Ion-Exchange Loading of Yttrium Acetate as a Sintering Aid on Aluminum Nitride Powder via Aqueous Processing
A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN powder in water was improved by the surface chemical modification with sebacic acid, while maintaining a hydrophilic surface. The treatment of the...
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Published in | Journal of the American Ceramic Society Vol. 83; no. 11; pp. 2793 - 2797 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Westerville, Ohio
American Ceramics Society
01.11.2000
Blackwell Wiley Subscription Services, Inc |
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Abstract | A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN powder in water was improved by the surface chemical modification with sebacic acid, while maintaining a hydrophilic surface. The treatment of the sebacic acid‐modified powder with yttrium acetate tetrahydrate resulted in strong immobilization of Y3+ ions, as a sintering aid, at a highly dispersive level on the AlN powder surface through ion exchange with the free carboxyl groups of the sebacic acid molecules attached to the AlN surface. By selecting slip compositions for a well‐deflocculated condition and firing conditions to burn out organic components in the slip cast compacts, a thermal conductivity of about 250 W/(m·K) could be attained by the pressureless sintering at 1900°C for 5 h. |
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AbstractList | A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN powder in water was improved by the surface chemical modification with sebacic acid, while maintaining a hydrophilic surface. The treatment of the sebacic acid‐modified powder with yttrium acetate tetrahydrate resulted in strong immobilization of Y3+ ions, as a sintering aid, at a highly dispersive level on the AlN powder surface through ion exchange with the free carboxyl groups of the sebacic acid molecules attached to the AlN surface. By selecting slip compositions for a well‐deflocculated condition and firing conditions to burn out organic components in the slip cast compacts, a thermal conductivity of about 250 W/(m·K) could be attained by the pressureless sintering at 1900°C for 5 h. A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN powder in water was improved by the surface chemical modification with sebacic acid, while maintaining a hydrophilic surface. The treatment of the sebacic acid‐modified powder with yttrium acetate tetrahydrate resulted in strong immobilization of Y 3+ ions, as a sintering aid, at a highly dispersive level on the AlN powder surface through ion exchange with the free carboxyl groups of the sebacic acid molecules attached to the AlN surface. By selecting slip compositions for a well‐deflocculated condition and firing conditions to burn out organic components in the slip cast compacts, a thermal conductivity of about 250 W/(m·K) could be attained by the pressureless sintering at 1900°C for 5 h. A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN powder in water was improved by the surface chemical modification with sebacic acid, while maintaining a hydrophilic surface. The treatment of the sebacic acid-modified powder with yttrium acetate tetrahydrate resulted in strong immobilization of Y exp 3+ ions, as a sintering aid, at a highly dispersive level on the AlN powder surface through ion exchange with the free carboxyl groups of the sebacic acid molecules attached to the AlN surface. By selecting slip compositions for a well-deflocculated condition and firing conditions to burn out organic components in the slip cast compacts, a thermal conductivity of approx250 W/(mK) could be attained by the pressureless sintering at 1900 deg C for 5 h. |
Author | Egashira, Makoto Hyodo, Takeo Hatano, Jun Shimizu, Yasuhiro |
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Keywords | Slip casting Particle suspension Experimental study Powder Non oxide ceramics Thermal properties Aluminium Nitrides Additive Sintering Thermal conductivity Manufacturing Ion exchange Microstructure Aqueous dispersion |
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Notes | istex:15CF3ADB1B11B1BD99F06337931A9B01678B090A ArticleID:JACE2793 ark:/67375/WNG-4CX40X71-C R. W. Rice—contributing editor Partly supported by a Grant‐in‐Aid for Scientific Research (B) (No. 1055219) from the Ministry of Education, Science, Sports and Culture of Japan. Member, American Ceramic Society. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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Snippet | A novel fabrication process of AlN ceramics via aqueous colloidal processing and pressureless sintering has been presented. The chemical stability of AlN... |
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SubjectTerms | aluminum nitride Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Exact sciences and technology Miscellaneous sintering Technical ceramics yttrium |
Title | Ion-Exchange Loading of Yttrium Acetate as a Sintering Aid on Aluminum Nitride Powder via Aqueous Processing |
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