Accurate Nanoscale Crystallography in Real-Space Using Scanning Transmission Electron Microscopy

Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by removing drift and residual scan distortion. We demonstrate real-space lattice parameter measurements with <0.1% error for complex-layered...

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Published inMicroscopy and microanalysis Vol. 21; no. 4; pp. 946 - 952
Main Authors Dycus, J. Houston, Harris, Joshua S., Sang, Xiahan, Fancher, Chris M., Findlay, Scott D., Oni, Adedapo A., Chan, Tsung-ta E., Koch, Carl C., Jones, Jacob L., Allen, Leslie J., Irving, Douglas L., LeBeau, James M.
Format Journal Article
LanguageEnglish
Published New York, USA Cambridge University Press 01.08.2015
Oxford University Press
Microscopy Society of America (MSA)
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Abstract Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by removing drift and residual scan distortion. We demonstrate real-space lattice parameter measurements with <0.1% error for complex-layered chalcogenides Bi2Te3, Bi2Se3, and a Bi2Te2.7Se0.3 nanostructured alloy. Pairing the technique with atomic resolution spectroscopy, we connect local structure with chemistry and bonding. Combining these results with density functional theory, we show that the incorporation of Se into Bi2Te3 causes charge redistribution that anomalously increases the van der Waals gap between building blocks of the layered structure. The results show that atomic resolution imaging with electrons can accurately and robustly quantify crystallography at the nanoscale.
AbstractList Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by removing drift and residual scan distortion. We demonstrate real-space lattice parameter measurements with <0.1% error for complex-layered chalcogenides Bi2Te3, Bi2Se3, and a Bi2Te2.7Se0.3 nanostructured alloy. Pairing the technique with atomic resolution spectroscopy, we connect local structure with chemistry and bonding. Combining these results with density functional theory, we show that the incorporation of Se into Bi2Te3 causes charge redistribution that anomalously increases the van der Waals gap between building blocks of the layered structure. The results show that atomic resolution imaging with electrons can accurately and robustly quantify crystallography at the nanoscale.
Abstract Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by removing drift and residual scan distortion. We demonstrate real-space lattice parameter measurements with <0.1% error for complex-layered chalcogenides Bi 2 Te 3 , Bi 2 Se 3 , and a Bi 2 Te 2.7 Se 0.3 nanostructured alloy. Pairing the technique with atomic resolution spectroscopy, we connect local structure with chemistry and bonding. Combining these results with density functional theory, we show that the incorporation of Se into Bi 2 Te 3 causes charge redistribution that anomalously increases the van der Waals gap between building blocks of the layered structure. The results show that atomic resolution imaging with electrons can accurately and robustly quantify crystallography at the nanoscale.
Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by removing drift and residual scan distortion. We demonstrate real-space lattice parameter measurements with &lt;0.1% error for complex-layered chalcogenides Bi2Te3, Bi2Se3, and a Bi2Te2.7Se0.3 nanostructured alloy. Pairing the technique with atomic resolution spectroscopy, we connect local structure with chemistry and bonding. Combining these results with density functional theory, we show that the incorporation of Se into Bi2Te3 causes charge redistribution that anomalously increases the van der Waals gap between building blocks of the layered structure. The results show that atomic resolution imaging with electrons can accurately and robustly quantify crystallography at the nanoscale.
Author Dycus, J. Houston
Sang, Xiahan
Findlay, Scott D.
Oni, Adedapo A.
Chan, Tsung-ta E.
Harris, Joshua S.
Fancher, Chris M.
Irving, Douglas L.
LeBeau, James M.
Allen, Leslie J.
Jones, Jacob L.
Koch, Carl C.
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  surname: LeBeau
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  email: jmlebeau@ncsu.edu
  organization: Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695, USA
BackLink https://www.ncbi.nlm.nih.gov/pubmed/26169835$$D View this record in MEDLINE/PubMed
https://www.osti.gov/biblio/1225090$$D View this record in Osti.gov
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Keywords Bi2Te3
scanning transmission electron microscopy
atomic resolution spectroscopy
nanoscale metrology
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Snippet Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made possible by...
Abstract Here, we report reproducible and accurate measurement of crystallographic parameters using scanning transmission electron microscopy. This is made...
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SubjectTerms Accuracy
Alloys
Calibration
Crystal structure
Crystallography
Materials Applications and Techniques
Software
Transmission electron microscopy
X-rays
Title Accurate Nanoscale Crystallography in Real-Space Using Scanning Transmission Electron Microscopy
URI https://www.cambridge.org/core/product/identifier/S1431927615013732/type/journal_article
https://www.ncbi.nlm.nih.gov/pubmed/26169835
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https://search.proquest.com/docview/1730020886
https://www.osti.gov/biblio/1225090
Volume 21
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