Hydrolysis of zeolite framework aluminum and its impact on acid catalyzed alkane reactions
[Display omitted] •Mild steaming leads to partially framework-bound aluminum oxide species.•These aluminum oxide clusters are in the vicinity of Brønsted acid sites.•Site proximity leads to an increase of activation entropies for alkane cracking.•n-Butane cracking and D2/OH exchange reaction rates a...
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| Published in | Journal of catalysis Vol. 365; pp. 359 - 366 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Inc
01.09.2018
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| Abstract | [Display omitted]
•Mild steaming leads to partially framework-bound aluminum oxide species.•These aluminum oxide clusters are in the vicinity of Brønsted acid sites.•Site proximity leads to an increase of activation entropies for alkane cracking.•n-Butane cracking and D2/OH exchange reaction rates are also enhanced.
Short exposure of HZSM-5 zeolites to water vapor at high temperatures (mild steaming) enhances the rates of alkane cracking and dehydrogenation as well as the rates of exchange between H2 and D2. Solid state 27Al MAS NMR results show that mild steaming leads to metastable aluminum oxide species, hypothesized to be partially framework-bound. Combining double quantum magic-angle spinning nuclear magnetic resonance experiments and kinetic analysis of cracking reactions allows us to conclude that the presence of these aluminum oxide clusters in the vicinity of Brønsted acid sites leads to an increase in the activation entropies during alkane cracking, induced by increasing steric constraints. Prolonged steaming results, in contrast, in the extraction of framework Al, which subsequently forms aggregated extra-framework Al oxide species partly blocking Brønsted acid sites and partly deposited at the outer surface of the crystallites. |
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| AbstractList | Short exposure of HZSM-5 zeolites to water vapor at high temperatures (mild steaming) enhances the rates of alkane cracking and dehydrogenation as well as the rates of exchange between H₂ and D₂. Solid state ²⁷Al MAS NMR results show that mild steaming leads to metastable aluminum oxide species, hypothesized to be partially framework-bound. Combining double quantum magic-angle spinning nuclear magnetic resonance experiments and kinetic analysis of cracking reactions allows us to conclude that the presence of these aluminum oxide clusters in the vicinity of Brønsted acid sites leads to an increase in the activation entropies during alkane cracking, induced by increasing steric constraints. Prolonged steaming results, in contrast, in the extraction of framework Al, which subsequently forms aggregated extra-framework Al oxide species partly blocking Brønsted acid sites and partly deposited at the outer surface of the crystallites. [Display omitted] •Mild steaming leads to partially framework-bound aluminum oxide species.•These aluminum oxide clusters are in the vicinity of Brønsted acid sites.•Site proximity leads to an increase of activation entropies for alkane cracking.