Supramolecular Polymerization Triggered by Molecular Recognition between Bisporphyrin and Trinitrofluorenone

Networking: A bisporphyrin compound possessing an electron‐deficient guest moiety assembles in a head‐to‐tail manner to form polymeric aggregates. Diffusion‐ordered NMR spectroscopy and viscosity measurements of the aggregates confirmed the formation of sizable supramolecular polymers. Widely spread...

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Published inAngewandte Chemie International Edition Vol. 51; no. 6; pp. 1473 - 1476
Main Authors Haino, Takeharu, Watanabe, Akihide, Hirao, Takehiro, Ikeda, Toshiaki
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 06.02.2012
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Aggregates
charge transfer
Chemistry
Chemistry, Multidisciplinary
Diffusion
Formations
host-guest systems
molecular recognition
Nanostructure
NMR spectroscopy
Physical Sciences
porphyrins
Recognition
Science & Technology
Solid state
Spreads
supramolecular chemistry
Viscosity measurement
MONOMERS
host-guest systems
GUEST
COORDINATION
COPOLYMERS
NETWORKS
PORES
charge transfer
porphyrins
ORGANIZATION
REVERSIBLE POLYMERS
molecular recognition
supramolecular chemistry
WATER
Online AccessGet full text

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Abstract Networking: A bisporphyrin compound possessing an electron‐deficient guest moiety assembles in a head‐to‐tail manner to form polymeric aggregates. Diffusion‐ordered NMR spectroscopy and viscosity measurements of the aggregates confirmed the formation of sizable supramolecular polymers. Widely spread nanonetworks (see picture) are formed in solid state.
AbstractList Networking: A bisporphyrin compound possessing an electron‐deficient guest moiety assembles in a head‐to‐tail manner to form polymeric aggregates. Diffusion‐ordered NMR spectroscopy and viscosity measurements of the aggregates confirmed the formation of sizable supramolecular polymers. Widely spread nanonetworks (see picture) are formed in solid state.
Author Hirao, Takehiro
Watanabe, Akihide
Ikeda, Toshiaki
Haino, Takeharu
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  surname: Haino
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  givenname: Akihide
  surname: Watanabe
  fullname: Watanabe, Akihide
  organization: Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)
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  givenname: Takehiro
  surname: Hirao
  fullname: Hirao, Takehiro
  organization: Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)
– sequence: 4
  givenname: Toshiaki
  surname: Ikeda
  fullname: Ikeda, Toshiaki
  organization: Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)
BackLink https://www.ncbi.nlm.nih.gov/pubmed/22294360$$D View this record in MEDLINE/PubMed
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Issue 6
Keywords MONOMERS
host-guest systems
GUEST
COORDINATION
COPOLYMERS
NETWORKS
PORES
charge transfer
porphyrins
ORGANIZATION
REVERSIBLE POLYMERS
molecular recognition
supramolecular chemistry
WATER
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Notes Electric Technology Research Foundation of Chugoku - No. 21350066; No. 23655105
We are grateful to Prof. Dr. Shin-ichi Kihara at the department of chemical engineering, graduate school of engineering, Hiroshima University for helpful discussions about solution rheology. This work is supported by the JSPS (Japan), the Yamada Science Foundation, and the Electric Technology Research Foundation of Chugoku through grant-in-aids for scientific research (B; grant number 21350066) and the challenging exploratory research (grant number 23655105).
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We are grateful to Prof. Dr. Shin‐ichi Kihara at the department of chemical engineering, graduate school of engineering, Hiroshima University for helpful discussions about solution rheology. This work is supported by the JSPS (Japan), the Yamada Science Foundation, and the Electric Technology Research Foundation of Chugoku through grant‐in‐aids for scientific research (B; grant number 21350066) and the challenging exploratory research (grant number 23655105).
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Snippet Networking: A bisporphyrin compound possessing an electron‐deficient guest moiety assembles in a head‐to‐tail manner to form polymeric aggregates....
Networking: A bisporphyrin compound possessing an electron-deficient guest moiety assembles in a head-to-tail manner to form polymeric aggregates....
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SubjectTerms Aggregates
charge transfer
Chemistry
Chemistry, Multidisciplinary
Diffusion
Formations
host-guest systems
molecular recognition
Nanostructure
NMR spectroscopy
Physical Sciences
porphyrins
Recognition
Science & Technology
Solid state
Spreads
supramolecular chemistry
Viscosity measurement
Title Supramolecular Polymerization Triggered by Molecular Recognition between Bisporphyrin and Trinitrofluorenone
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https://search.proquest.com/docview/1701123384
https://search.proquest.com/docview/919649264
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