A sound velocity method for determining isobaric specific heat capacity
Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large...
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| Published in | InfoMat Vol. 4; no. 12 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
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John Wiley & Sons, Inc
01.12.2022
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| Abstract | Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine Cp by measuring the sound velocity (υ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated Cp at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value.
Specific heat capacity can be accurately measured even at elevated temperature by a simple and easy‐to‐implement sound velocity method. |
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| AbstractList | Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine Cp by measuring the sound velocity (υ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated Cp at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value.
Specific heat capacity can be accurately measured even at elevated temperature by a simple and easy‐to‐implement sound velocity method. Abstract Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine Cp by measuring the sound velocity (υ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated Cp at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value. Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine Cp by measuring the sound velocity (υ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated Cp at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value. Isobaric specific heat capacity ( C p ) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine C p by measuring the sound velocity ( υ ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated C p at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value. image |
| Author | Pei, Jun Li, Hezhang Cai, Bowen Jiang, Yilin Li, Jing‐Wei Su, Bin Dong, Jinfeng Li, Jing‐Feng Hu, Haihua Zhao, Li‐Dong Zhuang, Hua‐Lu |
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| Snippet | Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly... Isobaric specific heat capacity ( C p ) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly... Abstract Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is... |
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| SubjectTerms | Accuracy Acoustic velocity Heat heat capacity High temperature Hot pressing Lasers Lattice vibration Performance evaluation Plasma sintering sound velocity Specific heat Standard error Temperature thermoelectric Thermoelectric materials Velocity Vibration measurement |
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| Title | A sound velocity method for determining isobaric specific heat capacity |
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