•n-Butane cracking and D2/OH exchange reaction rates are also enhanced. Short exposure of HZSM-5 zeolites to water vapor at high temperatures (mild steaming) enhances the rates of alkane cracking and dehydrogenation as well as the rates of exchange between H2 and D2. Solid state 27Al MAS NMR results show that mild steaming leads to metastable aluminum oxide species, hypothesized to be partially framework-bound. Combining double quantum magic-angle spinning nuclear magnetic resonance experiments and kinetic analysis of cracking reactions allows us to conclude that the presence of these aluminum oxide clusters in the vicinity of Brønsted acid sites leads to an increase in the activation entropies during alkane cracking, induced by increasing steric constraints. Prolonged steaming results, in contrast, in the extraction of framework Al, which subsequently forms aggregated extra-framework Al oxide species partly blocking Brønsted acid sites and partly deposited at the outer surface of the crystallites. |
| Author | Xue, Nianhua Mei, Donghai Lercher, Johannes A. Schallmoser, Stefan Fulton, John L. Hu, Jian Zhi Sanchez-Sanchez, Maricruz Vjunov, Aleksei |
| Author_xml | – sequence: 1 givenname: Nianhua surname: Xue fullname: Xue, Nianhua organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States – sequence: 2 givenname: Aleksei surname: Vjunov fullname: Vjunov, Aleksei organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States – sequence: 3 givenname: Stefan surname: Schallmoser fullname: Schallmoser, Stefan organization: Department of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany – sequence: 4 givenname: John L. surname: Fulton fullname: Fulton, John L. organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States – sequence: 5 givenname: Maricruz surname: Sanchez-Sanchez fullname: Sanchez-Sanchez, Maricruz organization: Department of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany – sequence: 6 givenname: Jian Zhi surname: Hu fullname: Hu, Jian Zhi organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States – sequence: 7 givenname: Donghai surname: Mei fullname: Mei, Donghai organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States – sequence: 8 givenname: Johannes A. surname: Lercher fullname: Lercher, Johannes A. email: Johannes.lercher@ch.tum.de organization: Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, United States |
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| Cites_doi | 10.1107/S0909049500016964 10.1021/ja4081937 10.1007/BF02068204 10.1039/b508358c 10.2138/am-1995-5-602 10.1016/j.jcat.2014.05.022 10.1016/j.cattod.2011.09.028 10.1023/A:1019155832086 10.1006/jmra.1996.0197 10.1021/jp509982r 10.1016/j.jcat.2013.07.021 10.1021/jp106621d 10.1016/j.jcat.2014.05.004 10.1016/0144-2449(91)80406-P 10.1006/jcat.1994.1203 10.1016/S0926-860X(98)00120-3 10.1021/ja501361v 10.1016/0927-7757(93)80399-Y 10.1016/0144-2449(93)90025-X 10.1021/jp106536m 10.1063/1.1680061 10.1021/cs501474u 10.1016/0144-2449(94)90146-5 10.1021/j100248a020 10.1021/j100126a004 10.1021/ja072767y 10.1016/0021-9517(92)90273-K 10.1021/j100068a027 10.1016/S0144-2449(82)80042-0 10.1007/BF02071200 10.1021/j150545a009 10.1021/cr00007a013 10.1006/jcat.2001.3265 10.1016/S0926-860X(98)00264-6 10.1006/jcat.1995.1304 10.1002/anie.200702628 10.1016/j.jcat.2007.02.022 10.1016/S0926-860X(98)00301-9 10.1002/anie.200905869 10.1016/j.apcata.2009.04.013 10.1107/S0909049505012719 10.1021/ja00407a002 10.1515/zpch-1985-26636 10.1016/0144-2449(85)90012-0 |
