Temperature sensing using junctions between mobile ions and mobile electrons

• Published in: Proceedings of the National Academy of Sciences - PNAS Vol. 119; no. 4; pp. 1 - 6
• Main Authors: Wang, Yecheng, Jia, Kun, Zhang, Shuwen, Kim, Hyeong Jun, Bai, Yang, Hayward, Ryan C., Suo, Zhigang
• Format: Journal Article
• Language: English
• Published: United States National Academy of Sciences 25.01.2022
• Subjects: Dielectrics; Electrodes; Electrolytes; Electrons; Interfaces; Ions; Open circuit voltage; Physical Sciences; Sensors; Temperature sensors; self-powered thermometer; hydrogel; nonfaradaic interface; stretchable electronics; ionotronics
• DOI: 10.1073/pnas.2117962119
• ISSN: 0027-8424; 1091-6490

Sensing technology is under intense development to enable the Internet of everything and everyone in new and useful ways. Here we demonstrate a method of stretchable and self-powered temperature sensing. The basic sensing element consists of three layers: an electrolyte, a dielectric, and an electrode. The electrolyte/dielectric interface accumulates ions, and the dielectric/electrode interface accumulates electrons (in either excess or deficiency). The ions and electrons at the two interfaces are usually not charge-neutral, and this charge imbalance sets up an ionic cloud in the electrolyte. The design functions as a charged temperature-sensitive capacitor. When temperature changes, the ionic cloud changes thickness, and the electrode changes open-circuit voltage. We demonstrate high sensitivity (∼1 mV/K) and fast response (∼10 ms). Such temperature sensors can be made small, stable, and transparent. Depending on the arrangement of the electrolyte, dielectric, and electrode, we develop four designs for the temperature sensor. In addition, the temperature sensor has good linearity in the range of tens of Kelvin. We further show that the temperature sensors can be integrated into stretchable electronics and soft robots.