Modular, Homochiral, Porous Coordination Polymers: Rational Design, Enantioselective Guest Exchange Sorption and Ab Initio Calculations of Host-Guest Interactions

• Published in: Chemistry : a European journal Vol. 16; no. 34; pp. 10348 - 10356
• Main Authors: Dybtsev, Danil N., Yutkin, Maxim P., Samsonenko, Denis G., Fedin, Vladimir P., Nuzhdin, Alexey L., Bezrukov, Andrey A., Bryliakov, Konstantin P., Talsi, Evgeniy P., Belosludov, Rodion V., Mizuseki, Hiroshi, Kawazoe, Yoshiyuki, Subbotin, Oleg S., Belosludov, Vladimir R.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 10.09.2010; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Chemistry; chirality; Coordination polymers; Crystals; density functional calculations; Dimethylformamide - chemistry; Drugs; Exchange; Heating; Hydrogen Bonding; Mathematical models; metal-organic frameworks; Models, Molecular; Modular; Molecular Structure; Organometallic Compounds - chemistry; Polymers; Polymers - chemistry; Porosity; porous materials; Quantum Theory; Sorption; Stereoisomerism; X-Ray Diffraction; Zinc - chemistry

Two new, homochiral, porous metal–organic coordination polymers [Zn2(ndc){(R)‐man}(dmf)]⋅3DMF and [Zn2(bpdc){(R)‐man}(dmf)]⋅2DMF (ndc=2,6‐naphthalenedicarboxylate; bpdc=4,4′‐biphenyldicarboxylate; man=mandelate; dmf=N,N′‐dimethylformamide) have been synthesized by heating ZnII nitrate, H2ndc or H2bp...