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| References | Babitz, Williams, Miller, Snurr, Haag, Kung (b0010) 1999; 179 Li, Bancroft, Fleet, Feng, Pan (b0225) 1995; 80 Zholobenko, Kustov, Kazansky, Loeffler, Lohse, Oehlmann (b0035) 1991; 11 Janda, Bell (b0120) 2013; 135 Krannila, Haag, Gates (b0230) 1992; 135 Xue, Chen, Nie, Guo, Ding, Chen, Gu, Xie (b0145) 2007; 248 Feike, Demco, Graf, Gottwald, Hafner, Spiess (b0090) 1996; 122 Niwa, Sota, Katada (b0015) 2012; 185 Sklenak, Dedecek, Li, Wichterlova, Gabova, Sierka, Sauer (b0210) 2007; 46 Masuda, Fujikata, Mukai, Hashimoto (b0075) 1998; 172 Williams, Babitz, Miller, Snurr, Kung (b0030) 1999; 177 Silva, Ribeiro, Ribeiro, Gnep, Guisnet, Benazzi (b0125) 1995; 54 Gounder, Iglesia (b0135) 2010; 49 To, Jentoft, Alvarez, Crossley, Resasco (b0065) 2014; 317 Xue, Olindo, Lercher (b0085) 2010; 114 Zhao, Xu, Hu, Bao, Peden, Hu (b0215) 2015; 119 Makarova, Dwyer (b0070) 1993; 97 Narbeshuber, Vinek, Lercher (b0115) 1995; 157 Almutairi, Mezari, Pidko, Magusin, Hensen (b0060) 2013; 307 Weller, Hindin (b0155) 1956; 60 Fyfe, Feng, Grondey, Kokotailo, Gies (b0170) 1991; 91 Lippmaa, Samoson, Brei, Gorlov (b0195) 1981; 259 van Bokhoven, Tromp, Koningsberger, Miller, Pieterse, Lercher, Williams, Kung (b0020) 2001; 202 Jiao, Kanellopoulos, Wang, Ray, Foerster, Freude, Hunger (b0095) 2005; 7 Silaghi, Chizallet, Petracovschi, Kerber, Sauer, Raybaud (b0080) 2015; 5 Zhu, Wang, Cheng, Chen, Zhan (b0025) 2009; 362 Schallmoser, Ikuno, Wagenhofer, Kolvenbach, Haller, Sanchez-Sanchez, Lercher (b0050) 2014; 316 Kung, Williams, Babitz, Miller, Haag, Snurr (b0005) 2000; 10 Zholobenko, Kustov, Kazansky, Loeffler, Lohser, Peuker, Oehlmann (b0040) 1990; 10 Li, Zheng, Su, Zhang, Chen, Yang, Ye, Deng (b0220) 2007; 129 Zhuravlev (b0190) 1993; 74 Fyfe, Gobbi, Kennedy (b0200) 1985; 89 Biaglow, Parrillo, Kokotailo, Gorte (b0045) 1994; 148 Lukyanov (b0055) 1993; 13 Ravel, Newville (b0100) 2005; 12 Engelhardt, Fahlke, Mägi, Lippmaa (b0175) 1985; 5 Lippmaa, Magi, Samoson, Tarmak, Engelhardt (b0160) 1981; 103 Engelhardt, Fahlke, Mägi, Lippmaa (b0165) 1985 Vjunov, Fulton, Huthwelker, Pin, Mei, Schenter, Govind, Camaioni, Hu, Lercher (b0110) 2014; 136 De Moor, Reyniers, Gobin, Lercher, Marin (b0130) 2011; 115 Pines, Gibby, Waugh (b0205) 1973; 59 Engelhardt, Lohse, Samoson, Magi, Tarmak, Lippmaa (b0185) 1982; 2 Novakova, Kubelkova, Jiru (b0140) 1975; 2 Newville (b0105) 2001; 8 Nováková, Kubelková, Jir (b0150) 1975; 2 Burkett, Davis (b0180) 1994; 98 Silaghi (10.1016/j.jcat.2018.07.015_b0080) 2015; 5 Newville (10.1016/j.jcat.2018.07.015_b0105) 2001; 8 Engelhardt (10.1016/j.jcat.2018.07.015_b0165) 1985 van Bokhoven (10.1016/j.jcat.2018.07.015_b0020) 2001; 202 Krannila (10.1016/j.jcat.2018.07.015_b0230) 1992; 135 Jiao (10.1016/j.jcat.2018.07.015_b0095) 2005; 7 Vjunov (10.1016/j.jcat.2018.07.015_b0110) 2014; 136 Zhu (10.1016/j.jcat.2018.07.015_b0025) 2009; 362 Zhuravlev (10.1016/j.jcat.2018.07.015_b0190) 1993; 74 Babitz (10.1016/j.jcat.2018.07.015_b0010) 1999; 179 Masuda (10.1016/j.jcat.2018.07.015_b0075) 1998; 172 Li (10.1016/j.jcat.2018.07.015_b0220) 2007; 129 Williams (10.1016/j.jcat.2018.07.015_b0030) 1999; 177 Sklenak (10.1016/j.jcat.2018.07.015_b0210) 2007; 46 Nováková (10.1016/j.jcat.2018.07.015_b0150) 1975; 2 Silva (10.1016/j.jcat.2018.07.015_b0125) 1995; 54 Pines (10.1016/j.jcat.2018.07.015_b0205) 1973; 59 Biaglow (10.1016/j.jcat.2018.07.015_b0045) 1994; 148 Zhao (10.1016/j.jcat.2018.07.015_b0215) 2015; 119 Fyfe (10.1016/j.jcat.2018.07.015_b0170) 1991; 91 Janda (10.1016/j.jcat.2018.07.015_b0120) 2013; 135 Kung (10.1016/j.jcat.2018.07.015_b0005) 2000; 10 Almutairi (10.1016/j.jcat.2018.07.015_b0060) 2013; 307 Xue (10.1016/j.jcat.2018.07.015_b0145) 2007; 248 Schallmoser (10.1016/j.jcat.2018.07.015_b0050) 2014; 316 Engelhardt (10.1016/j.jcat.2018.07.015_b0185) 1982; 2 Makarova (10.1016/j.jcat.2018.07.015_b0070) 1993; 97 Engelhardt (10.1016/j.jcat.2018.07.015_b0175) 1985; 5 Li (10.1016/j.jcat.2018.07.015_b0225) 1995; 80 Lukyanov (10.1016/j.jcat.2018.07.015_b0055) 1993; 13 Ravel (10.1016/j.jcat.2018.07.015_b0100) 2005; 12 Burkett (10.1016/j.jcat.2018.07.015_b0180) 1994; 98 Niwa (10.1016/j.jcat.2018.07.015_b0015) 2012; 185 Novakova (10.1016/j.jcat.2018.07.015_b0140) 1975; 2 Gounder (10.1016/j.jcat.2018.07.015_b0135) 2010; 49 Narbeshuber (10.1016/j.jcat.2018.07.015_b0115) 1995; 157 Weller (10.1016/j.jcat.2018.07.015_b0155) 1956; 60 Fyfe (10.1016/j.jcat.2018.07.015_b0200) 1985; 89 Zholobenko (10.1016/j.jcat.2018.07.015_b0035) 1991; 11 Xue (10.1016/j.jcat.2018.07.015_b0085) 2010; 114 To (10.1016/j.jcat.2018.07.015_b0065) 2014; 317 Zholobenko (10.1016/j.jcat.2018.07.015_b0040) 1990; 10 Lippmaa (10.1016/j.jcat.2018.07.015_b0195) 1981; 259 Feike (10.1016/j.jcat.2018.07.015_b0090) 1996; 122 De Moor (10.1016/j.jcat.2018.07.015_b0130) 2011; 115 Lippmaa (10.1016/j.jcat.2018.07.015_b0160) 1981; 103 |
| References_xml | – start-page: 239 year: 1985 ident: b0165 publication-title: Zeitschrift für Physikalische Chemie – volume: 5 start-page: 11 year: 2015 end-page: 15 ident: b0080 publication-title: ACS Catal. – volume: 60 start-page: 1506 year: 1956 end-page: 1512 ident: b0155 publication-title: J. Phys. Chem. – volume: 119 start-page: 1410 year: 2015 end-page: 1417 ident: b0215 publication-title: J. Phys. Chem. C – volume: 49 start-page: 808 year: 2010 end-page: 811 ident: b0135 publication-title: Angew. Chem.-Int. Ed. – volume: 7 start-page: 3221 year: 2005 end-page: 3226 ident: b0095 publication-title: PCCP – volume: 135 start-page: 115 year: 1992 end-page: 124 ident: b0230 publication-title: J. Catal. – volume: 157 start-page: 388 year: 1995 end-page: 395 ident: b0115 publication-title: J. Catal. – volume: 98 start-page: 4647 year: 1994 end-page: 4653 ident: b0180 publication-title: J. Phys. Chem. – volume: 103 start-page: 4992 year: 1981 end-page: 4996 ident: b0160 publication-title: J. Am. Chem. Soc. – volume: 59 start-page: 569 year: 1973 end-page: 590 ident: b0205 publication-title: J. Chem. Phys. – volume: 316 start-page: 93 year: 2014 end-page: 102 ident: b0050 publication-title: J. Catal. – volume: 2 start-page: 297 year: 1975 end-page: 303 ident: b0150 publication-title: React. Kinet. Catal. Lett. – volume: 2 start-page: 297 year: 1975 end-page: 303 ident: b0140 publication-title: React. Kinet. Catal. Lett. – volume: 80 start-page: 432 year: 1995 end-page: 440 ident: b0225 publication-title: Am. Mineral. – volume: 10 start-page: 59 year: 2000 end-page: 64 ident: b0005 publication-title: Top. Catal. – volume: 74 start-page: 71 year: 1993 end-page: 90 ident: b0190 publication-title: Colloids Surf. A-Physicochem. Eng. Asp. – volume: 13 start-page: 64 year: 1993 end-page: 66 ident: b0055 publication-title: Zeolites – volume: 148 start-page: 213 year: 1994 end-page: 223 ident: b0045 publication-title: J. Catal. – volume: 248 start-page: 20 year: 2007 end-page: 28 ident: b0145 