Light-enabled reversible self-assembly and tunable optical properties of stable hairy nanoparticles
The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and f...
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| Published in | Proceedings of the National Academy of Sciences - PNAS Vol. 115; no. 7; pp. E1391 - E1400 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
National Academy of Sciences
13.02.2018
|
| Series | PNAS Plus |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and functionalities. Here, we report an unconventional strategy for crafting stable hairy NPs with light-enabled reversible and reliable self-assembly and tunable optical properties. Central to our strategy is to judiciously design amphiphilic star-like diblock copolymers comprising inner hydrophilic blocks and outer hydrophobic photoresponsive blocks as nanoreactors to direct the synthesis of monodisperse plasmonic NPs intimately and permanently capped with photoresponsive polymers. The size and shape of hairy NPs can be precisely tailored by modulating the length of inner hydrophilic block of star-like diblock copolymers. The perpetual anchoring of photoresponsive polymers on the NP surface renders the attractive feature of self-assembly and disassembly of NPs on demand using light of different wavelengths, as revealed by tunable surface plasmon resonance absorption of NPs and the reversible transformation of NPs between their dispersed and aggregated states. The dye encapsulation/release studies manifested that such photoresponsive NPs may be exploited as smart guest molecule nanocarriers. By extension, the star-like block copolymer strategy enables the crafting of a family of stable stimuli-responsive NPs (e.g., temperature- or pH-sensitive polymer-capped magnetic, ferroelectric, upconversion, or semiconducting NPs) and their assemblies for fundamental research in self-assembly and crystallization kinetics of NPs as well as potential applications in optics, optoelectronics, magnetic technologies, sensory materials and devices, catalysis, nanotechnology, and biotechnology. |
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| AbstractList | The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and functionalities. Here, we report an unconventional strategy for crafting stable hairy NPs with light-enabled reversible and reliable self-assembly and tunable optical properties. Central to our strategy is to judiciously design amphiphilic star-like diblock copolymers comprising inner hydrophilic blocks and outer hydrophobic photoresponsive blocks as nanoreactors to direct the synthesis of monodisperse plasmonic NPs intimately and permanently capped with photoresponsive polymers. The size and shape of hairy NPs can be precisely tailored by modulating the length of inner hydrophilic block of star-like diblock copolymers. The perpetual anchoring of photoresponsive polymers on the NP surface renders the attractive feature of self-assembly and disassembly of NPs on demand using light of different wavelengths, as revealed by tunable surface plasmon resonance absorption of NPs and the reversible transformation of NPs between their dispersed and aggregated states. The dye encapsulation/release studies manifested that such photoresponsive NPs may be exploited as smart guest molecule nanocarriers. By extension, the star-like block copolymer strategy enables the crafting of a family of stable stimuli-responsive NPs (e.g., temperature- or pH-sensitive polymer-capped magnetic, ferroelectric, upconversion, or semiconducting NPs) and their assemblies for fundamental research in self-assembly and crystallization kinetics of NPs as well as potential applications in optics, optoelectronics, magnetic technologies, sensory materials and devices, catalysis, nanotechnology, and biotechnology. The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and functionalities. Here, we report an unconventional strategy for crafting stable hairy NPs with light-enabled reversible and reliable self-assembly and tunable optical properties. Central to our strategy is to judiciously design amphiphilic star-like diblock copolymers comprising inner hydrophilic blocks and outer hydrophobic photoresponsive blocks as nanoreactors to direct the synthesis of monodisperse plasmonic NPs intimately and permanently capped with photoresponsive polymers. The size and shape of hairy NPs can be precisely tailored by modulating the length of inner hydrophilic block of star-like diblock copolymers. The perpetual anchoring of photoresponsive polymers on the NP surface renders the attractive feature of self-assembly and disassembly of NPs on demand using light of different wavelengths, as revealed by tunable surface plasmon resonance absorption of NPs and the reversible transformation of NPs between their dispersed and aggregated states. The dye encapsulation/release studies manifested that such photoresponsive NPs may be exploited as smart guest molecule nanocarriers. By extension, the star-like block copolymer strategy enables the crafting of a family of stable stimuli-responsive NPs (e.g., temperature- or pH-sensitive polymer-capped magnetic, ferroelectric, upconversion, or semiconducting NPs) and their assemblies for fundamental research in self-assembly and crystallization kinetics of NPs as well as potential applications in optics, optoelectronics, magnetic technologies, sensory materials and devices, catalysis, nanotechnology, and biotechnology.The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and functionalities. Here, we report an unconventional strategy for crafting stable hairy NPs with light-enabled reversible and reliable self-assembly and tunable optical properties. Central to our strategy is to judiciously design amphiphilic star-like diblock copolymers comprising inner hydrophilic blocks and outer hydrophobic photoresponsive blocks as nanoreactors to direct the synthesis of monodisperse plasmonic NPs intimately and permanently capped with photoresponsive polymers. The size and shape of hairy NPs can be precisely tailored by modulating the length of inner hydrophilic block of star-like diblock copolymers. The perpetual anchoring of photoresponsive polymers on the NP surface renders the attractive feature of self-assembly and disassembly of NPs on demand using light of different wavelengths, as revealed by tunable surface plasmon resonance absorption of NPs and the reversible transformation of NPs between their dispersed and aggregated states. The dye encapsulation/release studies