Selective One-Pot Access to Symmetrical or Unsymmetrical Diaryl Ethers by Copper-Catalyzed Double Arylation of a Simple Oxygen Source

Great CO‐mbination: A novel method is reported for the controlled one‐pot synthesis of various symmetrical or unsymmetrical diaryl ethers by double arylation of a simple inorganic oxygen source (see scheme). This versatile and highly selective process is based on the use of a cheap and low toxicity...

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Bibliographic Details
Published inChemistry : a European journal Vol. 16; no. 41; pp. 12299 - 12302
Main Authors Tlili, Anis, Monnier, Florian, Taillefer, Marc
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 02.11.2010
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
Wiley-VCH Verlag
Subjects
arylation
catalysis
Chemical Sciences
Chemistry
Chemistry, Multidisciplinary
copper
diaryl ethers
Organic chemistry
Physical Sciences
Science & Technology
selectivity
selectivity
C-O BOND
catalysis
arylation
NUCLEOPHILES
IODIDES
COUPLING REACTIONS
PHENOLS
VERSATILE
diaryl ethers
ARYL HALIDES
CHLORIDES
copper
LIGAND
EFFICIENT
homogeneous catalysis
CO coupling
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Summary:Great CO‐mbination: A novel method is reported for the controlled one‐pot synthesis of various symmetrical or unsymmetrical diaryl ethers by double arylation of a simple inorganic oxygen source (see scheme). This versatile and highly selective process is based on the use of a cheap and low toxicity copper catalytic system.
Bibliography:ArticleID:CHEM201001373
CNRS
istex:07840D4D63A5A12D1DB75D0D164D2B00CC2B4CAE
ANR
ark:/67375/WNG-KQT3467N-1
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201001373