publication-title: J. Catal. – volume: 179 start-page: 71 year: 1999 end-page: 86 ident: b0010 publication-title: Appl. Catal. A-Gen. – volume: 8 start-page: 322 year: 2001 end-page: 324 ident: b0105 publication-title: J. Synchr. Radiat. – volume: 177 start-page: 161 year: 1999 end-page: 175 ident: b0030 publication-title: Appl. Catal. A-Gen. – volume: 5 start-page: 49 year: 1985 end-page: 52 ident: b0175 publication-title: Zeolites – volume: 89 start-page: 277 year: 1985 end-page: 281 ident: b0200 publication-title: J. Phys. Chem. – volume: 11 start-page: 132 year: 1991 end-page: 134 ident: b0035 publication-title: Zeolites – volume: 10 start-page: 304 year: 1990 end-page: 306 ident: b0040 publication-title: Zeolites – volume: 135 start-page: 19193 year: 2013 end-page: 19207 ident: b0120 publication-title: J. Am. Chem. Soc. – volume: 185 start-page: 17 year: 2012 end-page: 24 ident: b0015 publication-title: Catal. Today – volume: 97 start-page: 6337 year: 1993 end-page: 6338 ident: b0070 publication-title: J. Phys. Chem. – volume: 122 start-page: 214 year: 1996 end-page: 221 ident: b0090 publication-title: J. Magn. Reson. Ser. A – volume: 362 start-page: 26 year: 2009 end-page: 33 ident: b0025 publication-title: Appl. Catal. A-Gen. – volume: 12 start-page: 537 year: 2005 end-page: 541 ident: b0100 publication-title: J. Synchr. Radiat. – volume: 114 start-page: 15763 year: 2010 end-page: 15770 ident: b0085 publication-title: J. Phys. Chem. C – volume: 136 start-page: 8296 year: 2014 end-page: 8306 ident: b0110 publication-title: J. Am. Chem. Soc. – volume: 91 start-page: 1525 year: 1991 end-page: 1543 ident: b0170 publication-title: Chem. Rev. – volume: 115 start-page: 1204 year: 2011 end-page: 1219 ident: b0130 publication-title: J. Phys. Chem. C – volume: 46 start-page: 7286 year: 2007 end-page: 7289 ident: b0210 publication-title: Angew. Chem.-Int. Ed. – volume: 172 start-page: 73 year: 1998 end-page: 83 ident: b0075 publication-title: Appl. Catal. A – volume: 2 start-page: 59 year: 1982 end-page: 62 ident: b0185 publication-title: Zeolites – volume: 259 start-page: 403 year: 1981 end-page: 408 ident: b0195 publication-title: Doklady Akademii Nauk Sssr – volume: 129 start-page: 11161 year: 2007 end-page: 11171 ident: b0220 publication-title: J. Am. Chem. Soc. – volume: 54 start-page: 209 year: 1995 end-page: 215 ident: b0125 publication-title: React. Kinet. Catal. Lett. – volume: 317 start-page: 11 year: 2014 end-page: 21 ident: b0065 publication-title: J. Catal. – volume: 202 start-page: 129 year: 2001 end-page: 140 ident: b0020 publication-title: J. Catal. – volume: 307 start-page: 194 year: 2013 end-page: 203 ident: b0060 publication-title: J. Catal. – volume: 8 start-page: 322 year: 2001 ident: 10.1016/j.jcat.2018.07.015_b0105 publication-title: J. Synchr. Radiat. doi: 10.1107/S0909049500016964 – volume: 135 start-page: 19193 year: 2013 ident: 10.1016/j.jcat.2018.07.015_b0120 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja4081937 – volume: 2 start-page: 297 year: 1975 ident: 10.1016/j.jcat.2018.07.015_b0150 publication-title: React. Kinet. Catal. Lett. doi: 10.1007/BF02068204 – volume: 7 start-page: 3221 year: 2005 ident: 10.1016/j.jcat.2018.07.015_b0095 publication-title: PCCP doi: 10.1039/b508358c – volume: 80 start-page: 432 year: 1995 ident: 10.1016/j.jcat.2018.07.015_b0225 publication-title: Am. Mineral. doi: 10.2138/am-1995-5-602 – volume: 317 start-page: 11 year: 2014 ident: 10.1016/j.jcat.2018.07.015_b0065 publication-title: J. Catal. doi: 10.1016/j.jcat.2014.05.022 – volume: 185 start-page: 17 year: 2012 ident: 10.1016/j.jcat.2018.07.015_b0015 publication-title: Catal. Today doi: 10.1016/j.cattod.2011.09.028 – volume: 10 start-page: 59 year: 2000 ident: 10.1016/j.jcat.2018.07.015_b0005 publication-title: Top. Catal. doi: 10.1023/A:1019155832086 – volume: 122 start-page: 214 year: 1996 ident: 10.1016/j.jcat.2018.07.015_b0090 publication-title: J. Magn. Reson. Ser. A doi: 10.1006/jmra.1996.0197 – volume: 2 start-page: 297 year: 1975 ident: 10.1016/j.jcat.2018.07.015_b0140 publication-title: React. Kinet. Catal. Lett. doi: 10.1007/BF02068204 – volume: 119 start-page: 1410 year: 2015 ident: 10.1016/j.jcat.2018.07.015_b0215 publication-title: J. Phys. Chem. C doi: 10.1021/jp509982r – volume: 307 start-page: 194 year: 2013 ident: 10.1016/j.jcat.2018.07.015_b0060 publication-title: J. Catal. doi: 10.1016/j.jcat.2013.07.021 – volume: 114 start-page: 15763 year: 2010 ident: 10.1016/j.jcat.2018.07.015_b0085 publication-title: J. Phys. Chem. C doi: 10.1021/jp106621d – volume: 316 start-page: 93 year: 2014 ident: 10.1016/j.jcat.2018.07.015_b0050 publication-title: J. Catal. doi: 10.1016/j.jcat.2014.05.004 – volume: 11 start-page: 132 year: 1991 ident: 10.1016/j.jcat.2018.07.015_b0035 publication-title: Zeolites doi: 10.1016/0144-2449(91)80406-P – volume: 148 start-page: 213 year: 1994 ident: 10.1016/j.jcat.2018.07.015_b0045 publication-title: J. Catal. doi: 10.1006/jcat.1994.1203 – volume: 172 start-page: 73 year: 1998 ident: 10.1016/j.jcat.2018.07.015_b0075 publication-title: Appl. Catal. A doi: 10.1016/S0926-860X(98)00120-3 – volume: 136 start-page: 8296 year: 2014 ident: 10.1016/j.jcat.2018.07.015_b0110 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja501361v – volume: 74 start-page: 71 year: 1993 ident: 10.1016/j.jcat.2018.07.015_b0190 publication-title: Colloids Surf. A-Physicochem. Eng. Asp. doi: 10.1016/0927-7757(93)80399-Y – volume: 13 start-page: 64 year: 1993 ident: 10.1016/j.jcat.2018.07.015_b0055 publication-title: Zeolites doi: 10.1016/0144-2449(93)90025-X – volume: 115 start-page: 1204 year: 2011 ident: 10.1016/j.jcat.2018.07.015_b0130 publication-title: J. Phys. Chem. C doi: 10.1021/jp106536m – volume: 59 start-page: 569 year: 1973 ident: 10.1016/j.jcat.2018.07.015_b0205 publication-title: J. Chem. Phys. doi: 10.1063/1.1680061 – volume: 5 start-page: 11 year: 2015 ident: 10.1016/j.jcat.2018.07.015_b0080 publication-title: ACS Catal. doi: 10.1021/cs501474u – volume: 10 start-page: 304 year: 1990 ident: 10.1016/j.jcat.2018.07.015_b0040 publication-title: Zeolites doi: 10.1016/0144-2449(94)90146-5 – volume: 89 start-page: 277 year: 1985 ident: 10.1016/j.jcat.2018.07.015_b0200 publication-title: J. Phys. Chem. doi: 10.1021/j100248a020 – volume: 97 start-page: 6337 year: 1993 ident: 10.1016/j.jcat.2018.07.015_b0070 publication-title: J. Phys. Chem. doi: 10.1021/j100126a004 – volume: 129 start-page: 11161 year: 2007 ident: 10.1016/j.jcat.2018.07.015_b0220 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja072767y – volume: 135 start-page: 115 year: 1992 ident: 10.1016/j.jcat.2018.07.015_b0230 publication-title: J. Catal. doi: 10.1016/0021-9517(92)90273-K – volume: 98 start-page: 4647 year: 1994 ident: 10.1016/j.jcat.2018.07.015_b0180 publication-title: J. Phys. Chem. doi: 10.1021/j100068a027 – volume: 259 start-page: 403 year: 1981 ident: 10.1016/j.jcat.2018.07.015_b0195 publication-title: Doklady Akademii Nauk Sssr – volume: 2 start-page: 59 year: 1982 ident: 10.1016/j.jcat.2018.07.015_b0185 publication-title: Zeolites doi: 10.1016/S0144-2449(82)80042-0 – volume: 54 start-page: 209 year: 1995 ident: 10.1016/j.jcat.2018.07.015_b0125 publication-title: React. Kinet. Catal. Lett. doi: 10.1007/BF02071200 – volume: 60 start-page: 1506 year: 1956 ident: 10.1016/j.jcat.2018.07.015_b0155 publication-title: J. Phys. Chem. doi: 10.1021/j150545a009 – volume: 91 start-page: 1525 year: 1991 ident: 10.1016/j.jcat.2018.07.015_b0170 publication-title: Chem. Rev. doi: 10.1021/cr00007a013 – volume: 202 start-page: 129 year: 2001 ident: 10.1016/j.jcat.2018.07.015_b0020 publication-title: J. Catal. doi: 10.1006/jcat.2001.3265 – volume: 177 start-page: 161 year: 1999 ident: 10.1016/j.jcat.2018.07.015_b0030 publication-title: Appl. Catal. A-Gen. doi: 10.1016/S0926-860X(98)00264-6 – volume: 157 start-page: 388 year: 1995 ident: 10.1016/j.jcat.2018.07.015_b0115 publication-title: J. Catal. doi: 10.1006/jcat.1995.1304 – volume: 46 start-page: 7286 year: 2007 ident: 10.1016/j.jcat.2018.07.015_b0210 publication-title: Angew. Chem.-Int. Ed. doi: 10.1002/anie.200702628 – volume: 248 start-page: 20 year: 2007 ident: 10.1016/j.jcat.2018.07.015_b0145 publication-title: J. Catal. doi: 10.1016/j.jcat.2007.02.022 – volume: 179 start-page: 71 year: 1999 ident: 10.1016/j.jcat.2018.07.015_b0010 publication-title: Appl. Catal. A-Gen. doi: 10.1016/S0926-860X(98)00301-9 – volume: 49 start-page: 808 year: 2010 ident: 10.1016/j.jcat.2018.07.015_b0135 publication-title: Angew. Chem.-Int. Ed. doi: 10.1002/anie.200905869 – volume: 362 start-page: 26 year: 2009 ident: 10.1016/j.jcat.2018.07.015_b0025 publication-title: Appl. Catal. A-Gen. doi: 10.1016/j.apcata.2009.04.013 – volume: 12 start-page: 537 year: 2005 ident: 10.1016/j.jcat.2018.07.015_b0100 publication-title: J. Synchr. Radiat. doi: 10.1107/S0909049505012719 – volume: 103 start-page: 4992 year: 1981 ident: 10.1016/j.jcat.2018.07.015_b0160 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00407a002 – start-page: 239 year: 1985 ident: 10.1016/j.jcat.2018.07.015_b0165 publication-title: Zeitschrift für Physikalische Chemie doi: 10.1515/zpch-1985-26636 – volume: 5 start-page: 49 year: 1985 ident: 10.1016/j.jcat.2018.07.015_b0175 publication-title: Zeolites doi: 10.1016/0144-2449(85)90012-0 |
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•Mild steaming leads to partially framework-bound aluminum oxide species.•These aluminum oxide clusters are in the vicinity of Brønsted acid... Short exposure of HZSM-5 zeolites to water vapor at high temperatures (mild steaming) enhances the rates of alkane cracking and dehydrogenation as well as the... |
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| SubjectTerms | alkanes aluminum aluminum oxide Bronsted acids Butane cracking catalytic activity Confinement effect crystallites dehydrogenation entropy H/D exchange hydrogen hydrolysis HZSM-5 kinetics Mild steaming nuclear magnetic resonance spectroscopy solids stable isotopes steaming temperature water vapor zeolites |
| Title | Hydrolysis of zeolite framework aluminum and its impact on acid catalyzed alkane reactions |
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