manifested that such photoresponsive NPs may be exploited as smart guest molecule nanocarriers. By extension, the star-like block copolymer strategy enables the crafting of a family of stable stimuli-responsive NPs (e.g., temperature- or pH-sensitive polymer-capped magnetic, ferroelectric, upconversion, or semiconducting NPs) and their assemblies for fundamental research in self-assembly and crystallization kinetics of NPs as well as potential applications in optics, optoelectronics, magnetic technologies, sensory materials and devices, catalysis, nanotechnology, and biotechnology. This work reports a versatile and robust strategy for creating monodisperse plasmonic nanoparticles (NPs) intimately and permanently capped with photoresponsive polymers via capitalizing on amphiphilic star-like diblock copolymer nanoreactors. The reversibly assembled nanostructures comprising photoresponsive NPs may exhibit a broad range of new attributes, functions, and applications as a direct consequence of size-dependent physical property from individual NP and the collective property originated from the NP interaction due to their close proximity within nanostructure. The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up important perspectives for rapid and convenient construction of a rich variety of complex assemblies and materials with new structures and functionalities. Here, we report an unconventional strategy for crafting stable hairy NPs with light-enabled reversible and reliable self-assembly and tunable optical properties. Central to our strategy is to judiciously design amphiphilic star-like diblock copolymers comprising inner hydrophilic blocks and outer hydrophobic photoresponsive blocks as nanoreactors to direct the synthesis of monodisperse plasmonic NPs intimately and permanently capped with photoresponsive polymers. The size and shape of hairy NPs can be precisely tailored by modulating the length of inner hydrophilic block of star-like diblock copolymers. The perpetual anchoring of photoresponsive polymers on the NP surface renders the attractive feature of self-assembly and disassembly of NPs on demand using light of different wavelengths, as revealed by tunable surface plasmon resonance absorption of NPs and the reversible transformation of NPs between their dispersed and aggregated states. The dye encapsulation/release studies manifested that such photoresponsive NPs may be exploited as smart guest molecule nanocarriers. By extension, the star-like block copolymer strategy enables the crafting of a family of stable stimuli-responsive NPs (e.g., temperature- or pH-sensitive polymer-capped magnetic, ferroelectric, upconversion, or semiconducting NPs) and their assemblies for fundamental research in self-assembly and crystallization kinetics of NPs as well as potential applications in optics, optoelectronics, magnetic technologies, sensory materials and devices, catalysis, nanotechnology, and biotechnology. |
| Author | Jung, Jaehan Lin, Zhiqun Chen, Yihuang Wang, Zewei Yoon, Young Jun Zhang, Guangzhao He, Yanjie |
| Author_xml | – sequence: 1 givenname: Yihuang surname: Chen fullname: Chen, Yihuang organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 – sequence: 2 givenname: Zewei surname: Wang fullname: Wang, Zewei organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 – sequence: 3 givenname: Yanjie surname: He fullname: He, Yanjie organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 – sequence: 4 givenname: Young Jun surname: Yoon fullname: Yoon, Young Jun organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 – sequence: 5 givenname: Jaehan surname: Jung fullname: Jung, Jaehan organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 – sequence: 6 givenname: Guangzhao surname: Zhang fullname: Zhang, Guangzhao organization: Faculty of Materials Science and Engineering, South China University of Technology, 510640 Guangzhou, China – sequence: 7 givenname: Zhiqun surname: Lin fullname: Lin, Zhiqun organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29386380$$D View this record in MEDLINE/PubMed |
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| ContentType | Journal Article |
| Copyright | Volumes 1–89 and 106–114, copyright as a collective work only; author(s) retains copyright to individual articles Copyright National Academy of Sciences Feb 13, 2018 2018 |
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| DocumentTitleAlternate | Light-enabled reversible assembly of nanoparticles |
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| Keywords | photoresponsive polymers nanoreactor stable hairy nanoparticles reversible self-assembly tunable optical properties |
| Language | English |
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| Notes | SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 14 ObjectType-Article-1 ObjectType-Feature-2 content type line 23 Author contributions: Y.C. and Z.L. designed research; Y.C., Z.W., Y.H., Y.J.Y., and J.J. performed research; Y.C., Z.W., Y.H., Y.J.Y., J.J., G.Z., and Z.L. analyzed data; and Y.C., G.Z., and Z.L. wrote the paper. Edited by Steve Granick, IBS Center for Soft and Living Matter, Uvalju-gun, Ulsan, Republic of Korea, and approved January 5, 2018 (received for review August 20, 2017) |
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| Snippet | The ability to dynamically organize functional nanoparticles (NPs) via the use of environmental triggers (temperature, pH, light, or solvent polarity) opens up... This work reports a versatile and robust strategy for creating monodisperse plasmonic nanoparticles (NPs) intimately and permanently capped with... |
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| SubjectTerms | Anchoring Assemblies Biotechnology Block copolymers Catalysis Chemical synthesis Copolymers Crystallization Dismantling Ferroelectric materials Ferroelectricity Hydrophobicity Magnetic resonance Nanoparticles Nanotechnology Optical properties Optics Optoelectronics pH effects Physical Sciences PNAS Plus Polarity Polymers Reaction kinetics Resonance absorption Self-assembly Strategy Surface plasmon resonance Upconversion Wavelengths |
| Title | Light-enabled reversible self-assembly and tunable optical properties of stable hairy nanoparticles |
| URI | https://www.jstor.org/stable/26507374 https://www.ncbi.nlm.nih.gov/pubmed/29386380 https://www.proquest.com/docview/2011289099 https://www.proquest.com/docview/1993382732 https://pubmed.ncbi.nlm.nih.gov/PMC5816163 |
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