwX4SewtXD3W62_-bg3SO4TpfdtrcNWKtmC_MYAVZVPKlt6CccvB6m
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Outer-Sphere+Reactivity+Shift+of+Secondary+Phosphine+Oxide-Based+Nickel+Complexes%3A+From+Ethylene+Hydrophosphinylation+to+Oligomerization&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Lhermet%2C+Rudy&rft.au=Moser%2C+Emile&rft.au=Jeanneau%2C+Erwann&rft.au=Olivier-Bourbigou%2C+H%C3%A9l%C3%A8ne&rft.date=2017-06-01&rft.pub=Wiley-VCH+Verlag&rft.issn=0947-6539&rft.eissn=1521-3765&rft.volume=23&rft.issue=31&rft.spage=7433&rft.epage=7437&rft_id=info:doi/10.1002%2Fchem.201701414&rft.externalDBID=HAS_PDF_LINK&rft.externalDocID=oai_HAL_hal_01581820v1
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon