Aqua regia extractable selenium concentrations of some Scottish topsoils measured by ICP-MS and the relationship with mineral and organic soil components
BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationsh...
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Published in | Journal of the science of food and agriculture Vol. 90; no. 6; pp. 972 - 980 |
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Main Authors | , , , , , , |
Format | Journal Article |
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Chichester, UK
John Wiley & Sons, Ltd
30.04.2010
Wiley John Wiley and Sons, Limited |
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Abstract | BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction.RESULTS: The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg⁻¹. No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important.CONCLUSION: The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. |
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AbstractList | To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction.
The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg(-1). No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important.
The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction.RESULTS: The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg⁻¹. No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important.CONCLUSION: The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X‐ray diffraction. RESULTS: The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg−1. No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K‐feldspar concentration, with other minerals being less important. CONCLUSION: The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. Copyright © 2010 Society of Chemical Industry To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction. The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg... No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important. The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. (ProQuest: ... denotes formulae/symbols omitted.) To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction.BACKGROUNDTo provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction.The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg(-1). No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important.RESULTSThe aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg(-1). No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important.The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important.CONCLUSIONThe Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X-ray diffraction. RESULTS: The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg-1. No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K-feldspar concentration, with other minerals being less important. CONCLUSION: The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of their parent rock, which were expected to have relatively high, low or unclassified Se concentrations. To investigate relationships between the actual minerals in the soils and the aqua regia extractable Se concentration of the soil, soil minerals were quantified by X‐ray diffraction. RESULTS: The aqua regia extractable Se concentrations of the soils were between 0.19 and 1.46 mg kg −1 . No simple correlation between the aqua regia extractable Se concentrations of the soil and the parent rock classification estimated by soil survey was evident. Partial least squares analysis revealed that the aqua regia extractable Se concentration of the soils was positively related to loss on ignition (LOI) or C concentration and negatively related to the K‐feldspar concentration, with other minerals being less important. CONCLUSION: The Se concentration of arable topsoils from Scotland is more related to LOI or carbon concentration, with parent material being less important. Copyright © 2010 Society of Chemical Industry |
Author | Shand, Charles A Hudson, Gordon Hillier, Stephen J Balsam, Matthias Nicol, Fergus Arthur, John R Newman, Gareth |
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Keywords | soil carbon aqua regia extraction inductively coupled plasma mass spectrometry soil Concentration soil minerals Inductive coupling plasma spectrometry Carbon Inorganic element Soils Chemical composition Extraction Selenium Mass spectrometry |
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Snippet | BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on... BACKGROUND: To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on... To provide information concerning the geographical distribution of selenium (Se) in the soils of Scotland, we analysed 47 arable soils selected on the basis of... |
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SubjectTerms | acid treatment Aluminum Silicates Aluminum Silicates - analysis analysis aqua regia aqua regia extraction Arable land arable soils Biological and medical sciences Carbon Carbon - analysis chemical concentration chemistry classification Dietary minerals Diffraction extraction Extraction processes Food engineering Food industries Fundamental and applied biological sciences. Psychology General aspects geographical variation Geologic Sediments Geologic Sediments - chemistry Geologic Sediments - classification Hydrochloric Acid inductively coupled plasma mass spectrometry Least-Squares Analysis Mass Spectrometry mineral content Minerals Minerals - analysis Nitric Acid organic compounds Parents Potassium Potassium - analysis Potassium Compounds Potassium Compounds - analysis Rock Scotland Selenium Selenium - analysis Soil Soil (material) Soil - analysis soil carbon soil chemistry soil mineralogy soil minerals Soils Topsoil X-Ray Diffraction |
Title | Aqua regia extractable selenium concentrations of some Scottish topsoils measured by ICP-MS and the relationship with mineral and organic soil components |
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