Photoswitchable Conductivity in a Rigidly Dendronized Salt

Light switch: A dendronized salt exhibiting photoswitchable conductivity was designed and synthesized. The salt consists of tetrabutylammonium cations and large, rigidly dendronized borate anions, each bearing eight photoresponsive azobenzene moieties. The conductivity of solutions of this salt can...

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Published inAngewandte Chemie International Edition Vol. 52; no. 2; pp. 669 - 673
Main Authors Nguyen, Thi-Thanh-Tam, Türp, David, Wagner, Manfred, Müllen, Klaus
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 07.01.2013
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Anions
Bearing
Borates
Cations
Chemistry
Chemistry, Multidisciplinary
dendrimers
dendronized anions
Density
Irradiation
photoswitchable conductivity
Physical Sciences
Science & Technology
Switches
weakly coordinating anions
POLYMERS
dendrimers
borates
LIGHT
NANOCARRIERS
dendronized anions
photoswitchable conductivity
BRUSHES
DIARYLETHENE
AZOBENZENE
CONSTRUCTION
weakly coordinating anions
PH
DYNAMICS
POLYPHENYLENE DENDRIMERS
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Abstract Light switch: A dendronized salt exhibiting photoswitchable conductivity was designed and synthesized. The salt consists of tetrabutylammonium cations and large, rigidly dendronized borate anions, each bearing eight photoresponsive azobenzene moieties. The conductivity of solutions of this salt can be reversibly switched by irradiation, owing to light‐induced changes in the overall size of the dendronized anion and the density of its polyphenylene shell.
AbstractList Light switch: A dendronized salt exhibiting photoswitchable conductivity was designed and synthesized. The salt consists of tetrabutylammonium cations and large, rigidly dendronized borate anions, each bearing eight photoresponsive azobenzene moieties. The conductivity of solutions of this salt can be reversibly switched by irradiation, owing to light‐induced changes in the overall size of the dendronized anion and the density of its polyphenylene shell.
Author Wagner, Manfred
Nguyen, Thi-Thanh-Tam
Müllen, Klaus
Türp, David
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  email: muellen@mpip-mainz.mpg.de
  organization: Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz (Germany)
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Copyright Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
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Issue 2
Keywords POLYMERS
dendrimers
borates
LIGHT
NANOCARRIERS
dendronized anions
photoswitchable conductivity
BRUSHES
DIARYLETHENE
AZOBENZENE
CONSTRUCTION
weakly coordinating anions
PH
DYNAMICS
POLYPHENYLENE DENDRIMERS
Language English
License Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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These authors contributed equally to this work.
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Snippet Light switch: A dendronized salt exhibiting photoswitchable conductivity was designed and synthesized. The salt consists of tetrabutylammonium cations and...
Light switch: a dendronized salt exhibiting photoswitchable conductivity was designed and synthesized. The salt consists of tetrabutylammonium cations and...
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wiley
istex
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StartPage 669
SubjectTerms Anions
Bearing
Borates
Cations
Chemistry
Chemistry, Multidisciplinary
dendrimers
dendronized anions
Density
Irradiation
photoswitchable conductivity
Physical Sciences
Science & Technology
Switches
weakly coordinating anions
Title Photoswitchable Conductivity in a Rigidly Dendronized Salt
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https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201206010
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https://www.ncbi.nlm.nih.gov/pubmed/23192942
https://www.proquest.com/docview/1256877262
https://search.proquest.com/docview/1273114705
https://search.proquest.com/docview/1701053791
Volume 52
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